Skip to main content
Log in

Effects of surface modification of silane coupling agent on the properties of concrete with freeze-thaw damage

  • Structural Engineering
  • Published:
KSCE Journal of Civil Engineering Aims and scope

Abstract

Surface waterproofing treatment with silane coupling agent is developed to prepare surface modification concrete, in recent years, which possesses an excellent permeability resistance. Freeze-thaw damage inevitable exists in concrete exposed to the cold environment, therefor this paper intensively investigates the effects of surface modification of silane coupling agent on the properties of concrete with freeze-thaw damage. Freeze-thaw cycles, capillary absorption, chloride penetration and carbonization tests were carried out, respectively. The results demonstrate that the surface waterproofing treatment is appropriate for the durability repairing of concrete with freeze-thaw damage, and the penetration depth of silane coupling agent in concrete increases linearly with the rise of freeze-thaw damage. The water and chloride permeability both increase with the increased freeze-thaw cycles for various concrete; however, the surface modification concrete has a better permeability resistance than ordinary concrete with the same freeze-thaw damage. In particular, the permeability resistance increases with the increases of applied amount of silane coupling agent, and there exists a good correlation between the permeability behavior and induced freeze-thaw damage for various concrete. Abrasion significantly decrease the permeability resistance of surface modification concrete, which should be considered carefully in the durability repairing.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Atis, C. D. (2002). “High volume fly ash abrasion resistant concrete.” Journal of Materials in Civil Engineering, Vol. 14, No. 3, pp. 274–277, DOI: 10.1061/(ASCE)0899-1561(2002)14:3(274).

    Article  Google Scholar 

  • Atmani, F., Lahem, D., Poelman, M., Buess-Herman, C., and Olivier, M. G. (2013). “Mild steel corrosion in chloride environment: effect of surface preparation and influence of inorganic inhibitors.” Corrosion Engineering, Science and Technology, Vol. 48, No. 1, pp. 9–18, DOI: 10.1179/1743278212Y.0000000037.

    Article  Google Scholar 

  • Badar, M. S. and Kupwade, K. (2014). “Corrosion of steel bars induced by accelerated carbonation in low and high calcium fly ash geopolymer concretes.” Construction and Building Materials, Vol. 61, No. 61, pp. 79–89, DOI: 10.1016/j.conbuildmat.2014.03.015.

    Article  Google Scholar 

  • Bogas, J. A., Gomes, M. G., and Real, S. (2015). “Capillary absorption of structural lightweight aggregate concrete.” Materials and Structures, Vol. 48, No. 9, pp. 2869–2883, DOI: 10.1617/s11527-014-0364-x.

    Article  Google Scholar 

  • Bush, T. D., Kamel, A. A., and Kalluri, P. A. (1997). “Influence of field variables on laboratory performance of silane treated concrete.” ACI Materials Journal, Vol.94, No. 3, pp. 193–202.

    Google Scholar 

  • Christodoulou, C., Goodier, C. I., Austin, S. A., Webb, J., and Glass, G. K. (2013). “Long-term performance of surface impregnation of reinforced concrete structures with silane.” Construction and Building Materials, Vol. 48, pp. 708–716, DOI: 10.1016/j.conbuildmat.2013. 07.038.

    Article  Google Scholar 

  • Chindaprasirt, P. and Chalee, W. (2014). “Effect of sodium hydroxide concentration on chloride penetration and steel corrosion of fly ashbased geopolymer concrete under marine site.” Construction and Building Materials, Vol. 63, pp. 303–310, DOI: 10.1016/j.conbuildmat. 2014.04.010.

    Article  Google Scholar 

  • Gonen, T., Yazicioglu, S., and Demirel, B. (2015). “The influence of freezing-thawing cycles on the capillary water absorption and porosity of concrete with mineral admixture.” KSCE Journal of Civil Engineering, Vol. 19, No. 3, pp. 667–671, DOI: 10.1007/s12205-012-0207-7.

    Article  Google Scholar 

  • Hanjari, K. Z., Utgenannt, P., and Lundgren, K. (2011). “Experimental study of the material and bond properties of frost-damaged concrete.” Cement and Concrete Research, Vol. 41, No. 3, pp. 244–254, DOI: 10.1016/j.cemconres.2010.11.007.

    Article  Google Scholar 

  • Jacobsen, S., Gran, H. C., Sellevold, E. J., and Bakke, J. A. (1995). “High strength concrete-freeze/thaw testing and cracking.” Cement and Concrete Research, Vol. 25, No. 8, pp. 1775–1780, DOI: 10.1016/0008-8846(95)00173-5.

    Article  Google Scholar 

  • Kamal, A., Kunieda, M., Ueda, N., and Nakamura, H. (2008). “Evaluation of crack opening performance of a repair material with strain hardening behavior.” Cement and Concrete Composites, Vol. 30, No. 10, pp. 863–871, DOI: 10.1016/j.cemconcomp.2008.08.003.

    Article  Google Scholar 

  • Kelham, S. A. (1988). “A water absorption test for concrete.” Magazine of Concrete Research, Vol. 40, No. 1, pp. 106–110, DOI: 10.1680/ macr.1988.40.143.106.

    Article  Google Scholar 

  • Kim, S. W. and Yun, H. D. (2011). “Crack-damage mitigation and flexural behavior of flexure-dominant reinforced concrete beams repaired with strain-hardening cement-based composite.” Composites Part B: Engineering, Vol. 42, No. 4, pp. 645–656, DOI: 10.1016/j.compositesb.2011.02.022.

    Article  Google Scholar 

  • Li, G., Wang, Z., Leung, C. K., Tang, S., Pan, J., Huang, W., and Chen, E. (2016). “Properties of rubberized concrete modified by using silane coupling agent and carboxylated SBR.” Journal of Cleaner Production, Vol. 112, pp. 797–807, DOI: 10.1016/j.jclepro.2015. 06.099.

    Article  Google Scholar 

  • Li, M., Zhang, Y., Wu, Z., Qian, C., and Sun, W. (2013). “Effect of chloride salt and freeze-thaw cycling on the microstructure of concrete.” Cement Wapno Beton, Vol. 18, No. 2, pp. 74–80.

    Google Scholar 

  • Ma, Z., Wittmann, F. H., Xiao, J., and Zhao, T. (2016). “Influence of freeze-thaw cycles on properties of integral water repellent concrete.” Journal of Wuhan University of Technology-Mater. Sci. Ed., Vol. 31, No. 4, pp. 551–556, DOI: 10.1007/s11595-016-1458-9.

    Google Scholar 

  • Ma, Z., Zhao, T., and Zhao, Y. (2016). “Effects of hydrostatic pressure on chloride ion penetration into concrete.” Magazine of Concrete Research, Vol. 68, No. 17, pp. 877–886, DOI: 10.1680/jmacr.15.00364.

    Article  Google Scholar 

  • Ma, Z., Zhao, T., Xiao, J., and Guan, T. (2016). “Evaluation of rebar corrosion in reinforced concrete under freeze-thaw environment and protection measures.” Anti-Corrosion Methods and Materials, Vol. 63, No. 2, pp. 128–136, DOI: 10.1108/ACMM-11-2014-1461.

    Article  Google Scholar 

  • Marzouk, H. and Jiang, K. (1995). “Effects of freezing and thawing on tension properties of high-strength concrete.” ACI Materials Journal, Vol. 91, No. 6, pp. 577–586,.

    Google Scholar 

  • Naik, T. R, Singh, S. S., and Hossain, M. M. (1995). “Abrasion resistance of high-strength concrete made with class C fly ash.” ACI Materials Journal, Vol. 92, No. 6, pp. 649–659.

    Google Scholar 

  • Nanni, A. (1995). “Concrete repair with externally bonded FRP reinforcement.” Concrete International, Vol. 17, No. 6, pp. 22–26.

    Google Scholar 

  • Petersen, L., Lohaus, L., and Polak, M. A. (2007). “Influence of freezing-and-thawing damage on behavior of reinforced concrete elements.” ACI Materials Journal, Vol. 104, No. 4, pp. 369–378.

    Google Scholar 

  • Ramezanianpour, A. A., Pilvar, A., Mahdikhani, M., and Moodi, F. (2011). “Practical evaluation of relationship between concrete resistivity, water penetration, rapid chloride penetration and compressive strength.” Construction and Building Materials, Vol. 25, No. 5, pp. 2472–2479, DOI: 10.1016/j.conbuildmat.2010.11.069.

    Article  Google Scholar 

  • Saadatmanesh, H., Ehsani, M. R., and Jin, L. (1997). “Repair of earthquakedamaged RC columns with FRP wraps.” ACI Structural Journal, Vol. 94, pp. 206–215

    Google Scholar 

  • Thangavel, K. and Rengaswamy, N. S. (1998). “Relationship between chloride/hydroxide ratio and corrosion rate of steel in concrete.” Cement and Concrete Composites, Vol. 20, No. 4, pp. 283–292. DOI: 10.1016/S0958-9465(98)00006-7.

    Article  Google Scholar 

  • Tittarelli, F. and Moriconi, G. (2010). “The effect of silane-based hydrophobic admixture on corrosion of galvanized reinforcing steel in concrete.” Corrosion Science, Vol. 52, No. 9, pp. 2958–2963, DOI: 10.1016/j.corsci.2010.05.008.

    Article  Google Scholar 

  • Wang, D., Yang, P., Hou, P., Zhang, L., Zhou, Z., and Cheng, X. (2016). “Effect of SiO2, oligomers on water absorption of cementitious materials.” Cement and Concrete Research, Vol. 87, pp. 22–30, DOI: 10.1016/j.cemconres.2016.05.005.

    Article  Google Scholar 

  • Wang, H., Lu, C., Jin, W., and Bai, Y. (2011). “Effect of external loads on chloride transport in concrete.” Journal of Materials in Civil Engineering, Vol. 23, No. 7, pp. 1043–1049, DOI: 10.1061/(ASCE) MT.1943-5533.0000265.

    Article  Google Scholar 

  • Wang, L. and Li, S. (2014). “Capillary absorption of concrete after mechanical loading.” Magazine of Concrete Research, Vol. 66, No. 8, pp. 420–431, DOI: 10.1680/macr.13.00331.

    Article  Google Scholar 

  • Wang, Z., Zeng, Q., Wang, L., Yao, Y., and Li, K. (2014). “Corrosion of rebar in concrete under cyclic freeze–thaw and chloride salt action.” Construction and Building Materials, Vol. 53, No. 3, pp. 40–47, DOI: 10.1016/j.conbuildmat.2013.11.063.

    Article  Google Scholar 

  • Xiong, G., Luo, B., Wu, X., Li, G., and Chen, L. (2006). “Influence of silane coupling agent on quality of interfacial transition zone between concrete substrate and repair materials.” Cement and Concrete Composites, Vol. 28, No. 1, pp. 97–101, DOI: 10.1016/j.cemconcomp. 2005.09.004.

    Article  Google Scholar 

  • Yazici, H. (2008). “The effect of silica fume and high-volume Class C fly ash on mechanical properties, chloride penetration and freeze–thaw resistance of self-compacting concrete.” Construction and Building Materials, Vol. 22, No. 4, pp. 456–462, DOI: 10.1016/j.conbuildmat.2007.01.002.

    Article  Google Scholar 

  • Yuan, J., Liu, Y., Li, H., and Zhang, B. (2014). “Experimental investigation of the variation of concrete pores under the action of freeze-thaw cycles by using X-ray CT.” Advances in Materials Science and Engineering, DOI: 10.1155/2014/571357.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Zhiming Ma.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ma, Z., Zhu, F. & Zhao, T. Effects of surface modification of silane coupling agent on the properties of concrete with freeze-thaw damage. KSCE J Civ Eng 22, 657–669 (2018). https://doi.org/10.1007/s12205-017-1718-z

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12205-017-1718-z

Keywords

Navigation