Skip to main content
SpringerLink
Log in

Properties and reaction mechanisms of magnesium phosphate cement mixed with acetic acid

  • Structural Engineering
  • Published:
KSCE Journal of Civil Engineering Aims and scope

Abstract

Objective

This study aims to improve the coagulation time, strength, and construction cost of magnesium phosphate cement.

Methods

We analyzed the microstructure changes in the hardened magnesium phosphate cement paste through qualitative analysis, quantitative test, microscopic examination, and research regarding adding different concentrations of acetic acid on magnesium phosphate cement slurry time, effects of flow resistance, and mechanical properties.

Results

When a moderate amount of AA was used, the setting time of MAPC mortar was significantly prolonged but was later reduced as the concentration increased. In the early phase, the degree of MAPC mortar hydration increased, whereas compressive strength significantly increased initially and increased slowly in the later phase. The crystal morphology and size of MAPC hydrates changed, and hardened MAPC became more compact in structure. The AA absorbed some ammonia in the MAPC condensation.

Conclusion

Acetic acid can effectively regulate coagulation time, induce early hydration reaction rate, and improve the performance of magnesium phosphate cement, which can reduce the construction cost of magnesium phosphate cement.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • Del Valle-Zermeno, R., Aubert, J. E., and Laborel-Preneron, A. (2015). “Preliminary study of the mechanical and hygrothermal properties of hemp-magnesium phosphate cements.” Construction and Building Materials, Vol. 105, pp. 62–68, DOI: 10.1016/j.conbuildmat.2015. 12.081.

    Article  Google Scholar 

  • Ding, Z., Dong, B. Q., Xing, F., and Han, N. X. (2012). “Cementing mechanism of potassium phosphate based magnesium phosphate cement.” Ceramics International, Vol. 38, No. 8, pp. 6281–6288, DOI: 10.1016/j.ceramint.2012.04.083.

    Article  Google Scholar 

  • Lu, Z. Y., Hou, D. S., and Ma, H. Y. (2016). “Effects of graphene oxide on the properties and microstructures of the magnesium potassium phosphate cement paste.” Construction and Building Materials, Vol. 119, pp. 107–112, DOI: 10.1016/j.conbuildmat.2016. 05.060.

    Article  Google Scholar 

  • Patrick, K. D. and Matthew, D. A. (2010). “Durable phosphate-bonded natural fiber composite products.” Construction and Building Materials, Vol. 24, pp. 215–219, DOI: 10.1016/j.conbuildmat.2007.05.15.

    Article  Google Scholar 

  • Q, Z. B. and Wu, X. (2000). “Characteristics and durability test of magnesium phosphate cement-based material for rapid repair of concrete.” Materials and Structures, Vol. 33, pp. 229–234, DOI: 10.1007/BF02479332.

    Article  Google Scholar 

  • Qiao, Fei, Chau, C. K., and Li, Z. J. (2012). “Calorimetric study of mannesium potassium phosphate cement.” Materials and Structures, Vol. 45, pp. 447–456, DOI: 10.1617/s11527-011-9776-z.

    Article  Google Scholar 

  • Seehra, S. S., Gupta, S., and Kummar, S. (1993). “Rapid setting magnesium phosphate cement for quick repair of concrete pavements-Characterization and durability aspects.” Cement and Concrete Research, Vol. 23, pp. 254–266, DOI: 10.1016/0008-8846(93)90090-V.

    Article  Google Scholar 

  • Wagh, A. S. (2004). “Chemically bonded phosphateceramic.” Oxford: Elsevier Science Ltd, pp. 173–175, DOI: 10.1111/j.1151-2916.2003.tb03571.x.

    Google Scholar 

  • Xing, F., Ding, Z., and Li, Z. J. (2011). “Effect of additives on properties of magnesium phosphosilicate cement.” Adaancse in Cement Research, Vol. 23, pp. 69–74, DOI: 10.1680/adcr.9.00019.

    Article  Google Scholar 

  • Yang, Q. and Wu, X. (1999). “Faftors influencing properties of phosphate cement-based blinder for rapid repair of concrete.” Cement and Concrete Research, Vol. 29, pp. 389–396, DOI: 10.1016/S0008-8846(98)00230-0.

    Article  Google Scholar 

  • Yu, B. Y., Chen, Z. Q., and Yu, L. L. (2016). “Water-resisting ability of cemented broken rocks.” International Journal of Mining Science and Technology, Vol. 26, pp. 449–454, DOI: 10.1016/S0263-7863 (16)00060-X.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. State Key Laboratory for Geomechanics and Deep Underground Engineering, China University of Mining and Technology, Xuzhou, Jiangsu, 221008, China

    Jun Li, Yong-sheng Ji, Guo-dong Huang, Zhan-zhan Xu & Gui-hong Yan

  2. School of Civil Engineering and Architecture, Kaifeng University, Henan Kaifeng, 475004, China

    Jun Li

  3. JiangSu Collaborative Innovation Center for Building Energy Saving and Construction Technology, Xuzhou, Jiangsu, 221116, China

    Jun Li, Yong-sheng Ji, Guo-dong Huang, Zhan-zhan Xu & Gui-hong Yan

Authors
  1. Jun Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yong-sheng Ji
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Guo-dong Huang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Zhan-zhan Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Gui-hong Yan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yong-sheng Ji.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Li, J., Ji, Ys., Huang, Gd. et al. Properties and reaction mechanisms of magnesium phosphate cement mixed with acetic acid. KSCE J Civ Eng 22, 231–235 (2018). https://doi.org/10.1007/s12205-017-1408-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12205-017-1408-x

Keywords

Search

Navigation