Skip to main content

Advertisement

Log in

Lead-free transparent shields for diagnostic X-rays: Monte Carlo simulation and measurements

  • Published:
Radiological Physics and Technology Aims and scope Submit manuscript

Abstract

In recent years, the preference for using lead-free radiation protection shields has increased because of concerns regarding lead poisoning and leakage. In medical and research laboratories, glass shields are preferred because of their transparency. In this study, various glass shields were examined and compared based on the international standards. One commercially available lead-based shield, four recently studied shields, and three new lead-free shields were considered, and their shielding factors were calculated. We presented three glasses based on borate, phosphate, and silicate compounds, which were named Ir1, Ir2, and Ir3, respectively. Based on the International Electrotechnical Commission standard (IEC 61331), the air-kerma ratios (attenuation ratios) and lead equivalent values were derived using Monte Carlo N-Particle eXtended (MCNPX) calculations, and mass attenuation coefficients and effective atomic numbers (Zeff) of all the shields were obtained from XCOM database, in the diagnostic X-ray energy range of 40–120 keV. In addition, some measurements were performed for the reference (lead-based) glass to validate the simulations. The above-mentioned factors for silicate-bismuth-based (Ir3) and borosilicate-barium-based (Tu) glasses were found to be higher than the others and comparable to those of commercially available lead-based glass. In conclusion, Ir3 and Tu glasses were found to be the preferred lead-free transparent shields in the diagnostic X-ray energy range.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4: a
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Sharifi S, Bagheri R, Shirmardi S. Comparison of shielding properties for ordinary, barite, serpentine and steel–magnetite concretes using MCNP-4C code and available experimental results. Ann Nucl Energy. 2013;53:529–34.

    Article  CAS  Google Scholar 

  2. Shirmardi S, Shamsaei M, Naserpour M. Comparison of photon attenuation coefficients of various barite concretes and lead by MCNP code, XCOM and experimental data. Ann Nucl Energy. 2013;55:288–91.

    Article  CAS  Google Scholar 

  3. Akkurt I, Akyıldırım H, Karipcin F, Mavi B. Chemical corrosion on gamma-ray attenuation properties of barite concrete. J Saudi Chem Soc. 2012;16(2):199–202.

    Article  CAS  Google Scholar 

  4. Manohara S, Hanagodimath S, Gerward L. Photon interaction and energy absorption in glass: a transparent gamma ray shield. J Nucl Mater. 2009;393(3):465–72.

    Article  CAS  Google Scholar 

  5. Singh K, Singh N, Kaundal R, Singh K. Gamma-ray shielding and structural properties of PbO–SiO2 glasses. Nucl Instrum Methods Phys Res Sect B. 2008;266(6):944–8.

    Article  CAS  Google Scholar 

  6. Seenappa L, Manjunatha HC, Chandrika BM, Chikka H. A Study of shielding properties of X-ray and gamma in barium compounds. J Radiation Protection Res. 2017;42(1):26–32.

    Article  Google Scholar 

  7. Lee C-M, Lee YH, Lee KJ. Cracking effect on gamma-ray shielding performance in concrete structure. Prog Nucl Energy. 2007;49(4):303–12.

    Article  Google Scholar 

  8. Rezaei-Ochbelagh D, Azimkhani S. Investigation of gamma-ray shielding properties of concrete containing different percentages of lead. Appl Radiat Isot. 2012;70(10):2282–6.

    Article  CAS  Google Scholar 

  9. Kaewkhao J, Pokaipisit A, Limsuwan P. Study on borate glass system containing with Bi2O3 and BaO for gamma-rays shielding materials: comparison with PbO. J Nucl Mater. 2010;399(1):38–40.

    Article  CAS  Google Scholar 

  10. Hulbert SM, Carlson KA. Is lead dust within nuclear medicine departments a hazard to pediatric patients? J Nuclear Med Technol. 2009;37(3):170–2.

    Article  Google Scholar 

  11. Millstone E, Russell J. Lead toxicity and public health policy. J R Soc Health. 1995;115(6):347–50.

    Article  CAS  Google Scholar 

  12. Tuscharoen S, Kaewkhao J, Limsuwan P, Chewpraditkul W. Structural, optical and radiation shielding properties of BaO-B2O3-rice husk ash glasses. Procedia Eng. 2012;32:734–9.

    Article  CAS  Google Scholar 

  13. McCaffrey J, Shen H, Downton B, Mainegra-Hing E. Radiation attenuation by lead and nonlead materials used in radiation shielding garments. Med Phys. 2007;34(2):530–7.

    Article  CAS  Google Scholar 

  14. Singh K, Kaur S, Kaundal R. Comparative study of gamma ray shielding and some properties of PbO–SiO2–Al2O3 and Bi2O3–SiO 2–Al2O3 glass systems. Radiat Phys Chem. 2014;96:153–7.

    Article  CAS  Google Scholar 

  15. Rachniyom W, Tuscharoen S, Kaewkhao J, Pachana P. Pb-free radiation shielding glass using coal fly ash. J Math Fundamental Sci. 2015;47(3):309–15.

    Article  CAS  Google Scholar 

  16. Chanthima N, Kaewkhao J, Limsuwan P. Study of photon interactions and shielding properties of silicate glasses containing Bi 2 O 3, BaO and PbO in the energy region of 1 keV to 100GeV. Ann Nucl Energy. 2012;41:119–24.

    Article  CAS  Google Scholar 

  17. Im SH, Na YH, Kim NJ, Kim DH, Hwang CW, Ryu BK. Structure and properties of zinc bismuth phosphate glass. Thin Solid Films. 2010;518(24):e46–9.

    Article  Google Scholar 

  18. Doweidar H, Moustafa Y, El-Egili K, Abbas I. Infrared spectra of Fe2O3–PbO–P2O5 glasses. Vib Spectrosc. 2005;37(1):91–6.

    Article  CAS  Google Scholar 

  19. Bingham P, Hand R, Forder S. Doping of iron phosphate glasses with Al2O3, SiO2 or B2O3 for improved thermal stability. Mater Res Bull. 2006;41(9):1622–30.

    Article  CAS  Google Scholar 

  20. Kaur R, Singh S, Pandey O. Gamma ray irradiation effects on the optical properties of BaO–Na2O–B2O3–SiO2 glasses. J Mol Struct. 2013;1048:78–82.

    Article  CAS  Google Scholar 

  21. Kaundal R, Kaur S, Singh N, Singh K. Investigation of structural properties of lead strontium borate glasses for gamma-ray shielding applications. J Phys Chem Solids. 2010;71(9):1191–5.

    Article  CAS  Google Scholar 

  22. International Electrotechnical Commission. Protective devices against diagnostic medical X-radiation—part 1: determination of attenuation properties of materials. IEC Report. 2014; 61331–1.

  23. Berger M, Hubbell J, Seltzer S, Chang J, Coursey J, Sukumar R, Zucker D. XCOM: photon cross sections database. 2005 (last update).

  24. Sekimoto M, Katoh Y. Coloring characteristic of lead glass for X32 Ray irradiation. N J Glass Ceramics. 2015;5(03):25.

    Article  CAS  Google Scholar 

  25. Kaur K, Singh K, Anand V. Structural properties of Bi2O3–B2O3– SiO2–Na2O glasses for gamma ray shielding applications. Radiat Phys Chem. 2016;120:63–72.

    Article  CAS  Google Scholar 

  26. Srisittipokakun N, Kaewkhao J, Chewpraditkul W, Limsuwan P. Comparative study of optical and spectroscopic properties of lead and bismuth on borosilicate glasses. Procedia Eng. 2012;32:699–705.

    Article  CAS  Google Scholar 

  27. Kurudirek M, Özdemir Y, Şimşek Ö, Durak R. Comparison of some lead and non-lead based glass systems, standard shielding concretes and commercial window glasses in terms of shielding parameters in the energy region of 1 keV–100 GeV: a comparative study. J Nucl Mater. 2010;407(2):110–5.

    Article  CAS  Google Scholar 

  28. Hine G. The effective atomic numbers of materials for various gamma ray processes. Phys Rev. 1952;85:725.

    CAS  Google Scholar 

  29. Singh K, Singh H, Sharma V, Nathuram R, Khanna A, Kumar R, et al. Gamma-ray attenuation coefficients in bismuth borate glasses. Nucl Instrum Methods Phys Res Sect B. 2002;194(1):1–6.

    Article  CAS  Google Scholar 

  30. Khan FM, Gibbons JP. Khan’s the physics of radiation therapy. Philadelphia: Lippincott Williams and Wilkins; 2014.

    Google Scholar 

  31. Singh K, Singh H, Sharma G, Gerward L, Khanna A, Kumar R, et al. Gamma-ray shielding properties of CaO–SrO–B2O3 glasses. Radiat Phys Chem. 2005;72(2):225–8.

    Article  CAS  Google Scholar 

  32. Ruengsri S, Insiripong S, Sangwaranatee N, Kaewkhao J. Development of barium borosilicate glasses for radiation shielding materials using rice husk ash as a silica source. Prog Nucl Energy. 2015;83:99–104.

    Article  CAS  Google Scholar 

  33. Jahagirdar H, Hanumaiah B, Thontadarya S. Determination of narrow beam attenuation coefficients from a broad beam geometrical configuration for 320 keV photons. Int J Radiation Appl Instrumentation Part A Appl Radiation Isotopes. 1992;43(12):1511–4.

    Article  CAS  Google Scholar 

  34. Chimanski A, Cesar PF, Fredericci C, Yoshimura HN. Evaluation of glass viscosity of dental bioceramics by the SciGlass information system. Ceram Int. 2015;41(8):10000–9.

    Article  CAS  Google Scholar 

  35. Affatigato M, editor. Modern glass characterization. Wiley: New Jersey; 2015.

  36. Arbuzov VI, Andreeva NZ, Leko NA, Nikitina SI, Orlov NF, Fedorov YuK. Optical, spectral, and radiation-shielding properties of high-lead phosphate glasses. Glass Phys Chem. 2005;31(5):583–90.

    Article  CAS  Google Scholar 

  37. Pereira A, Strauss F, Da Silva D, inventors; Companhia Brasileira de Metalurgia e Mineracao, assignee. Glass compositions for the production of lead-free crystals. United States patent application US 10/540,727. 2006.

Download references

Acknowledgements

This study is a part of M.Sc. thesis of Mr. Milad Karimi with Grant No. 12755-01-01-95. Authors would like to thank Vice Chancellery for research and technology affairs of Shiraz University of Medical Sciences (SUMS) for supporting this research.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Hesameddin Mostaghimi.

Ethics declarations

Conflict of interest

There is not any relationship that might lead to a conflict of interest.

Ethical approval

This research does not contain any study with human participants or animals performed by any of the authors. Other ethical issues have been taken into consideration.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Karimi, M., Ghazikhanlou-sani, K., Mehdizadeh, A.R. et al. Lead-free transparent shields for diagnostic X-rays: Monte Carlo simulation and measurements. Radiol Phys Technol 13, 276–287 (2020). https://doi.org/10.1007/s12194-020-00580-5

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12194-020-00580-5

Keywords

Navigation