Abstract
The non-linear optical responses of cherry seed oil, avocado seed oil, and sesame oil were investigated by observing spatial self-phase modulation (SSPM) in oil samples using a continuous wave laser beam. The non-linear refraction coefficients and third-order non-linear susceptibility χ(3) of the edible oils were estimated to be 10−6 cm2/W and 10−5 esu, respectively, based on the intensity-dependent number of symmetric diffraction rings observed. Additionally, we examined the potential of the spatial self-phase modulation technique to determine the authenticity of three adulterated oils based on their non-linear optical properties. For this purpose, five different adulterated samples were prepared by diluting the samples with sunflower oil, a cheaper commercial oil, at various dilution ratios. The measured non-linear optical parameters of the adulterated samples revealed a strong correlation between the non-linear optical properties and the level of adulteration in the samples. These results suggest that the SSPM technique could be considered for estimating the degree of adulteration in samples based on their non-linear optical responses.
Similar content being viewed by others
Data Availability
All data generated or analyzed during this study are included in this published article
References
Alencar MA, Nascimento CM, Chávez-Cerda S, da Silva MG, Meneghetti MR, Hickmann JM (2006) Large spatial self-phase modulation in castor oil enhanced by gold nanoparticles. In: Paper read at Non-linear Frequency Generation and Conversion: Materials, Devices, and Applications V. https://doi.org/10.1117/12.647000
Alfred T, Matthäus B, Fiebig H (2002) Fats and fatty oils. Ullmann’s Encyclopedia of Industrial Chemistry. Wiley-VCH, Weinheim
Arena P, Rigano F, Guarnaccia P, Dugo P, Mondello L, Trovato E (2022) Elucidation of the lipid composition of hemp (Cannabis sativa L.) products by means of gas chromatography and ultra-high performance liquid chromatography coupled to mass spectrometry detection. Molecules 27(10):3358. https://doi.org/10.3390/molecules27103358
Boyd RW (2020) Nonlinear optics. Academic press
Cakaloglu B, Ozyurt VH, Otles S (2018) Cold press in oil extraction. A review. Ukr Food J 7(4):640–654. https://doi.org/10.24263/2304-974X-2018-7-4-9
de Souza DL, Bittencourt MV, Lenart VM, da Cruz GK, Turchiello RF, Gómez SL (2020) Nonlinear optical response of Chinese teas probed by spatial self-phase modulation. Braz J Phys 50(4):394–398. https://doi.org/10.1007/s13538-020-00756-9
Deng L, He K, Zhou T, Li C (2005) Formation and evolution of far-field diffraction patterns of divergent and convergent Gaussian beams passing through self-focusing and self-defocusing media. J Opt A Pure Applied Opt 7(8):409. https://doi.org/10.1088/1464-4258/7/8/011
Franken P, Hill AE, Peters CW, Weinreich G (1961) Generation of optical harmonics. Phys Rev Lett 7(4):118. https://doi.org/10.1103/PhysRevLett.7.118
Gouilleux B, Marchand J, Charrier B, Remaud G, Giraudeau P (2018) High-throughput authentication of edible oils with benchtop Ultrafast 2D NMR. Food Chem 244:153–158. https://doi.org/10.1016/j.foodchem.2017.10.016
Gunstone F (2011) Vegetable oils in food technology: composition, properties and uses. Wiley
Hasenhuettl GL (2016) Fats and fatty oils. In: Kirk-Othmer encyclopedia of chemical technology, 4th ed. Wiley, New York. https://doi.org/10.1002/0471238961.0601201908011905.a01.pub3
Henari FZ, Cassidy S (2012) Non-linear optical properties and all optical switching of Congo red in solution. Optik 123(8):711–714. https://doi.org/10.1016/j.ijleo.2011.06.029
Jia Y, Liao Y, Wu L, Shan Y, Dai X, Cai H, Xiang Y, Fan D (2019) Nonlinear optical response, all optical switching, and all optical information conversion in NbSe 2 nanosheets based on spatial self-phase modulation. Nanoscale 11(10):4515–4522. https://doi.org/10.1039/C8NR08966C
Kazempour-Samak M, Rashidi L, Ghavami M, Sharifan A, Hosseini F (2021) Sour cherry (Cerasus vulgaris Miller) kernel oil as the novel functional edible oil: Sensory evaluation and antioxidant and physicochemical properties. J Food Qual 2021:1–9. https://doi.org/10.1155/2021/5529613
Lechhab T, Lechhab W, Trovato E, Salmoun F, Mondello L, Cacciola F (2022a) Impact of edaphoclimatic conditions and crop season on olive oil's fatty acids. Agron J 114(6):3118–3128. https://doi.org/10.1002/agj2.21161
Lechhab T, Lechhab W, Trovato E, Salmoun F, Mondello L, Cacciola F (2022b) Screening of the volatile composition of moroccan olive oils by using SPME/GC-MS-FID over a two-year period: a pedoclimatic discrimination. Horticulturae 8(10):925. https://doi.org/10.3390/horticulturae8100925
Li C (2017) Nonlinear optics. Springer, Singapore. https://doi.org/10.1007/978-981-10-1488-8
Li J, Zhang Z, Yi J, Miao L, Huang J, Zhang J, He Y, Huang B, Zhao C, Zou Y (2020a) Broadband spatial self-phase modulation and ultrafast response of MXene Ti3C2Tx (T= O, OH or F). Nanophotonics 9(8):2415–2424. https://doi.org/10.1515/nanoph-2019-0469
Li T, Hao R, Zhang L, Mao J, Li F, Zhang Y, Fang J, Zhang L (2020b) Superior third-order nonlinearity in inorganic fullerene-like WS2 nanoparticles. Photonics Res 8(12):1881–1887. https://doi.org/10.1364/PRJ.399490
Liao Y, Song C, Xiang Y, Dai X (2020) Recent advances in spatial self-phase modulation with 2D materials and its applications. Ann Phys 532(12):2000322. https://doi.org/10.1002/andp.202000322
Maiman, T. H. (1960). Stimulated optical radiation in ruby.
Marbello OO, Valbuena DS, Racedo NF (2020) Optical limiting phenomenon study in oils of vegetable origin. J Appl Res Technol 18(6):333–340. https://doi.org/10.22201/icat.24486736e.2020.18.6.1345
Marbello O, Valbuena S, Racedo F (2019) Non-linear optical response of edible oils by means of the z-scan technique. J Phys Conf Ser 1219:012008. https://doi.org/10.1088/1742-6596/1219/1/012008
Moore JC, Spink J, Lipp M (2012) Development and application of a database of food ingredient fraud and economically motivated adulteration from 1980 to 2010. J Food Sci 77(4):R118–R126. https://doi.org/10.1111/j.1750-3841.2012.02657.x
Mota MFS, Waktola HD, Nolvachai Y, Marriott PJ (2021) Gas chromatography–mass spectrometry for characterisation, assessment of quality and authentication of seed and vegetable oils. TrAC Trends Anal Chem 138:116238. https://doi.org/10.1016/j.trac.2021.116238
Mousavi Z, Ghafary B, Ara MM (2019) Fifth-and third-order nonlinear optical responses of olive oil blended with natural turmeric dye using z-scan technique. J Mol Liq 285:444–450. https://doi.org/10.1016/j.molliq.2019.04.077
Nde DB, Foncha AC (2020) Optimization methods for the extraction of vegetable oils: a review. Processes 8(2):209. https://doi.org/10.3390/pr8020209
Ok S (2017) Detection of olive oil adulteration by low-field NMR relaxometry and UV-Vis spectroscopy upon mixing olive oil with various edible oils. Grasas Aceites 68(1):e173–e173. https://doi.org/10.3989/gya.0678161
Qin X, Zhong J (2016) A review of extraction techniques for avocado oil. J Oleo Sci 65:881–888. https://doi.org/10.5650/jos.ess16063
Ribeiro M, Turchiello R, Gómez S (2019) Employment of laser beam self-phase modulation for detecting adulterations in light-absorbing commercial fluids. Food Anal Methods 12(4):908–913. https://doi.org/10.1007/s12161-018-01422-2
Shan Y, Wu L, Liao Y, Tang J, Dai X, Xiang Y (2019) A promising nonlinear optical material and its applications for all-optical switching and information converters based on the spatial self-phase modulation (SSPM) effect of TaSe 2 nanosheets. J Mater Chem 7(13):3811–3816. https://doi.org/10.1039/C9TC00333A
Sheik-Bahae M, Hasselbeck MP (2009) Third-order optical nonlinearities. In: Bass M (ed) Handbook of optics, volume IV: optical properties of materials, nonlinear optics, quantum optics, 3rd edn. McGraw-Hill, pp 16.1–16.36
Sota-Uba I, Bamidele M, Moulton J, Booksh K, Lavine BK (2021) Authentication of edible oils using Fourier transform infrared spectroscopy and pattern recognition methods. Chemom Intel Lab Syst 210:104251. https://doi.org/10.1016/j.chemolab.2021.10425
Souza RF, Alencar MA, Meneghetti MR, Hickmann JM (2009) Large nonlocal nonlinear optical response of castor oil. Opt Mater 31(11):1591–1594. https://doi.org/10.1016/j.optmat.2009.03.006
Wu Y, Zhu L, Wu Q, Sun F, Wei J, Tian Y, Wang W, Bai X, Zuo X, Zhao J (2016) Electronic origin of spatial self-phase modulation: evidenced by comparing graphite with C60 and graphene. Appl Phys Lett 108(24):241110. https://doi.org/10.1063/1.4953827
Xu S, Li X (2021) Refractive index characteristics of edible oils based on spectrometry and effects of oil dispersion on OCT. J Innov Opt Health Sci 14(01):2140010. https://doi.org/10.1142/S1793545821400101
Yang X, Qi S, Chen K, Zhang C, Tian J, Wu Q (2005) Optical limiting characteristics of mercury dithizonate in polymer film. Opt Mater 27(8):1358–1362. https://doi.org/10.1016/j.optmat.2004.07.014
Zamiri R, Parvizi R, Zakaria A, Sadrolhosseini A, Zamiri G, Darroudi M, Husin M (2012) Investigation on nonlinear-optical properties of palm oil/silver nanoparticles. JEOS:RP 7. https://doi.org/10.2971/jeos.2012.12020
Author information
Authors and Affiliations
Contributions
All authors contributed to the concept and design of the study. Data preparation, collection, and analysis were performed by all authors. All authors read and approved the final manuscript.
Corresponding author
Ethics declarations
Ethics Approval
Not applicable.
Informed Consent
Not applicable.
Consent to Participate
Not applicable.
Consent to Publish
Not applicable.
Conflict of Interest
Amir Namiq Hassan declares that he has no conflict of interest. Mohammad Ali Haddad declares that he has no conflict of interest. Moein Golestanifar declares that he has no conflict of interest. Abbas Behjat declares that he has no conflict of interest.
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Hassan, A.N., Haddad, M.A., Golestanifar, M. et al. Non-linear Optical Response as a Food Authentication: Investigation of Non-linear Optical Properties of Edible Oils by Spatial Self-Phase Modulation (SSPM) Method. Food Anal. Methods 16, 1392–1402 (2023). https://doi.org/10.1007/s12161-023-02514-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12161-023-02514-4