Skip to main content

Advertisement

Springer Nature Link
Log in

Solid-Phase Microextraction and Determination of Tin Species in Beverages and Food Samples by Using Poly (ε-Caprolactone-b-4-Vinyl Benzyl-g-Dimethyl Amino Ethyl Methacrylate) Polymer in Syringe System: a Multivariate Study

  • Published:
Food Analytical Methods Aims and scope Submit manuscript

Abstract

A new solid-phase microextraction (SPμE) procedure has been developed for separation and preconcentration of Sn ions by using graphite furnace atomic absorption spectrometry (GFAAS). This technique is based on the complexation of Sn(IV) ions with 1-(2-pyridylazo)-2-naphthol (PAN). The poly (ε-caprolactone-b-4-vinyl benzyl-g-dimethyl amino ethyl methacrylate) polymer (PCL vacr) was used as an adsorbent, and it was loaded in micropipette tip of syringe system. Sn(IV) ions were adsorbed on polymer at pH 6. Different experimental conditions were optimized such as pH, amount of complexing agent, and amount of adsorbent. The detection limit (LOD), limit of quantification, preconcentration factor (PF), and relative standard deviation (RSD) were found as 4.5 ng L−1, 13.5 ng L−1, 100, and 3.3%, respectively. Certified reference materials were used to confirm the accuracy of the investigated procedure, and the procedure was successfully practiced for determination of entire concentration of tin within beverages and different food samples.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

Explore related subjects

Discover the latest articles and news from researchers in related subjects, suggested using machine learning.

References

  • Adams IU, Happiness IU (2010) Estimation of toxic metals in canned milk products from unlaquered tin plate cans. J Am Sci 6:1–6

    Google Scholar 

  • Bermejo-Barrera P, Gonzalez-Campos G, Ferron-Novais M, Bermejo-Barrera A (1998) Column preconcentration of organotin with tropolone-immobilized and their determination by electrothermal atomization absorption spectrometry. Talanta 46:1479–1484

    Article  CAS  PubMed  Google Scholar 

  • Commission Regulation (EC) No 1881/2006. Setting maximum levels for certain contaminants in foodstuffs. Available in: https://ec.europa.eu/jrc/en/eurl/heavymetals/legislation

  • Cruz-Vera M, Lucena R, Cárdenas S, Valcárcel M (2009) One-step in-syringe ionic liquid-based dispersive liquid–liquid microextraction. J Chromatogr A 1216:6459–6465

    Article  CAS  PubMed  Google Scholar 

  • Fornieles AC, de Torres AG, Alonso EV, Pavón JC (2013) Determination of antimony, bismuth and tin in natural waters by flow injection solid phase extraction coupled with online hydride generation inductively coupled plasma mass spectrometry. J Anal At Spectrom 28:364–372

    Article  CAS  Google Scholar 

  • Gholivand M, Babakhanian A, Rafiee E (2008) Determination of Sn (II) and Sn (IV) after mixed micelle-mediated cloud point extraction using α-polyoxometalate as a complexing agent by flame atomic absorption spectrometry. Talanta 76:503–508

    Article  CAS  PubMed  Google Scholar 

  • Gurkan R, Altunay N (2015) Determination of total Sn in some canned beverages by FAAS after separation and preconcentration. Food Chem 177:102–110

    Article  CAS  PubMed  Google Scholar 

  • Hazer B (2010) Amphiphilic poly (3-hydroxy alkanoate) s: potential candidates for medical applications. Int J Polym Sci 2010:1–8. https://doi.org/10.1155/2010/423460

    Article  CAS  Google Scholar 

  • Huang X, Zhang W, Han S, Wang X (1997) Determination of tin in canned foods by UV/visible spectrophotometric technique using mixed surfactants. Talanta 44:817–822

    Article  CAS  PubMed  Google Scholar 

  • Leepipatpiboon V (1995) Trace enrichment by solid-phase extraction for the analysis of heavy metals in water. J Chromatogr A 697:137–143

    Article  CAS  Google Scholar 

  • Lemos VA, Teixeira LSG, Bezerra MA, Costa ACS, Castro JT, Cardoso LAM, de Jesus DS, Santos ES, Baliza PX, Santos LN (2008) New materials for solid-phase extraction of trace elements. Appl Spectrosc Rev 43:303–334

    Article  CAS  Google Scholar 

  • Madrakian T, Ghazizadeh F (2009) Micelle-mediated extraction and determination of tin in soft drink and water samples. J Braz Chem Soc 20:1535–1540

    Article  CAS  Google Scholar 

  • Manzoori JL, Amjadi M, Abolhasani D (2006) Spectrofluorimetric determination of tin in canned foods. J Hazard Mater 137:1631–1635

    Article  CAS  PubMed  Google Scholar 

  • Naeemullah, Kazi TG, Tuzen M (2015) Magnetic stirrer induced dispersive ionic-liquid microextraction for the determination of vanadium in water and food samples prior to graphite furnace atomic absorption spectrometry. Food Chem 172:161–165

  • Pawlik-Skowrońska B, Kaczorowska R, Skowroński T (1997) The impact of inorganic tin on the planktonic cyanobacterium Synechocystis aquatilis: the effect of pH and humic acid. Environ Pollut 97:65–69

    Article  PubMed  Google Scholar 

  • Puri BK, Muñoz-Olivas R, Cámara C (2004) A new polymeric adsorbent for screening and pre-concentration of organotin compounds in sediments and seawater samples. Spectrochim Acta B At Spectrosc 59:209–214

    Article  CAS  Google Scholar 

  • Saleh S, Said S, El-Shahawi M (2001) Extraction and recovery of Au, Sb and Sn from electrorefined solid waste. Anal Chim Acta 436:69–77

    Article  CAS  Google Scholar 

  • Şanal T, Oruç O, Öztürk T, Hazer B (2015) Synthesis of pH-and thermo-responsive poly (ε-caprolactone-b-4-vinyl benzyl-g-dimethyl amino ethyl methacrylate) brush type graft copolymers via RAFT polymerization. J Polym Res 22:3

    Article  CAS  Google Scholar 

  • Somer G, Unal U (2011) Simultaneous determination of trace Sn (II) and Sn (IV) using differential pulse polarography and application. Turk J Chem 35:73–85

    Google Scholar 

  • Tsogas GZ, Giokas DL, Vlessidis AG (2009) Graphite furnace and hydride generation atomic absorption spectrometric determination of cadmium, lead, and tin traces in natural surface waters: study of preconcentration technique performance. J Hazard Mater 163:988–994

    Article  CAS  PubMed  Google Scholar 

  • Tuzen M, Soylak M (2007) Evaluation of trace element contents in canned foods marketed from Turkey. Food Chem 102:1089–1095

    Article  CAS  Google Scholar 

  • Uluozlu OD, Tuzen M (2015) Carrier element-free coprecipitation and speciation of inorganic tin in beverage samples and total tin in food samples using N-Benzoyl-N, N-diisobutylthiourea and its determination by graphite furnace atomic absorption spectrometry. LWT Food Sci Technol 63:1091–1096

    Article  CAS  Google Scholar 

  • Ulusoy S, Ulusoy HI, Akçay M, Gürkan R (2012) Inexpensive and versatile method for trace Sn (II) and Sn (IV) ions in food samples by CPE/FAAS. Food Chem 134:419–426

    Article  CAS  Google Scholar 

  • Ulusoy Hİ, Aksoy Ü, Akçay M (2013) Simultaneous pre-concentration of Pb and Sn in food samples and determination by atomic absorption spectrometry. Eur Food Res Technol 236:725–733

    Article  CAS  Google Scholar 

  • Yang H-J, Jiang S-J, Yang Y-J, Hwang C-J (1995) Speciation of tin by reversed phase liquid chromatography with inductively coupled plasma mass spectrometric detection. Anal Chim Acta 312:141–148

    Article  CAS  Google Scholar 

  • Yildiz U, Hazer B, Tauer K (2012) Tailoring polymer architectures with macromonomer azoinitiators. Polym Chem 3:1107–1118

    Article  CAS  Google Scholar 

  • Yuan C-G, Jiang G-B, He B, J-f L (2005) Preconcentration and determination of tin in water samples by using cloud point extraction and graphite furnace atomic absorption spectrometry. Microchim Acta 150:329–334

    Article  CAS  Google Scholar 

  • Zaporozhets O, Ivanko L, Marchenko I, Orlichenko E, Sukhan V (2001) Quercetin immobilized on silica gel as a solid phase reagent for tin (IV) determination by using the sorption-spectroscopic method. Talanta 55:313–319

    Article  CAS  PubMed  Google Scholar 

  • Zhang W, Müller AH (2010) Synthesis of tadpole-shaped POSS-containing hybrid polymers via click chemistry. Polymer 51:2133–2139

    Article  CAS  Google Scholar 

  • Zhou Q, Bai H, Xie G, Xiao J (2008) Temperature-controlled ionic liquid dispersive liquid phase micro-extraction. J Chromatogr A 1177:43–49

    Article  CAS  PubMed  Google Scholar 

  • Zounr RA, Tuzen M, Khuhawar MY (2017) Novel ultrasonic-assisted deep eutectic solvent-based dispersive liquid–liquid microextraction for determination of vanadium in food samples by electrothermal atomic absorption spectrometry: a multivariate study. Appl Organomet Chem 32. https://doi.org/10.1002/aoc.4144

Download references

Funding

Rizwan Ali Zounris gratefully acknowledge the financial support from TUBITAK, Government of Turkey, through the 2216 fellowship program for the foreign citizens and providing financial support. Dr. Mustafa Tuzen thank the Gaziosmanpasa University and King Fahd University of Petroleum and Minerals, Research Institute, Center for Environment and Water for their supports. He also thank the Turkish Academy of Sciences for the financial support.

Author information

Authors and Affiliations

  1. Faculty of Science and Arts, Chemistry Department, Gaziosmanpasa University, Tokat, Turkey

    Rizwan Ali Zounr & Mustafa Tuzen

  2. Institute of Advanced Research Studies in Chemical Sciences, University of Sindh, Jamshoro, Pakistan

    Rizwan Ali Zounr & Muhammad Yar Khuhawar

  3. Research Institute, Center for Environment and Water, King Fahd University of Petroleum and Minerals, Dhahran, 31261, Saudi Arabia

    Mustafa Tuzen

  4. Faculty of Science and Arts, Chemistry Department and Faculty of Engineering, Departments of Metallurgical and Materials Engineering, Nano Technology Engineering, 67100, Zonguldak, Turkey

    Baki Hazer

Authors
  1. Rizwan Ali Zounr
    View author publications

    Search author on:PubMed Google Scholar

  2. Mustafa Tuzen
    View author publications

    Search author on:PubMed Google Scholar

  3. Baki Hazer
    View author publications

    Search author on:PubMed Google Scholar

  4. Muhammad Yar Khuhawar
    View author publications

    Search author on:PubMed Google Scholar

Corresponding author

Correspondence to Mustafa Tuzen.

Ethics declarations

Conflict of Interest

R. A. Zounr declares that he has no conflict of interest. Mustafa Tuzen declares that he has no conflict of interest. Baki Hazer declares that he has no conflict of interest. M. Y. Khuhawar declares that he has no conflict of interest.

Ethical Approval

This research does not have any studies with human subjects or animals performed by any of the authors.

Informed Consent

Not applicable.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zounr, R.A., Tuzen, M., Hazer, B. et al. Solid-Phase Microextraction and Determination of Tin Species in Beverages and Food Samples by Using Poly (ε-Caprolactone-b-4-Vinyl Benzyl-g-Dimethyl Amino Ethyl Methacrylate) Polymer in Syringe System: a Multivariate Study. Food Anal. Methods 11, 2538–2546 (2018). https://doi.org/10.1007/s12161-018-1237-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12161-018-1237-7

Keywords