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Food Analytical Methods

, Volume 9, Issue 8, pp 2194–2199 | Cite as

Determination of Three Alcohols in Chinese Dukang Base Liquor by FT-NIR Spectroscopy

  • Sihai HanEmail author
  • Weiwei Zhang
  • Xuan Li
  • Peiyan Li
  • Jianxue LiuEmail author
Article

Abstract

Alcohols are important aroma compounds in Chinese liquors. In this work, 3-methyl-1-butanol, 1-butanol, and 1-propanol in Dukang base liquor were simultaneously analyzed by gas chromatography (GC) and fourier-transform near-infrared (FT-NIR) spectroscopy. The optimal combinations of spectral intervals for three alcohols were selected for modeling. The calibration models, which are based on FT-NIR spectral variables and the chemical values, were established with partial least square (PLS) and validated using internal cross validation. In calibration set, the coefficients of determination (R 2) for 1-propanol, 1-butanol, and 3-methyl-1-butanol were 95.21, 98.05, and 98.05, respectively; corresponding root mean square errors of calibration (RMSEC) were 0.27, 0.49, and 0.67 mg per 100 mL. In validation set, the R 2 were 94.72, 97.96, and 95.22; the root mean square errors of prediction (RMSEP) were 0.40, 0.81, and 1.35 mg per 100 mL. The results indicated that the correlation between the values determined by GC and the values estimated by the calibration for the three alcohols was excellent. The FT-NIR spectroscopy calibration models, which with good prediction performance and high precision, could be used as a rapid methods for determination of alcohols in Chinese liquor.

Keywords

Chinese liquor Alcohols Fourier-transform near-infrared (FT-NIR) Partial least squares 

Notes

Compliance with Ethical Standards

This article does not contain any studies with human participants or animals performed by any of the authors.

Funding

This study was funded by the National Natural Science Foundation of China (Grant No. 31471658) and the Doctoral Research Fund of Henan University of Science and Technology (Grant No. 09001701).

Conflict of Interest

Sihai Han declares that he has no conflict of interest. Weiwei Zhang declares that she has no conflict of interest. Xuan Li declares that she has no conflict of interest. Peiyan Li declares that she has no conflict of interest. Jianxue Liu declares that he has no conflict of interest.

Informed Consent

Not applicable.

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Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  1. 1.College of Food and BioengineeringHenan University of Science and TechnologyLuoyangPeople’s Republic of China

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