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The Effect of the Addition of Emulsifiers on the Pasting Properties of Barley Grain and Malt

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Abstract

The characteristics of the starch granule such as swelling, breakdown and retrogradation in large determines the texture and stability of starchy foods. However, other characteristics of the grain and/or the presence or addition of chemical compounds to the grain/food matrix can modify or alter these properties. The aim of this study was to evaluate the effect of the addition of an emulsifier (Tween 20 and 80) on the pasting properties of barley grain and malt using the rapid visco analyser (RVA). A decrease in peak viscosity (PV, cP), breakdown (B, cP) and final viscosity (FV, cP), while an increase in time to peak (TTP, min) and pasting temperature (PT, °C) as consequence of the addition of Tween 20 was observed. However, this trend was not the same for all the varieties analysed. Overall, these results showed that complex between sugars and lipids are present in barley flour and malt. The practical implications of this study are related with the fact that starch alone (amylose and amylopectin) might not be necessarily the only main driver of malt quality in barley.

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References

  • Addo K, Slepak M, Akoh CC (1995) Effects of sucrose fatty acid ester andblends on alveograph characteristics of wheat flour doughs. J Cereal Sci 22:123–127

    Article  CAS  Google Scholar 

  • Azizi MH, Rao GV (2005) Effect of surfactants in pasting characteristics of various starches. Food Hydrocoll 19:739–743

    Article  CAS  Google Scholar 

  • Bason ML, Ronalds JA, Wrigley CW, Hubbard LJ (1993) Testing for sprout damage in malting barley using the Rapid Visco Analyser. Cereal Chem 70:269–272

  • Batey IL (2007) Interpretation of RVA curves. In: Ross AS (ed) Crosbie, G.B. The RVA Handbook, AACC International, pp 19–31

    Google Scholar 

  • BeMiller JN (2011) Pasting, paste, and gel properties of starch-hydrocolids combinations. Carbohydr Polym 86:386–423

    Article  CAS  Google Scholar 

  • Blazek J, Copeland L (2009) Effect of monopalmitin on pasting properties of wheat starches with varying amylose content. Carbohydr Polym 78:131–136

    Article  CAS  Google Scholar 

  • Booth R, Bason ML (2007) Principles of operation and experimental techniques. In: Crosbie GB, Ross AS (eds) The RVA Handbook. AACC international, pp.1-19

  • Choy AL, Hughes JG, Small DM (2010) The effects of microbial transglutaminase, sodium stearoyl lactylate and water on the quality of instant fried noodles. Food Chem 122:957–964

    Article  CAS  Google Scholar 

  • Copeland L, Blazek J, Salman H, Tang MC (2009) Form and functionality of starch. Food Hydrocoll 23:1527–1534

    Article  CAS  Google Scholar 

  • Cozzolino D, Allder K, Roumeliotis S, Eglinton J (2012) Feasibility study on the use of multivariate data methods and derivatives to enhance information from the Rapid Visco Analyser. J Cereal Sci 56:610–614

    Article  CAS  Google Scholar 

  • Cozzolino D, Roumeliotis S, Eglinton J (2014) Combining partial least squares (PLS) discriminant analysis and Rapid Visco Analyser (RVA) to classify barley samples according to year of harvest and locality. Food Anal Methods 7:887–892

    Article  Google Scholar 

  • Cozzolino D, Roumeliotis S, Eglinton J (2015) Relationships between fatty acids content and malt quality in barley grain, malt and wort. Cereal Chem 92:93–97

    Article  CAS  Google Scholar 

  • Deffenbaugh LB, Walker CE (1990) Use of the rapid visco analyzer to measure starch pasting properties. II: Effects of emulsifiers and sugar-emulsifier interactions. Starch 42:89–95

    Article  CAS  Google Scholar 

  • Dickinson E (2009) Hydrocolloids as emulsifiers and emulsion stabilizers. Food Hydrocoll 23:1473–1482

    Article  CAS  Google Scholar 

  • Fox G, Visser J, Skov T, Meijering I, Manley M (2014) Effect of different analysis conditions on Rapid Visco Analyser malt viscograms in relation to malt of varying fermentability. J Inst Brew 120:183–192

    Article  CAS  Google Scholar 

  • Fu Z, Chen J (2015) Shun-Jing Luo, Liu, Ch-M., Liu, W. Effect of food additives on starch retrogradation: A review. Starch-Starke 67:69–78

    Article  CAS  Google Scholar 

  • Gelders GG, Vanderstukken TC, Goesaert H, Delcour JA (2004) Amylose-lipid complexation: a new fractionation method. Carbohydr Polym 56(4):447–458

    Article  CAS  Google Scholar 

  • Ghiasi K, Hoseney RC, Varriano-Marston E (1982) Gelatinization of Wheat Starch 1, Excess Water Systems.”. Cereal Chem 59:81–85

    CAS  Google Scholar 

  • Gunaratne A, Ranaweera S, Corke H (2007) Thermal, pasting, and gelling properties of wheat and potato starches in the presence of sucrose, glucose, glycerol, and hydroxypropyl b-cyclodextrin. Carbohydr Polym 70:112–122

    Article  CAS  Google Scholar 

  • Jovanovich C, Añon MC (1999) Amylose–lipid complex dissociation. A study of the kinetic parameters biopolymers. 49:81–89

  • Juhasz R, Salgo A (2008) Pasting behaviour of amylose, amylopectin and their mixtures determined by RVA curves and first derivatives. Starch 60:70–78

    Article  CAS  Google Scholar 

  • Kaewprapan K, Baros F, Marie E, Inprakhon P, Durand A (2012) Macromolecular surfactants synthesized by lipase-catalyzed transesterification of dextran with vinyl decanoate. Carbohydr Polym 88:313–320

    Article  CAS  Google Scholar 

  • Krog N (1973) Influence of food emulsifiers on pasting temperature and viscosity of various starches. Starch 25:22–27

    Article  CAS  Google Scholar 

  • Meadows F (2002) Pasting process in rice flour using rapid visco analyser curves and first derivatives. Cereal Chem 79:559–562

    Article  CAS  Google Scholar 

  • Meng YC, Sun MH, Fang S, Chen J, Li YH (2014) Effect of sucrose fatty acid esters on pasting, rheological properties and freeze-thaw stability of rice flour. Food Hydrocoll 40:64–70

    Article  CAS  Google Scholar 

  • Mira I, Eliasson A-C, Persson K (2005) Effect of surfactant structure on the pasting properties of wheat flour and starch suspensions. Cereal Chem 82(1):44–52

    Article  CAS  Google Scholar 

  • Morris VJ (1990) Starch gelation and retrogradation. Trends Food Sci Technol 1:2–6

    Article  CAS  Google Scholar 

  • Naes T, Isaksson T, Fearn T, Davies T (2002) A User-friendly guide to multivariate calibration and classification. NIR Publications, Chichester

    Google Scholar 

  • Ross AS, Walker CE, Booth RI, Orth RA, Wrigley CW (1987) The Rapid Visco Analyser: a new technique for the evaluation of sprout damage. Cereal Foods World 32:827–829

    Google Scholar 

  • Sadtler VM, Imbert P, Dellacherie E (2002) Ostwald ripening of oil-in-water emulsions stabilized by phenoxy-substituted dextrans. J Colloid Interface Sci 254:355–361

    Article  CAS  Google Scholar 

  • Sharma P, Gujral HS (2014) Anti-staling effects of b-glucan and barley flour in wheat flour chapatti. Food Chem 145:102–108

    Article  CAS  Google Scholar 

  • Tang MC, Copeland L (2007) Analysis of complexes between lipids and wheat starch. Carbohydr Polym 67:80–85

    Article  CAS  Google Scholar 

  • van den Broek LAM, Boeriu CG (2013) Enzymatic synthesis of oligo- and polysaccharide fatty acid esters. Carbohydr Polym 93:65–72

    Article  Google Scholar 

  • Yuan Y, Gao YX, Mao LK, Zhao J (2008) Food Res Int 41:61–68

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors thank technical staff of the Barley Quality Laboratory and Barley Breeding Program, University of Adelaide. This project (UA00126) is supported by Australia’s grain growers through their investment body the Grain Research and Development Corporation (GRDC), with matching funds from the Australian government.

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Funding

This study was funded by project UA00126, supported by Australia’s grain growers through their investment body the Grain Research and Development Corporation (GRDC), with matching funds from the Australian government.

Conflict of Interest

Daniel Cozzolino declares that he has no conflict of interest. Sophia Degner declares that she has no conflict of interest. Jason Eglinton declares that he has no conflict of interest.

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This article does not contain any studies with human participants performed by any of the authors.

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Correspondence to D. Cozzolino.

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Cozzolino, D., Degner, S. & Eglinton, J. The Effect of the Addition of Emulsifiers on the Pasting Properties of Barley Grain and Malt. Food Anal. Methods 9, 664–669 (2016). https://doi.org/10.1007/s12161-015-0235-2

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  • DOI: https://doi.org/10.1007/s12161-015-0235-2

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