Abstract
Flavonoids, natural vegetable dyes synthesized from phenylalanine, are responsible for the colour of blooming portions of plants. They are very essential for human health due to their activity as free radical acceptors. In this study, electrochemical modification of a glassy carbon (GC) electrode with 4,4′-methylenedianiline (MDA) was carried out, and the modified electrode was investigated separately and simultaneously for the availability in determination of quercetin, kaempferol, luteolin and galangin. The surface modification of the GC electrode was performed with MDA using cyclic voltammetry (CV), whereas the characterization of this sensor electrode was performed using CV, electrochemical impedance spectroscopy and scanning electron microscopy. The usability of the modified electrode has been examined in the determination of some flavonoids using CV, differential pulse voltammetry and square wave voltammetry. Consequently, flavonoid derivatives can easily be determined separately and simultaneously by using an MDA-modified GC sensor electrode.
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Chen G, Ma X, Meng F, Li G (2008) Bioelectrochemistry 72:169
Clifford AH, Cuppett SL (2000) J Sci Food Agric 80:1063
Corte JS, Granados SG, Ordaz A, Griveau S, Bediouib F (2007) Electroanalysis 19:61
Cristani M, D’Arrigo M, Mandalari G, Castelli F, Sarpietro MG, Micieli D, Trombetta D (2007) J Agric Food Chem 55:6300
De Martino L, De Feo V, Fratianni F, Nazzaro F (2009) Nat Prod Commun 4:1741
Demir Mülazımoğlu A, Mülazımoğlu İE, Yılmaz E (2012a) Rev Anal Chem doi:10.1515/revac.2011.151
Demir Mülazımoğlu A, Yılmaz E, Mülazımoğlu İE (2012b) Sensors 12:3916
Denisov ET, Afanasev IB (2005) Chemistry of antioxidants in oxidation and antioxidants in organic chemistry and biology. CRC Press, Taylor & Francis Group, Boca Raton, p 488
Downard AJ (2000) Electroanalysis 12:1085
Geneste F, Moinet C, Jezequel G (2002) New J Chem 26:1539
Halliwell B (1999) Food Sci Agric Chem 1:67
He JB, Wang Y, Deng N, Lin XQ (2007) Bioelectrochemistry 71:157
İsbir-Turan AA, Kılıç E, Üstündağ Z, Ekşi H, Solak AO, Zorer B (2012) J Solid State Electrochem 16:235
Jin G, Zhang Y, Cheng W (2005) Sensors Actuators B 107:528
Karadag A, Ozcelik B, Saner S (2009) Food Anal Method 2:41
Katalinic M, Rusak G, Domacinovic’ Barovic J, Sinko G, Jelic D, Antolovic R, Kovarik Z (2010) Eur J Med Chem 45:186
Keyrouz R, Abasq ML, Le Bourvellec C, Blanc N, Audibert L, ArGall E, Hauchard D (2011) Food Chem 126:831
Kubant R, Malinski C, Burewicz A, Malinski T (2006) Electroanalysis 18:410
Li X, Wan Y, Sun C (2004) J Electroanal Chem 569:79
Macdonald DD (2006) Electrochim Acta 51:1376
Malinauskas A (1999) Synth Met 107:75
Morita K, Yamaguchi A, Teramae N (2004) J Electroanal Chem 563:249
Mulazimoglu IE (2011) Energy Educ Sci Technol Part A 28(1):393
Mülazımoğlu İE, Demir Mülazımoğlu A (2012) Food Anal Methods doi:10.1007/s12161-012-9393-7
Mülazımoğlu İE Desalin (2012) Water Treat. doi:10/5004/dwt.2012.2994
Mulazımoglu IE, Ozkan E (2008) E-J Chem 5(3):539
Mülazımoğlu İE, Solak AO (2011) Anal Methods 3:2534
Mülazımoğlu İE, Yılmaz E (2010) Desalination 256:64
Mülazımoğlu IE, Demir Mülazımoğlu A, Yılmaz E (2011a) Desalination 268:227
Mülazımoğlu İE, Üstündağ Z, Özkan E, Solak AO (2011b) Rev Anal Chem 30:177
Prior RL, Cao G (1999) Free Radic Biol Med 27:1173
Ramanaviciene A, Ramanavicius A (2004) Biosens Bioelectron 20:1076
Ren W, Qian Z, Wang H, Zhu L, Zhang L (2003) Med Chem Res 23(4):519
Samra MA, Chedea VS, Economou A, Calokerinos A, Kefalas P (2011) Food Chem 125:622–629
Sengul M, Yildiz H, Gungor N, Cetin BT, Eser Z, Ercisli S (2009) Pak J Pharm Sci 22:102
Xu MS, Luo MF, Xing XH, Chen HZ (2006) Food Bioprod Process 84:237
Xue J, Ying X, Chen J, Xian Y, Jin LT (2000) Anal Chem 72:5313
Yao LH, Jiang YM, Shi J, Toma’ NFA, Barbera’ S, Datta N, Singanusong R (2004) Plant Foods Hum Nutr 59:113
Yao H, Sun Y, Lin X, Tang Y, Huang L (2007) Electrochim Acta 52:6165
Zhao H, Zhang Y, Yuan Z (2001) Anal Chim Acta 441:117
Zhao H, Zhang YZ, Yuan ZB (2002) Anal Chim Acta 454:75
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Mülazımoğlu, A.D., Mülazımoğlu, İ.E. Electrochemical Properties of MDA/GC Electrode and Investigation of Usability as Sensor Electrode for Determination of Que, Kae, Lut and Gal Using CV, DPV and SWV. Food Anal. Methods 6, 141–147 (2013). https://doi.org/10.1007/s12161-012-9426-2
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DOI: https://doi.org/10.1007/s12161-012-9426-2