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Catalytic Packed-Bed Reactor Configuration for Biodiesel Production Using Waste Oil as Feedstock

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Abstract

Pumice, a natural porous silica material, exchanged with potassium is an efficient heterogeneous particulate catalytic material for triglycerides and free fatty acids transesterification reaction from sunflower oil and waste frying oil at low temperature. In this work, a packed-bed catalytic configuration reactor using this catalytic material was developed for biodiesel fuel production from sunflower oil and frying oil feedstock. Reactor operation variables as methanol/oil molar ratio, catalyst amount, reaction time, and reaction temperature were studied. Results were compared with those obtained from the same transesterification reaction proceeding in a slurry batch reactor. The packed-bed catalytic reactor configuration can be useful in order to minimize catalyst mechanical damage occurring in the slurry reactor due to continuous stirring. The possibility of using a packed-bed reactor shows some advantages because the catalyst stays confined in the reactor bed and the reaction products can be easily separated, besides the mechanical stability of the catalyst particles is achieved.

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References

  1. Yu X, Wen Z, Lin Y, Tu S, Wang Z, Yan J (2010) Intensification of biodiesel synthesis using metal foam reactor. Fuel 89:3450–3456

    Article  CAS  Google Scholar 

  2. Georgogianni KG, Katsoulidis AK, Pomonis PJ, Manos G, Kontominas MG (2009) Transesterification of rapeseed oil for the production of biodiesel using homogeneous and heterogeneous catalysis. Fuel Process Technol 90:1016–1022

    Article  CAS  Google Scholar 

  3. Parlak A, Karabas H, Ayhan V, Yasar H, Soyhan HS, Ozsert I (2009) Comparison of the variables affecting the yield of tobacco seed oil methyl ester for KOH and NaOH catalysts. Energy Fuel 23:1818–1824

    Article  CAS  Google Scholar 

  4. Dias JM, Alvim-Ferraz MCM, Almeida MF (2008) Comparison of the performance of different homogeneous alkali catalysts during transesterification of waste and virgin oils and evaluation of biodiesel quality. Fuel 87:3572–3578

    Article  CAS  Google Scholar 

  5. Hsieh L, Kumar U, Wu JCS (2010) Continuous production of biodiesel in a packed-bed reactor using shell-core structural Ca(C3H7O3)2/CaCO3 catalyst. Chem Eng J 158:250–256

    Article  CAS  Google Scholar 

  6. Kusdiana D, Saka S (2004) Effects of water on biodiesel fuel production by supercritical methanol treatment. Bioresour Technol 91:289–295

    Article  PubMed  CAS  Google Scholar 

  7. Xie WL, Peng H, Chen LG (2006) Calcined Mg-Al hydrotalcites as solid base catalyst for methanolysis of soybean oil. J Mol Catal A Chem 246:24–32

    Article  CAS  Google Scholar 

  8. Xie W, Yang Z (2007) Ba-ZnO catalyst for soybean oil transesterification. Catal Lett 117:159–165

    Article  CAS  Google Scholar 

  9. Neri G, Rizzo G, De Luca L, Corigliano F, Arrigo I, Aricò AS et al (2008) Pt catalysts supported on zeolitized-pumice for the selective hydrogenation of campholenic aldehyde: a characterization and kinetic study. Appl Catal Gen 350:169–177

    Article  CAS  Google Scholar 

  10. Álvarez-Galván MC, Brito A, García-Álvarez FJ, De la Peña O’Shea VA, Borges ME, Pawelec B (2008) Catalytic behaviour of bifunctional pumice-supported and zeolite/pumice hybrid catalysts for n-pentane hydroisomerization. Appl Catal Gen 350:38–45

    Article  Google Scholar 

  11. Chuan XY, Hirano M, Inagaki M (2004) Preparation and photocatalytic performance of anatase-mounted natural porous silica, pumice, by hydrolysis under hydrothermal conditions. Appl Catal B Environ 51:255–260

    Article  CAS  Google Scholar 

  12. Gök A, Göde F, Türkaslan BE (2006) Synthesis and characterization of polyaniline/pumice (PAn/Pmc) composite. Mater Sci Eng B 133:20–25

    Article  Google Scholar 

  13. Gelbard G (2005) Organic synthesis by catalysis with ion-exchange resins. Ind Eng Chem Res 44:8468–8498

    Article  CAS  Google Scholar 

  14. Kiss M, Losonczi B, Morgos J, Rusznak I, Haklits I (1980) Study of alkylating reactions catalyzed by cation-exchange resins. J Chromatogr A 201:383–389

    Article  CAS  Google Scholar 

  15. Ni J, Meunier FC (2007) Esterification of free fatty acids in sunflower oil over solid acid catalyst using bath and packed bed-reactors. Appl Catal Gen 333:122–130

    Article  CAS  Google Scholar 

  16. Borges ME, Díaz L, Alvarez-Galván MC, Brito A (2011) High performance heterogeneous catalyst for biodiesel production from vegetal and waste oil at low temperature. Appl Catal B Environ 102:310–315

    Article  CAS  Google Scholar 

  17. Shibasaki-Kitakawa N, Honda H, Kuribayashi H, Toda T, Fukumura T, Yonemoto T (2007) Biodiesel production using anionic ion-exchange resin as heterogeneous catalyst. Bioresour Technol 98:416–421

    Article  PubMed  CAS  Google Scholar 

  18. Gelbard G, Brès O, Vargas RM, Vielfaure F, Schuchardt UF (1995) 1H nuclear magnetic resonance determination of the yield of the transesterification of rapeseed oil with methanol. J Am Oil Chem Soc 72:1239–1241

    Article  CAS  Google Scholar 

  19. Borges ME, Díaz L, Gavín J, Brito A (2011) Estimation of the content of fatty acid methyl esters (FAME) in biodiesel samples from dynamic viscosity measurements. Fuel Process Technol 92:597–599

    Article  CAS  Google Scholar 

  20. Liu H, Su L, Liu F, Li C, Solomon U (2011) Cinder supported K2CO3 as catalyst for biodiesel production. Appl Catal B Environ 106:550–558

    Article  CAS  Google Scholar 

  21. Chiu C, Goff M, Suppes G (2005) Distribution of methanol and catalysts between biodiesel and glycerin phases. AICHE J 51(4):1274–1278

    Article  CAS  Google Scholar 

  22. Martín Alonso D, Mariscal R, Moreno-Tost R, Zafra Poves MD, López Granados M (2007) Potassium leaching during triglyceride transesterification using K/γ-Al2O3 catalysts. Catal Commun 8:2074–2080

    Article  Google Scholar 

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Acknowledgments

The authors acknowledge a research grant support by Programa de FPU del Ministerio de Educación, Spain.

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Authors and Affiliations

  1. Chemical Engineering Department, University of La Laguna, Avda. Astrofísico Fco. Sánchez s/n, La Laguna, Tenerife, Canary Island, 38200, Spain

    M. E. Borges & L. Díaz

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  1. M. E. Borges
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  2. L. Díaz
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Correspondence to M. E. Borges.

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Borges, M.E., Díaz, L. Catalytic Packed-Bed Reactor Configuration for Biodiesel Production Using Waste Oil as Feedstock. Bioenerg. Res. 6, 222–228 (2013). https://doi.org/10.1007/s12155-012-9246-7

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  • DOI: https://doi.org/10.1007/s12155-012-9246-7

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