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Development and characterization of copper doped perovskite-polymer composite through high-temperature technique

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Abstract

Ceramic powders of Cu doped lead Titanate (Pb0.5Cu0.5TiO3) are synthesized through a solid-state reaction method at high-temperature. Different percentage of ceramic filler into the polymer matrix was prepared by solution casting techniques. The structural studies of this polymeric composite were characterized by the X-ray diffraction technique and a tetragonal phase was found. Moreover, the surface morphology of this material was done by scanning electron microscopy. The impedance studies of this polymeric composite were characterized by an LCR meter between the frequencies range 102 and106 Hz. The modulus study of the material was done between the frequency ranges 102 and106 Hz. The variation of ac conductivity with frequency at different temperatures satisfied Jonscher’s universal power law.

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Abbreviations

K:

Kelvin

k:

Kilo (103)

ε* :

Complex permitivity

Z* :

Complex impedance

°C:

Degree celcius

\(D\) :

Crystallite size

K:

Shape factor (constant) = 0.89

\(\theta\) :

Diffraction angle

\(\lambda\) :

Wavelength = 1.5406 Å

\(\beta_{1/2}\) :

Full width of the reflection at half of the maximum intensity

Å:

Angstrom

\(\varepsilon\) :

Microstrain

\(\delta \) :

Dislocation density

ε r :

Dielectric constant

tanδ:

Dielectric loss

Z′:

Real part of the impedance

Z″:

Imaginary part of the impedance

M′:

Real part of the impedance

M″:

Imaginary part of the impedance

\({\sigma }_{ac}\) :

AC conductivity

\({\varepsilon }_{0}\) :

Absolute permitivity

\({\varepsilon }_{r}\) :

Relative permitivity

\(\omega \) :

Frequency

\({\sigma }_{dc}\) :

DC conductivity

\(A\) :

The temperature pre-exponential factor

n:

The dimensionless exponent

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Authors and Affiliations

  1. Centurion University of Technology and Management, Bhubaneswar, Odisha, India

    Priyambada Mallick, Rashmiranjan Patra & Santosh Ku. Satpathy

  2. Yuan Ze University, Taoyuan City, Taiwan

    Debabrata Mohanty

Authors
  1. Priyambada Mallick
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  2. Rashmiranjan Patra
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  3. Debabrata Mohanty
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  4. Santosh Ku. Satpathy
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Correspondence to Santosh Ku. Satpathy.

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Mallick, P., Patra, R., Mohanty, D. et al. Development and characterization of copper doped perovskite-polymer composite through high-temperature technique. Sādhanā 47, 134 (2022). https://doi.org/10.1007/s12046-022-01904-4

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