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Study on the structural, optical and dielectric properties of lead tin sulphide nanocrystals

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Abstract

In this work, a study was done on the structural, optical and dielectric properties of lead tin sulphide (PbSnS) nanocrystals and their thin films, which have got wide range of applications in photovoltaic systems. The nanocrystals of PbSnS were prepared by employing colloidal synthesis technique in which cubic PbSnS were obtained apart from the commonly found orthorhombic form. Nanocrystals of 5.84 nm were obtained which had a high band gap of 3.76 eV and Urbach energy of 0.163 eV. Almost 100% transmittance in the wavelength range of 300–800 nm was found. Nanocrystal thin films of PbSnS were prepared using successive ionic layer adsorption and reaction (SILAR) technique. The preparation of thin film samples by varying the amounts of complexing agent has been investigated. By varying the amount of complexing agents, the crystalline phase changed from cubic to orthorhombic. The lattice strain and dislocation density were found to be lower for the cubic phase. All the samples had high absorption coefficient in the ultraviolet region confirming that the thin films were composed of nanocrystals. There was an increase in transmittance from 60% to 80% with the increase of complexing agent. All the samples had high band gap, high refractive index and large surface roughness which make these PbSnS nanocrystal thin films suitable materials for window layer of solar cells. The cubic and mixed phase structured thin films behaved as polar dielectrics which can find potential applications in the design of efficient capacitors too.

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References

  1. A J Ragina, K V Murali, K C Preetha, K Deepa and T L Remadevi. J. Mater. Sci.: Mater. Electron. 23(12), 2264 (2012)

    Google Scholar 

  2. K C Preetha and T L Remadevi, J. Mater. Sci.: Mater. Electron. 25(4), 1783 (2014)

    Google Scholar 

  3. C E Pérez-García, S Meraz-Dávila, G Arreola-Jardón, F de Moure-Flores, R Ramírez-Bon and Y V Vorobiev, Mater. Res. Exp. 7(1), 015530 (2020)

    Article  Google Scholar 

  4. T V Beatriceveena, E Prabhu, V Jayaraman and K I Gnanasekar, Mater. Lett. 238, 324 (2019)

    Article  Google Scholar 

  5. Rosario, S Rex, I Kulandaisamy, K Deva Arun Kumar, A M S Arulanantham, S Valanarasu, Maha A Youssef and Nasser S Awwad, Physica B 575, 411704 (2019)

  6. Fekadu Gashaw Hone and Francis Birhanu Dejene, Inorg. Chem. Commun. 111, 107583 (2020)

    Article  Google Scholar 

  7. Chrysoula Ioannidou, Christos B Lioutas, Nikolaos Frangis, Steven N Girard and Mercouri G Kanatzidis, Chem. Mater. 28(11), 3771 (2016)

    Article  Google Scholar 

  8. Jian Zhang, Yang Ye, Chao Li, Jun Yang, Huiwen Zhao, Xiaoxuan Xu, Rong Huang, Lin Pan, Chunhua Lu and Yifeng Wang, J. Alloys Compd 696, 1342 (2017)

    Article  Google Scholar 

  9. Kane Norton et al, Chem. Sci. 10(9), 2843 (2019)

  10. T A Kuku, S O Azi and O Osasona, J. Mater. Sci. 41(4), 1067 (2006)

    Article  ADS  Google Scholar 

  11. S A Bashkirov, V F Gremenok, V A Ivanov, K Bente, P P Gladyshev, T Yu Zelenyak, A M Saad and M S Tivanov, Thin Solid Films 616, 773 (2016)

    Article  ADS  Google Scholar 

  12. Juan Fang, Debesh Devadutta Mishra, Weiquan Cai and Guolong Tan, Mater. Sci. Semicond. Process. 68, 58 (2017)

    Article  Google Scholar 

  13. B Thangaraju and P Kaliannan, J. Exp. Ind. Crystallogr. 35(1), 71 (2000)

    Google Scholar 

  14. A M Salem and M O Abou-Helal, Mater. Chem. Phys. 80(3), 740 (2003)

    Article  Google Scholar 

  15. Ronald B Soriano, Christos D Malliakas, Jinsong Wu and Mercouri G Kanatzidis, J. Am. Chem. Soc. 134(6), 3228 (2012)

  16. Gul Amin, M H Asif, Ahmed Zainelabdin, Siama Zaman, Omer Nur and Magnus Willander, J. Nanomater. 96, 2200 (2011)

  17. Fekadu Gashaw Hone and Francis Birhanu Dejene, J. Mater. Res. Technol. 8(1), 467 (2019)

    Article  Google Scholar 

  18. Md Azimul Haque and S Mahalakshmi, Mater. Focus 2(6), 469 (2013)

  19. Ming Du, Xuesong Yin and Hao Gong, Mater. Lett. 152, 40 (2015)

    Article  Google Scholar 

  20. Chengzhi Ruan, Jiahua Tao, Chengyun Zhu and Chen Chen, J. Mater. Sci.: Mater. Electron. 29(15), 12824 (2018)

    Google Scholar 

  21. Hao Wei, Yanjie Su, Shangzhi Chen, Yang Lin, Zhi Yang, Huai Sun and Yafei Zhang, CrystEngComm 13(22), 6628 (2011)

    Article  Google Scholar 

  22. Charles Kittel, Paul McEuen and Paul McEuen, Introduction to solid state physics (Wiley, New York, 1996) Vol. 8

  23. Jariya Rakspun, Nathakan Kantip, Veeramol Vailikhit, Supab Choopun and Auttasit Tubtimtae, J. Phys. Chem. Solids 115, 103 (2018)

    Article  ADS  Google Scholar 

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Acknowledgements

The authors thank STIC Cochin for the XRD and UV analyses, NCESS, Trivandrum for the SEM analysis and KUSICC, Kariavattom campus, Kerala University for the ellipsometric analyses. The authors also thank the University Grants Commission for the Junior Research Fellowship for the successful completion of this project.

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Authors and Affiliations

  1. Department of Physics, Payyannur College, Kannur,  670 327, India

    Maya Mathew & K C Preetha

  2. Sree Narayana College, Varkala, Thiruvananthapuram,  695 141, India

    K C Preetha

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  1. Maya Mathew
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  2. K C Preetha
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Correspondence to K C Preetha.

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Mathew, M., Preetha, K.C. Study on the structural, optical and dielectric properties of lead tin sulphide nanocrystals. Pramana - J Phys 95, 174 (2021). https://doi.org/10.1007/s12043-021-02200-2

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  • DOI: https://doi.org/10.1007/s12043-021-02200-2

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