Skip to main content
SpringerLink
Log in

Solvent-dependent Raman study of ethyl acetate and N,N-dimethyl formamide in methanol and carbon tetrachloride

  • Published:
Pramana Aims and scope Submit manuscript

Abstract

Raman spectra corresponding to C=O stretching mode of ethyl acetate (\(\hbox {C}_{{4}}\hbox {H}_{{8}}\hbox {O}_{{2}}\)) and N,N-dimethyl formamide (\(\hbox {C}_{3}\hbox {H}_{7}\hbox {NO}\)) in methanol (\(\hbox {CH}_{3}\hbox {OH}\)) and carbon tetrachloride (\(\hbox {CCl}_{{4}}\)) solvents were investigated in the region 1600–\(1800~\hbox {cm}^{{-1}}\). The variations of bandwidths corresponding to isotropic and anisotropic components of the C\(=\)O stretching mode with varying solvent concentration were discussed using different mechanisms. The variation in the vibrational and reorientational correlation times with concentration have been explained in terms of self-association, diffusion mechanism, formation of hydrogen bond and screening effect. The Onsager–Fröhlich dielectric model on anisotropy shift has been tested. This model holds good for the solute–\(\hbox {CH}_{3}\hbox {OH}\) system. However, the exponential curve for the solute–\(\hbox {CCl}_{{4}}\) system shows repulsive type of intermolecular forces playing a vital role in such complex system.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. S Velsko and D W Oxtoby, J. Chem. Phys. 4, 72 (1980)

  2. D W Oxtoby, J. Phys. Chem. 87, 3028 (1983)

    Article  Google Scholar 

  3. M Musso, H Torii, M G Giorgini and G Döge, J. Chem. Phys. 110, 10076 (1999)

    Article  ADS  Google Scholar 

  4. P Mirone and G Fini, J. Chem. Phys. 71, 2241 (1979)

    Article  ADS  Google Scholar 

  5. Th G Devi, A Das and K Kumar, Spectrochim. Acta A 60, 211 (2004)

    Article  ADS  Google Scholar 

  6. Th G Devi and K Kumar, J. Raman Spectrosc. 35, 835 (2004)

    Article  ADS  Google Scholar 

  7. Th G Devi and K Kumar, Spectrochim Acta A 62, 972 (2005)

    Article  ADS  Google Scholar 

  8. Th G Devi, J. Raman Spectrosc. 41, 1261 (2010)

    Article  ADS  Google Scholar 

  9. Th G Devi and G Upadhayay, Spectrochim. Acta A 91, 106 (2012)

  10. Th G Devi, Vib. Spectrosc. 75, 65 (2014)

    Article  Google Scholar 

  11. G Upadhayay and Th G Devi, J. Mol. Liq. 197, 263 (2014)

    Article  Google Scholar 

  12. G Upadhayay, P Upadhayay and Th G Devi, J. Raman Spectrosc. 46, 1291 (2015)

    Article  ADS  Google Scholar 

  13. P Upadhayay and Th G Devi, Vib. Spectrosc. 96, 110 (2018)

    Article  Google Scholar 

  14. M Musso, H Torii, M G Giorgini, G Döge and A Asenbaum, Mol. Phys. 92, 97 (1997)

    ADS  Google Scholar 

  15. A K Ojha, S K Srivastava, R K Singh and B P Asthana, J. Phys. Chem. A 110, 9849 (2006)

    Article  Google Scholar 

  16. A K Ojha, S K Srivastava, R K Singh, W Kiefer and B P Asthana, Vib. Spectrosc. 43, 177 (2007)

    Article  Google Scholar 

  17. A K Ojha, S K Srivastava, R K Singh, W Kiefer and B P Asthana, J. Raman Spectrosc. 38, 159 (2007)

    Article  ADS  Google Scholar 

  18. A Singh, D Gangopadhyay, R Nandi, P Sharma and R K Singh, J. Raman Spectrosc. 47, 712 (2016)

    Article  ADS  Google Scholar 

  19. D K Singh, S K Srivastava, P Raghuvansh, R K Singh and B P Asthana, Vib. Spectrosc. 56, 34 (2011)

    Article  Google Scholar 

  20. A Morresi, L Mariani, M R Distefano and M G Giorgini, J. Raman Spectrosc. 26, 179 (1995)

    Article  ADS  Google Scholar 

  21. V Ramakrishnan, A Sarua, M Kuball and A F Abdullah, J. Raman Spectrosc. 41, 320 (2010)

    Google Scholar 

  22. A F Bondarev and A I Mardaeva, Opt. Spectrosc. 35, 286 (1973)

    Google Scholar 

  23. E W Knapp and S F Fischer, J. Chem. Phys. 76, 4730 (1982)

    Article  ADS  Google Scholar 

  24. J Yarwood and R Arndt, IN. Mol. Assoc. London 2, 287 (1997)

    Google Scholar 

  25. A Purkayastha and K Kumar, J. Raman Spectrosc. 19, 249 (1988)

    Article  ADS  Google Scholar 

  26. A Purkayastha, R Das and K Kumar, Spectrochim. Acta A 46, 1545 (1990)

    Article  ADS  Google Scholar 

  27. A Das and K Kumar, Spectrochim. Acta A 54, 793 (1998)

    Article  ADS  Google Scholar 

  28. S Dutta and K Kumar, J. Raman Spectrosc. 36, 50 (2005)

    Article  ADS  Google Scholar 

  29. D Bhattacharjee, A Ghosh, T N Misra and S K Nandy, J. Raman Spectrosc. 27, 457 (1996)

    Article  ADS  Google Scholar 

  30. K Tanabe, Spectrochim. Acta A 40, 437 (1984)

    Article  ADS  Google Scholar 

  31. C H Wang and J Mchale, J. Chem. Phys. 72, 4039 (1980)

    Article  ADS  Google Scholar 

  32. J L McHale, J. Chem. Phys. 75, 30 (1981)

    Article  ADS  Google Scholar 

  33. G Tarjus and S Bratos, Mol. Phys. 42, 307 (1981)

    Article  ADS  Google Scholar 

  34. S Bratos and G Tarjus, Phys. Rev. A 24, 1591 (1981)

    Article  ADS  Google Scholar 

  35. S Bratos and G Tarjus, Can. J. Chem. 63, 2047 (1985)

    Article  Google Scholar 

  36. S Bratos and G Tarjus, Phys. Rev. A 32, 2431 (1985)

    Article  ADS  Google Scholar 

  37. R G Gordon, Adv. Magn. Reson. 3, 1 (1986)

    Article  Google Scholar 

  38. G Tarjus and S Bratos, Phys. Rev. A 34, 4202 (1986)

    Article  ADS  Google Scholar 

  39. H Torii, J. Chem. Phys. 119, 2192 (2003)

    Article  ADS  Google Scholar 

  40. D Yamini and V Ramakrishnan, Spectrochim. Acta A 111, 14 (2013)

    Article  ADS  Google Scholar 

  41. A K Ojha, S K Srivastava, R K Singh, W Kiefer and B P Asthana, Vib. Spectrosc. 43, 177 (2007)

    Article  Google Scholar 

  42. A K Ojha, S K Srivastava, B P Asthana and R K Singh, J. Raman Spectrosc. 38, 159 (2007)

    Article  ADS  Google Scholar 

  43. R K Singh, S K Srivastava, A K Ojha, U Arvind and B P Asthana, J. Raman Spectrosc. 37, 76 (2006)

    Article  ADS  Google Scholar 

  44. C M Muntean, L Bratu and A Hernanz, J. Phys. Chem. B 121, 6909 (2017)

  45. V M Shelly and J Yarwood, J. Chem. Phys. 137, 277 (1989)

    Google Scholar 

  46. M G Giorgini, Pure Appl. Chem. 76, 157 (2004)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Physics, North-Eastern Hill University, Shillong, 793 022, India

    Smriti Adhikari & S S Khatri

Authors
  1. Smriti Adhikari
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S S Khatri
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S S Khatri.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Adhikari, S., Khatri, S.S. Solvent-dependent Raman study of ethyl acetate and N,N-dimethyl formamide in methanol and carbon tetrachloride. Pramana - J Phys 95, 133 (2021). https://doi.org/10.1007/s12043-021-02159-0

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s12043-021-02159-0

Keywords

PACS Nos

Search

Navigation