Abstract
In-situ monitoring of silver nanoparticle formation was studied in thin films of polyvinyl alcohol and silver nitrate. We proposed the observation of surface-enhanced Raman spectroscopy (SERS) as a novel and simple technique to record the growth of silver nanoparticles in polyvinyl alcohol thin films. Observed enhancement in the Raman bands of polyvinyl alcohol is explained through the localized surface plasmon resonance of silver nanoparticles. Influence of temperature generated by silver nanoparticles on the formation of nanoparticles is also discussed.
Similar content being viewed by others
References
J Z Zhang and C Noguez, Plasmonics 3, 127 (2008)
E C LeRu and P G Etchegoin, Principles of surface enhanced Raman spectroscopy and related plasmonic effects (Elsevier, Amsterdam, 2009)
S Porel, S Singh, S S Harsha, D N Rao and T P Radhakrishnan, Chem. Mater. 17, 9 (2004)
J Zhang and C Noguez, Plasmonics 3, 127 (2008)
G Upender, R Satyavati, B Raju, K Shadak Alee, D Narayana Rao and C Bansal, Chem. Phys. Lett. 511, 309 (2011)
V Resta1, J Siegel, J Bonse, J Gonzalo, C N Afonso, E Piscopiello and G Van Tenedeloo, J. Appl. Phys. 100, 084311 (2006)
A C Sant’Ana, T C R Rocha, P S Santos, D Zanchet and M L A Temperini, J. Raman Spectr. 40, 183 (2009)
A D McFarland and R P Van Duyne, Nano Lett. 3, 1057 (2003)
J D Holmes, K P Johnston, R C Doty and B A Korgel, Science 287, 1471 (2000)
J Ouyang, C-W Chu, C R Szmanda, L Ma and Y Yang, Appl. Phys. Lett. 3, 918 (2004)
J Ouyang, C-W Chu, D Sieves and Y Yang, Appl. Phys. Lett. 86, 123507 (2005)
F Hao, C L Nehl, J H Hafner and P Nordlander, Nano Lett. 7, 729 (2007)
S Krimm, C Y Liang and G B B M Sutherland, J. Polym. Sci. 22, 227 (1956)
S Porel, N Venkatram, D Narayana Rao and T P Radhakrishnan, J. Nanosci. Nanotechnol. 7, 1 (2007)
S Kai, W Chaozhi and X Guangzhi, Spectrochim. Acta Part A 45, 1029 (1989)
C Y Panicker, H T Varghese, D Philip and H I S Nogueira, Spectrochim. Acta 64, 744 (2006)
A Michota, A Kudelski and J Bukowska, Surf. Sci. 502, 214 (2002)
B G Oliver and G J Janz, J. Phys. Chem. 74, 3819 (1970)
D Roy and T E Furtack, Chem. Phys. Lett. 124, 299 (1986)
A O Govorov, W Zhang, T Skeini, H Richardson, J Lee and N A Kotov, Nano. Res. Lett. 1, 84 (2006)
A O Govorov and H H Richardson, Nano Today 2, 30 (2007)
A Slistan-Grijalva, R Herrera-Urbinab, J F Rivas-Silvac, M Ávalos-Borjad, F F Castillón-Barrazad and A Posada-Amarillase, Physica E: Low-dimensional Systems and Nanostructures 27, 104 (2005)
G Krishna Bama, P Indra Devi and K Ramachandran, J. Mater. Sci. 44, 1302 (2009)
P Zijlstra, J W M Chon and M Gu, Opt. Express 15, 12151 (2007)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
ALEE, K.S., RAO, D.N. Time-dependent micro-Raman scattering studies of polyvinyl alcohol and silver nitrate thin films. Pramana - J Phys 82, 425–431 (2014). https://doi.org/10.1007/s12043-014-0701-1
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12043-014-0701-1