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A comparative simulation study on three lattice systems for the phase separation of polymer-dispersed liquid crystals

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Abstract

This article reports a comparative study of the phase separation process in a polymer-dispersed liquid crystal, based on a Metropolis Monte Carlo simulation study of three lattice systems. We propose a model for the different processes occurring in the formation of polymer-dispersed liquid crystals (PDLCs). The mechanism of PDLC is studied as a function of quench temperature, concentration and degree of polymerization of liquid crystals and polymers. The obtained resultant phase diagrams of the three systems are approximated and compared with the Flory-Huggins theory, and show a good agreement. It has been observed in the simulation results that among all the three systems, the 40 × 40 × 40 lattice showed the most accurate, reliable and stable results.

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Correspondence to M. Jamil.

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Jeon, Y.J., Jamil, M., Lee, HD. et al. A comparative simulation study on three lattice systems for the phase separation of polymer-dispersed liquid crystals. Pramana - J Phys 71, 559–572 (2008). https://doi.org/10.1007/s12043-008-0131-z

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  • DOI: https://doi.org/10.1007/s12043-008-0131-z

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