Abstract
The dielectric relaxation times τ jk ’s and dipole moments μ jk ’s of the binary (jk) polar liquid mixture of N,N-dimethyl acetamide (DMA) and acetone (Ac) dissolved in benzene (i) are estimated from the measured real σ′ ijk and imaginary σ″ ijk parts of complex high frequency conductivity σ* ijk of the solution for different weight fractions w jk ’s of 0.0, 0.3, 0.5, 0.7 and 1.0 mole fractions x j of Ac and temperatures (25, 30, 35 and 40°C) respectively under 9.88 GHz electric field. τ jk ’s are obtained from the ratio of slopes of σ″ ijk -w jk and σ′ ijk -w jk curves at w jk → 0 as well as linear slope of σ″ ijk -σ′ ijk curves of the existing method (Murthy et al, 1989) in order to eliminate polarpolar interaction in the latter case. The calculated τ’s are in excellent agreement with the reported τ’s due to Gopalakrishna’s method. μ jk ’s are also estimated from slopes β’s of total conductivity σ ijk -w jk curves at w jk → 0 and the values agree well with the reported μ’s from G.K. method. The variation of τ jk ’s and μ jk ’s with x j of Ac reveals that solute-solute molecular association occurs within 0.0–0.3x j of Ac beyond which solute-solvent molecular association is predicted. The theoretical dipole moments μ theo’s are calculated from bond angles and bond moments to have exact μ’s only to show the presence of inductive, mesomeric and electromeric effects in the substituent polar groups. The thermodynamic energy parameters are estimated from ln(τ jk T) against 1/T linear curve from Eyring’s rate theory to know the molecular dynamics of the system and to establish the fact that the mixture obeys the Debye-Smyth relaxation mechanism.
Similar content being viewed by others
References
A K Sharma and D R Sharma, J. Phys. Soc. (Japan) 53, 4771 (1984)
V S Rangra and D R Sharma, Indian J. Phys. B78(I), 111 (2004)
N Nandi, K Bhattacharyya and B Bagchi, Chem. Rev. 100, 2013 (2000)
A K Jonscher, Physics of dielectric solids, invited paper edited by CHL Goodman, 1980
A Schallamach, Trans. Faraday Soc. A42, 180 (1946)
E Frost and C P Smyth, J. Phys. Chem. Ithaca 69, 1294 (1965)
A K Chatterjee, U Saha, N Nandi, R C Basak and S Acharyya, Indian J. Phys. B66, 291 (1992)
V S Rangra and D R Sharma, Indian J. Pure Appl. Phys. 41, 630 (2003)
J J Lagowski, The chemistry of non-aqueous solvents (Academic Press, New York and London, 1966)
G R Ueader and J F Gormley, J. Am. Chem. Soc. 73, 5731 (1951)
A K Sharma and D R Sharma, J. Phys. Soc. (Japan) 61, 1049 (1992)
S Sahoo, K Dutta, S Acharyya and S K Sit, Indian J. Pure Appl. Phys. 45, 529 (2007)
S K Sit, K Dutta, S Acharyya, T Pal Majumder and S Roy, J. Mole. Liquids 89, 111 (2000)
N E Hill, W E Vaughan, A H Price and M Davies, Dielectric properties and molecular behaviour (Van Nostrand Reinhold, London, 1969)
M B R Murthy, R L Patil and D K Deshpande, Indian J. Phys. B63, 491 (1989)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Sahoo, S., Dutta, K., Acharyya, S. et al. Dielectric relaxation of binary polar liquid mixture measured in benzene at 10 GHz frequency. Pramana - J Phys 70, 543–552 (2008). https://doi.org/10.1007/s12043-008-0069-1
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12043-008-0069-1