Abstract
The rare-earth and actinide based compounds are endowed with several exotic physical and chemical properties due to the presence of f-electrons. These properties exhibit interesting changes under the action of various thermodynamic fields and hence continues to be a subject of extensive research. For instance, under pressure, the nature of f-electrons can be changed from localized to itinerant, leading to a variety of changes in their structural, physical and chemical properties. The present review on the high pressure phase transition behaviour of dialuminides of rare earths and actinides is an outcome of research in our laboratory during the last five years using a unique combination of a Guinier diffractometer and a diamond anvil cell built in-house. To bring out the correlations between the compressibility and structural behaviour with the electronic structure, we have also carried out electronic structure calculation. Further, the usefulness of Villars’ three parameter structure maps in predicting pressure induced structural transitions has been explored and this has been illustrated with the available phase transition data.
Similar content being viewed by others
References
A Jayaraman, Rev. Mod. Phys. 55, 65 (1983)
J V Badding, L J Parker and D C Nesting, J Solid State Chem. 117, 229 (1995)
U Benedict, in Handbook on the Physics and Chemistry of Actinides edited by A J Freeman and G H Lander (North Holland, Amsterdam, 1987) vol. 5, p. 227
U Benedict and W B Holzapfel, in Handbook on the Physics and Chemistry of Rare Earths edited by K A Gschneidner Jr, L Eyring, G H Lander and G R Choppin (Elsevier, Amsterdam, 1993) vol. 17, p. 245
P Ch Sahu, N V Chandra Shekar, N Subramanian, Mohammad Yousuf and K Govinda Rajan, in Advances in High Pressure Research in Condensed Matter edited by S K Sikka, S C Gupta and B K Godwal (NISCOM, New Delhi, 1997) p. 187
A K McMohan, Physica B139/140, 31 (1986), J Less Common Metals 147, 1 (1987)
H Tups, K Takemura and K Syassen, Phys. Rev. Lett. 49, 1776 (1982)
A Jayaraman, in Handbook on the Physics and Chemistry of Rare Earths edited by K A Gschneidner Jr and L Eyring (North Holland, Amsterdam, 1979) vol. 2, p. 575
K Takemura, in International Conference on High Pressure Science and Technology, AIRAPT-17, 25–30 July 1999, Honolulu, Hawaii, p. 169
B Johansson and M S S Brooks, in Handbook on the Physics and Chemistry of Rare Earths edited by K A Gschneidner Jr, L Eyring, G H Lander and G R Choppin (Elsevier, Amsterdam, 1993) vol. 17, p.1
M S S Brooks, B Johansson and H L Skriver, in Handbook on the Physics and Chemistry of the Actinides edited by A J Freeman and G H Lander (North Holland, Amsterdam, 1984) vol. 1, p. 153
J M Fournier and R Troc, in Handbook on the Physics and Chemistry of the Actinides edited by A J Freeman and G H Lander (North-Holland, Amsterdam, 1985) vol. 2, p. 29
K Govinda Rajan, Current Science 53, 1115 (1984)
B Johansson, J. Alloys and Compounds 223, 211 (1995)
N V Chandra Shekar, P Ch Sahu, Mohammad Yousuf and K Govinda Rajan, Phys. Rev. B55, 745 (1997)
P Ch Sahu, N V Chandra Shekar, N Subramanian, Mohammad Yousuf and K Govinda Rajan, J. Alloys and Compounds 223, 49 (1995)
P Ch Sahu, N V Chandra Shekar, N Subramanian, Mohammad Yousuf and K Govinda Rajan, High Press. Res. 13, 295 (1995)
J P Itie, J Staun Olsen, L Gerward, U Benedict and J C Spirlet, Physica B139–140, 330 (1986)
N V Chandra Shekar, P Ch Sahu, Mohammad Yousuf, K Govinda Rajan and M Rajagopalan, Solid State Commun. 111, 529 (1999)
N V Chandra Shekar, P Ch Sahu, Mohammad Yousuf and K Govinda Rajan, (unpublished)
H Bartholin, F Kervella, A Waintal, G Parisot and J P Senateur, Phys. Status Solidi A6, K87 (1980)
U Schwarz, S Brauninger, Yu Grin and K Syassen, J. Alloys and Compounds 245, 23 (1996)
P Villars, K Mathis and F Hulliger, in The Structures of Binary Compounds edited by F R De Boer and D G Pettifor (North Holland, Amsterdam, 1989) p. 1
P Ch Sahu, Mohammad Yousuf, N V Chandra Shekar, N Subramanian and K Govinda Rajan, Rev. Sci. Instrum. 66, 2599 (1995)
Mohammad Yousuf, in High Pressure in Semiconductor Physics II, Semiconductors and Semimetals edited by T Suski and W Paul (Academic Press, San Diego, 1998) vol. 55, ch. 7, p. 381
R Deivasigamani, N Gunasegaran, N Easwaran, Mohammad Yousuf, K V Thomaskutty, P Ch Sahu, N V Chandra Shekar, N Subramanian and K Govinda Rajan, in Advances in High Pressure Science and Technology edited by A K Singh (Tata Mc-Graw Hill, New Delhi, 1995) p. 381
L Liu and W A Bassett, J. Appl. Phys. 44, 1475 (1973)
H K Mao, P M Bell, J W Shaner and D J Steinberg, J. Appl. Phys. 49, 3276 (1978)
J D Barnett, S Block and G J Piermarini, Rev. Sci. Instrum. 44, (1973)
G J Piermarini, S Block, J D Barnett and R A Forman, J Appl. Phys. 46, 2774 (1975)
P M Bell, J Xu and H K Mao, in Shock Waves in Condensed Matter edited by Y M Gupta (Plenum, New York, 1986) p. 125
N Subramanian, N V Chandra Shekar, P Ch Sahu, Mohammad Yousuf and K Govinda Rajan, Phys. Rev. B58, R555 (1998)
J M Fournier, Solid State Commun. 29, 111 (1979)
J M Fournier and E Gratz, in Handbook on the Physics and Chemistry of Rare Earths edited by K A Gschneidner Jr, L Eyring, G H Lander and G R Choppin (North-Holland, Amsterdam, 1993) vol. 17, p. 409
R J Trainor, M B Brodsky and H V Culbert, Phys. Rev. Lett. 34, 1019 (1975)
J M Fournier and J Beille, J. de Phys. C4, 145 (1979)
K H J Buschow and H J van Daal, AIP Conf. Proc. 5, 1464 (1972)
A J Arko, M B Brodsky and W J Nellis, Phys.Rev. B5, 4564 (1972)
A J Arko, M B Brodsky and W J Nellis, Bull. Am. Phys. Soc. 15, 293 (1970)
H H Hill, in Plutonium 1970 and other actinides edited by W N Miner (Metallurgical Society of AIME, New York, 1970) p. 2
R Naegele, L Manes, J C Spirlet, L Pellegrini and J M Fournier, Physica B+C102, 122 (1980)
J R Naegele, L Manes and J C Spirlet, Appl. Surf. Sci. 4, 510 (1980)
W Potzel, High Press. Res. 2, 367 (1990) and the references cited therein
D D Koelling, B D Dunlop and C W Crabtree, Phys. Res. B31, 4996 (1985)
M H Van Maaren, H J van Daal, K H J Buschow and C J Schinkel, Solid State Commun. 14, 145 (1974)
A Mielke, W W Kim, G Fraunberger and G R Stewart, J. Alloys and Compounds 189, 123 (1992)
J M Fournier, Physica B130, 268 (1985)
M S Wire, J D Thompson and Z Fisk, Phys. Rev. B30, 5591 (1984)
N V Chandra Shekar, P Ch Sahu, M Rajagopalan, Mohammad Yousuf and K Govinda Rajan, J. Phys. Condens. Matter 9, 5867 (1997)
U Benedict, J. Alloys and Compounds 223, 216 (1995)
F D Murnaghan, Am. J. Math. 59, 235 (1937)
F Birch, Phys. Rev. 71, 809 (1947); J. Geophys. Res. 57, 227 (1962)
W B Holzapfel, High Press. Res. 16, 81 (1998)
J M Fournier and L Manes, in Actinides-Chemistry and Physical Properties-Structure and Bonding edited by L Manes (Springer-Verlag, Berlin, 1985) vol. 59/60, p. 1
U von Barth and L Hedin, J. Phys. C5, 1629 (1972)
S Y Savrasov, Phys. Rev. B54, 16470 (1996)
M Methfessel, Phys. Rev. B38, 1537 (1988)
A J Arko, D D Koelling and J E Schirber, in Hand book of Physics and Chemistry of Actinides edited by A J Freeman and G H Lander (Netherlands, Amsterdam, 1995) vol. 2, p. 175
K H J Buschow, Rep. Prog. Phys. 40, 1179 (1977); 42, 1373 (1979)
J M Fournier, in Actinides-Chemistry and Physical Properties — Structure and Bonding edited by L Manes (Springer, Berlin, 1985) vol. 59/60, p. 127
A Slebarski, J. Magn. Magn. Mater. 66, 107 (1987)
Y Komura and K Tokunaga, Acta Cryst. 36, 1548 (1980)
Y Komura, Acta Cryst. 15, 770 (1962)
B G Hyde and S Andersson, in Inorganic Crystal Structure (John Wiley, New York, 1989)
F Laves and H White, Metallwirtsch Metallwiss. Metalltech. 14, 645 (1935); 15, 840 (1936)
R P Elliot and W Rostoker, Trans. Am. Soc. Met. 50, 617 (1958).
P Villars, J. Less-Common Met. 92, 215 (1983)
P Villars, J. Less Common Metals 92, 215 (1983)
J F Cannon, D L Robertson, H T Hall and A C Lawson, J. Less-Common Met. 31, 174 (1973)
P Villars and L D Calvert, in Pearson’s Handbook of Crystallographic Data for Intermetallic Phases (ASM, Metals Park, 1991) vol. 1–4
B K Godwal, V Vijayakumar, S K Sikka and R Chidambaram, Physica 144, 44 (1986); J. Phys. F16, 1415 (1986)
S Lee, J. Am. Chem. Soc. 113, 101 (1991)
H J van Daal and K H J Buschow, Solid State Commun. 7, 217 (1969)
For example, see the papers in Valence Instabilities and Related Narrow-Band Phenomena edited by R D Parks (Plenum Press, New York, 1977)
T G Ramesh and W B Holzapfel, Pramana — J. Phys. 29, 183 (1987)
M Croft and A Jayaraman, Solid State Commun. 29, 9 (1979)
I Vedel, A M Redo, J M Leger, J M Mignot and J Flouquet, J. Magn. Magn. Mater. 54–57, 361 (1986)
B K Godwal, A Jayaraman, S Meenakshi, R S Rao, S K Sikka, and V Vijayakumar, Phys. Rev. B57, 773 (1998)
I M Lifshitz, Sov. Phys. JETP 11, 1130 (1960)
J Zankert, U Potzel, J Moser, W Potzel, T Obenhuber, M Wunsch, G M Kalvius, J Gal and U Benedict, High Temp.-High Press. 16, 533 (1984)
V I Makarow and V G Barlyakhtar, Sov. Phys. JETP 21, 1151 (1965)
C W Chu, T F Smith and W E Gardner, Phys. Rev. B1, 214 (1970)
M Rajagopalan, M Alouani and N E Christensen, J. Low Temp. Phys. 75, 1 (1989)
D G Pettifor, in Solid State Physics edited by H Ehrenreich and D Turnbull (Academic Press, New York, 1987) p. 43
D G Pettifor, New Scientist 29, 48 (1986); J. Phys. C19, 285 (1986)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Sahu, P.C., Chandra Shekar, N.V. Pressure induced phase transition behaviour in f-electron based dialuminides. Pramana - J Phys 54, 685–708 (2000). https://doi.org/10.1007/s12043-000-0115-0
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/s12043-000-0115-0