Abstract
The sorption of uranium onto mullite influenced by pH, initial adsorbate concentration, sorption dose and reaction duration was probed utilising batch techniques. X-ray powder diffraction was used to characterise mullite. Sorption isotherms, sorption kinetics and thermodynamic characteristics were also investigated. The Freundlich isotherm model could best depict experimental data, suggesting that the sorption mechanism of uranium onto mullite may be multi-layer adsorption. The E value obtained from the Dubinin–Radushkevich model implied that uranium sorption onto mullite is a chemical process. The pseudo-second-order model successfully depicted uranium sorption onto mullite, indicating that the sorption rate is mainly controlled by chemical sorption. The thermodynamic parameters computed showed that entropy and enthalpy under the trial conditions were positive and that values of ΔGϴ were negative. Thermodynamics illustrated that the sorption process was endothermic and spontaneous. The results achieved in this study are intended to further a deeper comprehension of uranium migration in silicate minerals.
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References
Aytas S, Yurtlu M and Donat R 2009 Adsorption characteristic of U(VI) ion onto thermally activated bentonite; J. Hazards Mater. 172(2–3) 667–674, https://doi.org/10.1016/j.jhazmat.2009.07.049.
Castelein O, Soulestin B, Bonnet J P and Blanchart P 2001 The influence of heating rate on the thermal behaviour and mullite formation from a kaolin raw material; Ceram. Int. 27(5) 517–522, https://doi.org/10.1016/S0272-8842(00)00110-3.
Chisholm-Brause C J, Berg J M, Matzner R A and Morris D E 2001 Uranium(VI) sorption complexes on montmorillonite as a function of solution chemistry; J. Colloid Interface Sci. 233(1) 38–49, https://doi.org/10.1006/jcis.2000.7227.
Clark D L, Conradson S D, Donohoe R J, Keogh D W, Morris D E, Palmer P D, Rogers R D and Tait C D 1999 Chemical speciation of the uranyl ion under highly alkaline conditions. Synthesis, structures, and oxo ligand exchange dynamics; Inorg. Chem., https://doi.org/10.1021/ic981137h.
Crawford S E, Lofts S and Liber K 2017 The role of sediment properties and solution PH in the adsorption of uranium (VI) to freshwater sediments; Environ. Pollut. 220 873–881, https://doi.org/10.1016/j.envpol.2016.10.071.
Cumberland S A, Douglas G, Grice K and Moreau J W 2016 Uranium mobility in organic matter-rich sediments: A review of geological and geochemical processes; Earth-Sci. Rev. 159 160–185, https://doi.org/10.1016/j.earscirev.2016.05.010.
Ding D, Fu P, Li L, Xin X, Hu N and Li G 2014 U(VI) ion adsorption thermodynamics and kinetics from aqueous solution onto raw sodium feldspar and acid-activated sodium feldspar; J. Radioanal. Nucl. Chem. 299(3) 1903–1909, https://doi.org/10.1007/s10967-013-2903-2.
Du Y, Yin Z, Wu H, Li P, Qi W and Wu W 2015 Sorption of U(VI) on magnetic illite: Effects of pH, ions, humic substances and temperature; J. Radioanal. Nucl. Chem. 304(2) 793–804, https://doi.org/10.1007/s10967-014-3893-4.
Fatima H, Djamel N, Samira A and Mahfoud B 2013 Modelling and adsorption studies of removal uranium(VI) ions on synthesised zeolite NaY; Desalination Water Treat., https://doi.org/10.1080/19443994.2013.769756.
Freimann S and Rahman S 2001 Refinement of the real structures of 2:1 and 3:2 mullite; J. Eur. Ceram. Soc. 21(14) 2453–2461.
Ganesh R, Robinson K G, Chu L, Kucsmas D and Reed G D 1999 Reductive precipitation of uranium by Desulfovibrio Desulfuricans: Evaluation of cocontaminant effects and selective removal; Water Res. 33(16) 3447–3458, https://doi.org/10.1016/S0043-1354(99)00024-X.
Gao X, Bi M, Shi K, Chai Z and Wu W 2017 Sorption characteristic of uranium(VI) ion onto K-feldspar; Appl. Radiat. Isot. 128 311–317, https://doi.org/10.1016/j.apradiso.2017.07.041.
Griesser K J, Beran A, Voll D and Schneider H 2008 Boron incorporation into mullite; Mineral. Petrol. 92(3–4) 309–320, https://doi.org/10.1007/s00710-007-0210-8.
Huang Y, Zheng C and Xie C 1998 Study on the preparation and structure of mullite membrane; J. Inorg. Mater. 16(3) 555–558.
Kulkarni P S 2003 Recovery of uranium(VI) from acidic wastes using Tri-n-octylphosphine oxide and sodium carbonate based liquid membranes; Chem. Eng. J. 92(1–3) 209–214, https://doi.org/10.1016/S1385-8947(02)00255-3.
Li S Y, Xie S B, Zhao C, Zhang Y P, Liu J X and Cai T 2013 Efficiency of adsorption of wastewater containing uranium by fly ash; Adv. Mater. Res. 639–640 1295–1299, https://doi.org/10.4028/www.scientific.net/AMR.639-640.1295.
Lima A T, Ottosen L M and Ribeiro A B 2012 Assessing fly ash treatment: Remediation and stabilization of heavy metals; J. Environ. Manage. 95(Suppl) S110–S115, https://doi.org/10.1016/j.jenvman.2010.11.009.
Mellah A, Chegrouche S and Barkat M 2006 The removal of uranium(VI) from aqueous solutions onto activated carbon: Kinetic and thermodynamic investigations; J. Colloid Interface Sci. 296(2) 434–441, https://doi.org/10.1016/j.jcis.2005.09.045.
Michard P, Guibal E, Vincent T and Le Cloirec P 1996 Sorption and desorption of uranyl ions by silica gel: pH, particle size and porosity effects; Microporous Mater. 5(5) 309–324, https://doi.org/10.1016/0927-6513(95)00067-4.
Monnet A, Gabriel S and Percebois J 2017 Long-term availability of global uranium resources; Resour. Policy 53 394–407, https://doi.org/10.1016/j.resourpol.2017.07.008.
Nekhunguni P M, Tavengwa N T and Tutu H 2017 Sorption of uranium(VI) onto hydrous ferric oxide-modified zeolite: Assessment of the effect of pH, contact time, temperature, selected cations and anions on sorbent interactions; J. Environ. Manage. 204 571–582, https://doi.org/10.1016/j.jenvman.2017.09.034.
Pu Y, Yang X, Zheng H, Wang D, Su Y and He J 2013 Adsorption and desorption of thallium(I) on multiwalled carbon nanotubes; Chem. Eng. J. 219 403–410, https://doi.org/10.1016/j.cej.2013.01.025.
Reinoso-Maset E and Ly J 2016 Study of uranium(VI) and radium(II) sorption at trace level on kaolinite using a multisite ion exchange model; J. Environ. Radioact. 157 136–148. https://doi.org/10.1016/j.jenvrad.2016.03.014.
Ren X, Wang S, Yang S and Li J 2010 Influence of contact time, pH, soil humic/fulvic acids, ionic strength and temperature on sorption of U(VI) onto MX-80 bentonite; J. Radioanal. Nucl. Chem. 283(1) 253–259, https://doi.org/10.1007/s10967-009-0323-0.
Rüscher C H 1996 Phonon spectra of 2:1 mullite in infrared and Raman experiments; Phys. Chem. Min. 50–55, https://doi.org/10.1007/BF00202993.
Schneider H, Schreuer J and Hildmann B 2008 Structure and properties of mullite – A review; J. Eur. Ceram. Soc. 28(2) 329–344, https://doi.org/10.1016/j.jeurceramsoc.2007.03.017.
Singh S K, Tripathi S C and Singh D K 2010 Studies on the separation and recovery of uranium from phosphoric acid medium using a synergistic mixture of (2-ethylhexyl)phosphonic acid mono 2-ethyl hexyl ester (PC-88A) and Tri-n-octylphosphine oxide (TOPO); Separation Sci. Tehnol. 45(6) 824–831, https://doi.org/10.1080/01496391003607498.
Suzuki Y, Awano M, Kondo N and Ohji T 2001 CH4-sensing of porous CaZrO3/MgO composites with three-dimensional; J. Ceram. Soc. Japan 109(1) 79–81.
Sylwester E R, Hudson E A and Allen P G 2000 The structure of uranium(VI) sorption complexes on silica, alumina, and montmorillonite; Geochim. Cosmochim. Acta 64(14) 2431–2438, https://doi.org/10.1016/S0016-7037(00)00376-8.
Vaaramaa K, Pulli S and Lehto J 2000 Effects of pH and uranium concentration on the removal of uranium from drinking water by ion exchange; Radiochim. Acta 88(12) 845–849, https://doi.org/10.1524/ract.2000.88.12.845.
Vassilev S V, Menendez R, Alvarez D, Diaz-Somoano M and Martinez-Tarazona M R 2003 Phase-mineral and chemical composition of coal fly ashes as a basis for their multicomponent utilization. 1. Characterization of feed coals and fly ashes; Fuel 82(14) 1793–1811, https://doi.org/10.1016/S0016-2361(03)00123-6.
Voll D, Lengauer C, Beran A and Schneider H 2001 Infrared band assignment and structural refinement of Al–Si, Al–Ge, and Ga–Ge mullites; Eur. J. Min. 13(3) 591–604, https://doi.org/10.1127/0935-1221/2001/0013-0591.
Zhao G, Rao P and Lu M 2006 Research and application of mullite and porous mullite; China Ceram. 42(9) 13–17.
Zheng H, Liu D, Zheng Y, Liang S and Liu Z 2009 Sorption isotherm and kinetic modeling of aniline on Cr-bentonite; J. Hazards Mater. 167(1–3) 141–147, https://doi.org/10.1016/j.jhazmat.2008.12.093.
Zhu W, Liu Z, Chen L and Dong Y 2011 Sorption of uranium(VI) on Na-attapulgite as a function of contact time, solid content, pH, ionic strength, temperature and humic acid; J. Radioanal. Nucl. Chem. 289(3) 781–788, https://doi.org/10.1007/s10967-011-1129-4.
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The comments and suggestions of the responsible editors and reviewers during the submission and review of this paper are always appreciated by our team. The National Natural Science Foundation of China (No. 41373120) and the Ministry of Environmental Protection of China (No. 201509024) sustained this research with financial support.
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Rong, L., Zeming, S., Yun, H. et al. Uranium sorption onto mullite: Characteristics of isotherms, kinetics and thermodynamics. J Earth Syst Sci 128, 176 (2019). https://doi.org/10.1007/s12040-019-1215-5
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DOI: https://doi.org/10.1007/s12040-019-1215-5