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Palaeoweathering characteristics of an intrabasaltic red bole of the Deccan Flood Basalts near Shrivardhan of western coast of India

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Abstract

An intrabasaltic red bole horizon is studied for its weathering characteristics with respect to the underlying and overlying basalts. The study indicates that all the three units have been considerably weathered; the red bole unit, however shows some distinctive characteristics. The red boles show a higher cation exchange capacity (CEC) and lower sodium adsorption ratio (SAR) and organic carbon (OC) as compared to the weathered basalts. The lower values of Al2O3, TiO2 and Fe2O3(T) in red boles indicate their lesser weathering than the underlying and overlying basalts, which is further corroborated by the weathering intensity measured by the indices like chemical index of alteration (CIA) and statistical empirical index of chemical weathering (W). It is also evident that the red bole samples show more retention of original mafic and felsic components. While K2O exhibits an erratic behaviour, the MgO and CaO do not show much leaching in red boles. Lesser leaching and salinity in the red boles is indicated by the higher values of calcification and lower values of salinization. The SiO2–Al2O3–Fe2O3 plot indicates that red bole samples are close to the basalt field, while the weathered upper basalt is more kaolinized than the weathered lower basalt. These observations reveal that the post-formational weathering processes have least affected the original palaeoweathering characters of the red bole horizon and hence the intrabasaltic palaeosols (weathering horizons) can effectively be used to constrain the palaeoweathering and palaeoclimates during the continental flood basalt episodes in the geologic past.

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References

  • Agashe L V and Gupte R B 1968 Some significant features of Deccan Traps; Geol. Soc. India Memoir 2 309–311.

    Google Scholar 

  • Balaram V, Gnaneswara Rao T, and Anjaiah K V 1999 International proficiency tests for analytical geochemistry laboratories: An assessment of accuracy and precision in routine geochemical analysis; J. Geol. Soc. India 53 417–423.

    Google Scholar 

  • Boulange B and Colin F 1994 Rare earth element mobility during conversion of nepheline syenite into lateritic bauxite at Passa Quatro, Minais Gerais, Brazil; Appl. Geochem. 9 701–711.

    Article  Google Scholar 

  • Braun J -J, Pagel M, Muller J -P, Bilong P, Michard A, and Guillet B 1990 Cerium anomalies in lateritic profiles; Geochim. Cosmochim. Acta 54 781–795.

    Article  Google Scholar 

  • Braun J -J, Pagel M, Herbillon A, and Rosin C 1993 Mobilization and redistribution of REEs and Thorium in a syenitic lateritic profile – a mass-balance study; Geochim. Cosmochim. Acta 57 4419–4434.

    Article  Google Scholar 

  • Coffin M F and Eldholm O 1994 Large igneous provinces: Crustal structure, dimensions and external consequences; Rev. Geophys. 32 1–36.

    Article  Google Scholar 

  • Compton J S, White R A, and Smith M 2003 Rare earth element behavior in soils and salt pan sediments of a semi-arid granitic terrain in the Western Cape, South Africa; Chem. Geol. 201 239–255.

    Article  Google Scholar 

  • Courtillot V 1990 Deccan Volcanism at the Cretaceous tertiary boundary: Past climate crises as a key to the future? Palaeogeogr. Palaeoclimatol. Paleoecol. 189 291– 299.

    Article  Google Scholar 

  • Courtillot V, Jaeger J J, Yang Z, Feraud G, and Hofman C 1996 The influence of continental flood basalts on mass extinctions: Where do we stand? In: The Cretaceous–Tertiary event and other catastrophes in earth history (eds) Ryder G, Fastovsky D and Gartner S, Geol. Soc. America, Spec. Paper 307 513–526.

  • Duddy L R 1980 Redistribution and fractionation of rare-earth and other elements in a weathering profile; Chem. Geol. 30 363–381.

    Article  Google Scholar 

  • Fermor L L 1927 On the basaltic lava flows penetrated by deep boring for coal at Bhusawal, Bombay Presidency; Rec. Geol. Surv. India 58 95–240.

    Google Scholar 

  • Gerard M, Caquineau S, Chenet A L, Fluteau F, Courtillot V, and Subbarao K V 2006 Red boles in the Deccan traps: Time constraints from alteration processes; Geophys. Res. Abstr. 8 07092.

    Google Scholar 

  • Ghosh P., Sayyed M R G, Islam R, and Hundekari S M 2006 Inter-basaltic clay (bole bed) horizons from Deccan traps of India: Implications for palaeo-weathering and palaeo-climate during Deccan volcanism; Palaeogeogr. Palaeoclimatol. Paleoecol. 242 90–109.

    Article  Google Scholar 

  • Gnandi K and Tobschall H J 2003 Distribution patterns of rare-earth elements and uranium in tertiary sedimentary phosphorites of Hahotoe-Kpogame, Togo; J. African Earth Sci. 37 1–10.

    Article  Google Scholar 

  • Hill I G, Worden R H, and Meighan I G 2000 Geochemical evolution of a palaeolaterite: The intrabasaltic formation, northern Ireland; Chem. Geol. 166 65–84.

    Article  Google Scholar 

  • Huang C and Gong Z T 2001 Geochemical implication of rare earth elements in process of soil development; J. Rare Earths 19 57–62.

    Google Scholar 

  • Inamdar P M and Darshan K. 1994 On the origin of bole beds in Deccan Traps; J. Geol. Soc. India 44 331–334.

    Google Scholar 

  • Jerram D A and Widdowson M 2005 The anatomy of Continental Flood Basalt Provinces: Geological constrains on processes and products of flood volcanism; Lithos 79 385–405.

    Article  Google Scholar 

  • Laveuf C and Cornu S 2009 A review on the potentiality of rare earth elements to trace pedogenetic processes; Geoderma 154 1–12.

    Article  Google Scholar 

  • Lyell C 1958 On the structure of lavas, which have consolidated on steep slopes; Philosophical Transactions, Chapter XXXII, 711p.

  • Ma Y-J, Huo R-K and Liu C-Q 2002 Speciation and fractionation of rare earth elements in a lateritic profile from southern China: Identification of the carriers of Ce anomalies; Proceedings of the Goldschmidt Conference, Davos, Switzerland.

  • McLean D M 1985 Deccan Trap mantle degassing in the terminal Cretaceous Marine extinctions; Cret. Res. 6 235–259.

    Article  Google Scholar 

  • Mohapatra B K and Nair K K K 1996 Some observations on bole beds in Deccan Traps; Gondwana Geol. Mag. Spec. Publ. 2 531–534.

    Google Scholar 

  • Nair K K K, Chatterjee A K and Sano T 1996 Stratigraphy and geochemistry of Deccan basalts along Toranmal section, western Satpura region; Gondwana Geol. Mag. Spec Publ. 2 23–48.

    Google Scholar 

  • Nesbitt H W 1979 Mobility and fractionation of rare-earth elements during weathering of a granodiorite; Nature 279 206–210.

    Article  Google Scholar 

  • Nesbitt H W and Markovics G 1997 Weathering of granodioritic crust, long-term storage of elements in weathering profiles, and petrogenesis of siliciclastic sediments; Geochim. Cosmochim. Acta 61 1653–1670.

    Article  Google Scholar 

  • Nesbitt H W and Young G M 1982 Early Proterozoic climates and plate tectonics inferred from major element geochemistry of lutites; Nature 299 715–717.

    Article  Google Scholar 

  • Ohta T and Arai H 2007 Statistical empirical index of chemical weathering in igneous rocks: A new tool for evaluating the degree of weathering; Chem. Geol. 240 280–297.

    Article  Google Scholar 

  • Pascoe E H 1973 A manual of geology of India and Burma, V.3, Govt. of India Publication, 1361p.

  • Reiche P 1943 Graphic representation of chemical weathering; J. Sedim. Petrol. 13 58–68.

    Google Scholar 

  • Retallack G J 2003 Soils and global change in the carbon cycle over geological time; In: Treatise on geochemistry, Elsevier Ltd., 5 581–605.

  • Ronov A B, Balashov Y A, and Migdisov A A 1967 Geochemistry of rare earths in sedimentary cycle; Geochem. Int. USSR 4 1–17.

    Google Scholar 

  • Sayyed M R G and Hundekari S M 2006 Preliminary comparison of ancient bole beds and modern soils developed upon the Deccan volcanic basalts around Pune (India): Potential for palaeoenvironmental reconstruction; Quat. Int. 156–157 189–199.

  • Schellmann W 1986 A new definition of Laterite; In: Lateritization Processes (ed.) Banerji P K, Geol. Surv. India Memoir 120 I1–I7.

  • Sheldon N D 2002 Do ‘red beds indicate deserts or monsoons? In: Palaeosols and Phanerozoic climate: Geochemistry to trace fossils, Denver annual meeting, Session 23.

  • Sheldon N D 2003 Pedogenesis and geochemical alteration of Picture Gorge Sub-Group, Columbia River basalt, Oregon; Geol. Soc. Am. Bull. 115 1377– 1387.

    Article  Google Scholar 

  • Sheldon N D, Retallack G J, and Tanaka S 2002 Geochemical climofunctions from North American soils and application to paleosols across the Eocene–Oligocene boundary in Oregon; J. Geol. 110 687–696.

    Article  Google Scholar 

  • Shepard F P 1963 Submarine Geology; Harper and Row, New York, Evanston and London, 557p.

    Google Scholar 

  • Solleiro-Rebolledo E, Sedov S, Gama-Castro J, Flores Roman D, and Escamilla-Sarabia G 2003 Paleosol-sedimentary sequence of the Glacis de Buenavista, Central Mexico: Interaction of Late Quaternary pedogenesis and volcanic sedimentation; Quat. Int. 106-107 185–201.

    Article  Google Scholar 

  • Tabor N J, Montanez I P, Zierenberg R, and Currie B S 2004 Mineralogical and geochemical evolution of a basalt hosted fossil soil (Late Triassic) Ischigualastu Formation, northwest Argentina): Potential for palaeoenvironmental reconstruction; Geol. Soc. Am. Bull. 116 1280–1293.

    Article  Google Scholar 

  • Thiry M, Schmitt J M, and Simon-Coincon R 1999 Problems, progress and future research concerning palaeoweathering and palaeosurfaces; Int. Assoc. Sedim. Spec. Publ. 27 3–17.

    Google Scholar 

  • Topp S E, Salbu B, Roaldset E, and Jørgensen P 1984 Vertical distribution of trace elements in laterite soil (Suriname); Chem. Geol. 47 (1–2) 159–174.

    Article  Google Scholar 

  • Trivedi R K, Goel P K, and Trisal C L 1987 Practical Methods in Ecology and Environmental Science; Karad, India, 350p.

  • Widdowson M 1997a The geomorphological and geological importance of palaeosurfaces; In: Palaeosurfaces: Recognition, reconstruction and palaeoenvironmental interpretation (ed.) Widdowson M, Geol. Soc. Spec. Publ. 120 1–12.

  • Widdowson M 1997b Tertiary palaeosurfaces of the SW Deccan, western India: Implications for the passive margin uplift; In: Palaeosurfaces: Recognition, reconstruction and palaeoenvironmental interpretation (ed.) Widdowson M, Geol. Soc. Spec. Publ. 120 221–248.

  • Widdowson M, Walsh J N, and Subbarao K V 1997 The geochemistry of Indian bole horizons: Palaeoenvironmental implications of Deccan intravolcanic palaeosurfaces; In: Palaeosurfaces: Recognition, reconstruction and palaeoenvironmental interpretation (ed.) Widdowson M, Geol. Soc. Spec. Publ. 120 269–281.

  • Wignall P B 2001 Large igneous provinces and mass extinctions; Earth Sci. Rev. 53 1–33.

    Article  Google Scholar 

  • Wilkins A, Subbarao K B, Ingram G, and Walsh J N 1994 Weathering regimes within the Deccan Basalts; In: Volcanism (ed.) Subbarao K, Wiley Eastern Ltd., pp. 217–231.

  • Yedekar D B, Aramaki S, Fujiii T and Sano T 1996 Geochemical signature and stratigraphy of the Chhindwara–Jabalpur–Seoni–Mandla sector of the eastern Deccan volcanicprovince and problems of the correlation; Gondwana Geol. Mag. Spec. Publ. 2 49–68.

    Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Geology, Poona College, Camp, Savitribai Phule University of Pune, Pune, 411 001, India

    M R G Sayyed

  2. Department of Geology, Fergusson College, Savitribai Phule University of Pune, Pune, 411 004, India

    R G Pardeshi

  3. Wadia Institute of Himalayan Geology, Dehara Dun, 248001, India

    R Islam

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Correspondence to M R G Sayyed.

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Sayyed, M.R.G., Pardeshi, R.G. & Islam, R. Palaeoweathering characteristics of an intrabasaltic red bole of the Deccan Flood Basalts near Shrivardhan of western coast of India. J Earth Syst Sci 123, 1717–1728 (2014). https://doi.org/10.1007/s12040-014-0481-5

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