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Geochemical and Sm–Nd isotopic study of titanite from granitoid rocks of the eastern Dharwar craton, southern India

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Titanite occurs as an accessory phase in a variety of igneous rocks, and is known to concentrate geologically important elements such as U, Th, rare earth element (REE), Y and Nb. The differences in the abundances of the REEs contained in titanite from granitoid rocks could reflect its response to changes in petrogenetic variables such as temperature of crystallization, pressure, composition, etc. Widespread migmatization in the granodiorite gneisses occurring to the east of Kolar and Ramagiri schist belts of the eastern Dharwar craton resulted in the enrichment of the REEs in titanite relative to their respective host rocks. A compositional influence on the partitioning of REEs between titanite and the host rock/magma is also noticed. The relative enrichment of REEs in titanite from quartz monzodiorite is lower than that found in the granodioritic gneiss. Depletion of REE and HFSE (high field-strength elements) abundances in granitic magmas that have equilibrated with titanite during fractional crystallization or partial melting has been modelled. As little as 1% of titanite present in residual phases during partial melting or in residual melts during fractional crystallization can significantly lower the abundances of trace elements such as Nb, Y, Zr and REE which implies the significance of this accessory mineral as a controlling factor in trace element distribution in granitoid rocks. Sm–Nd isotope studies on titanite, hornblende and whole rock yield isochron ages comparable to the precise U–Pb titanite ages, invoking the usefulness of Sm–Nd isochron ages involving minerals like titanite.

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References

  • Adam J and Green T H 1994 The effect of pressure and temperature on the partitioning of Ti, Sr, and REE between amphibole, clinopyroxene and basanitic melts; Chem. Geol. 117 219–233.

    Article  Google Scholar 

  • Balakrishnan S and Rajamani V 1987 Geochemistry and petrogenesis of granitoids around Kolar schist belt, south India: Constraints for the evolution of the crust in the Kolar area; J. Geol. 95 219–240.

    Article  Google Scholar 

  • Balakrishnan S, Rajamani V and Hanson G N 1999 U–Pb ages for zircon and titanite from the Ramagiri area, southern India: Evidence for accretionary origin of the eastern Dharwar craton during the late Archean; J. Geol. 107 69–86.

    Article  Google Scholar 

  • Basir S R and Balakrishnan S 1999 Geochemistry of sphene from granitoids surrounding the Hutti–Maski Schist Belt: Significance to rare earth element (REE) modelling; J. Geol. Soc. India 54 107–119.

    Google Scholar 

  • Bea F 1996 Residence of REE, Y, Th and U in granites and crustal protoliths; implications for the chemistry of crustal melts; J. Petrol. 37 521–552.

    Article  Google Scholar 

  • Chadwick B, Ramakrishnan M and Viswanatha M N 1981a The stratigraphy and structure of the Chitradurga region: An illustration of cover-basement interaction in Late Archean evolution of the Karnataka craton, Southern India; Precamb. Res. 16 31–54.

    Article  Google Scholar 

  • Chadwick B, Ramakrishnan M and Viswanatha M N 1981b Structural and metamorphic relations between Sargur and Dharwar supracrustal rocks and Peninsular Gneiss in central Karnataka; J. Geol. Soc. India 22 557–569.

    Google Scholar 

  • Chadwick B, Ramakrishnan M and Viswanatha M N 1985a Bababudan – A Late Archean intracratonic volcano-sedimentary basin, Karnataka, Southern India. Part I: Stratigraphy and Basin Development; J. Geol. Soc. India 26 769–801.

    Google Scholar 

  • Chadwick B, Ramakrishnan M and Viswanatha M N 1985b Bababudan – A Late Archean intracratonic volcano-sedimentary basin, Karnataka, Southern India. Part II: Structure; J. Geol. Soc. India 26 802–821.

    Google Scholar 

  • Chadwick B, Vasudev V N, Krishna Rao B and Hegde G V 1992 The Dharwar supergroup: Basin development and implications for Late Archean tectonic setting in western India, southern India; In: The Archean: Terrains, Processes and Metallogeny (eds) Glover J E and Ho S (University of Western Australia Publ.) vol. 22, pp. 3–15.

  • Chadwick B, Vasudev V N and Ahmed N 1996 The Sandur Schist belt and its adjacent plutonic rocks: Implications for Late Archean crustal evolution in Karnataka; J. Geol. Soc. India 47 37–57.

    Google Scholar 

  • Chadwick B, Vasudev V N and Hegde G V 2000 The Dharwar craton, southern India, interpreted as the result of Late Archean oblique convergence; Precamb. Res. 99 91–111.

    Article  Google Scholar 

  • Corfu F and Stone D 1998 The significance of titanite and apatite U–Pb ages: Constraints for the post-magmatic thermal-hydrothermal evolution of a batholithic complex, Berens river area, northwestern Superior Province, Canada; Geochim. Cosmochim. Acta 62 2979–2995.

    Article  Google Scholar 

  • Deer W A, Howie R A and Zussman J 1992 An introduction to the rock-forming minerals (Harlow, Essex: Longman) 696 pp.

    Google Scholar 

  • DePaolo D J and Wasserburg G J 1979 Sm–Nd age for the Stillwater complex and the mantle evolution curve for neodymium; Geochim. Cosmochim. Acta 43 999–1008.

    Article  Google Scholar 

  • Fleischer M and Altschuler Z S 1969 The relationship of the rare-earth composition of the minerals to geological environment; Geochim. Cosmochim. Acta 33 725–732.

    Article  Google Scholar 

  • Franz G and Spear F S 1985 Aluminous titanite (sphene) from the eclogite zone, South Central Tauern Window, Austria; Chem. Geol. 50 33–46.

    Article  Google Scholar 

  • Frost B R, Chamberlain K R and Schumacher J C 2000 Sphene (titanite): Phase relations and role as a geochronometer; Chem. Geol. 172 131–145.

    Article  Google Scholar 

  • Futa K 1981 Sm–Nd systematics of a tonalitic augen gneiss and its constituent minerals from northern Michigan; Geochim. Cosmochim. Acta 45 1245–1249.

    Article  Google Scholar 

  • Ghosh D B, Sastry B B K, Rao A J and Rahim A A 1970 Ore environment and ore genesis in Ramagiri gold field, Andhra Pradesh, India; Econ. Geol. 65 801–814.

    Article  Google Scholar 

  • Gieré R 1992 Compositional variation of metasomatic titanite from Adamello, Italy; Swiss Bull. Mineral. Petrol. 72 167–177.

    Google Scholar 

  • Gioia S M C L and Pimentel M M 2000 The Sm–Nd isotopic method in the geochronology laboratory of the University of Brasília; An. Acad. Bras. Ci. 72 219–245.

    Google Scholar 

  • Govindaraju K 1994 Compilation of working values and sample description for 383 geostandards; Geostandards Newslett. 18 1–158.

    Google Scholar 

  • Green T H and Pearson N J 1986 Rare-earth element partitioning between sphene and coexisting silicate liquid at high pressure and temperature; Chem. Geol. 55 105–119.

    Article  Google Scholar 

  • Green T H and Pearson N J 1987 An experimental study of Nb and Ta partitioning between Ti-rich minerals and silicate liquids at high pressure and temperature; Geochim. Cosmochim. Acta 51 55–62.

    Article  Google Scholar 

  • Gromet L P and Silver L T 1983 REE distributions among minerals in a granodiorite and their petrogenetic implications; Geochim. Cosmochim. Acta 47 925–939.

    Article  Google Scholar 

  • Hanson G N 1978 The application of trace elements to the petrogenesis of igneous rocks of granitic composition; Earth Planet. Sci. Lett. 38 26–43.

    Article  Google Scholar 

  • Huges J M, Bloodaxe E S, Hanchar J M and Foord E E 1997 Incorporation of rare earth elements in titanite: Stabilization of the A2/a dimorph by creation of antiphase boundaries; Am. Mineral. 82 512–516.

    Google Scholar 

  • Jayananda M, Martin H and Mahabaleshwar B 1992 The mechanisms of recycling of Archean continental crust: Example of the Closepet granite, Southern India; Proc. 3rd Int. Archean Symp. Perth, pp. 213–222.

  • Jayananda M, Moyen J-F, Martin H, Peucat J-J, Auvray B and Mahabalesawar B 2000 Late Archaean (2550–2520 Ma) juvenile magmatism in the Eastern Dharwar craton, southern India: Constraints from geochronology, Nd–Sr isotopes and whole rock geochemistry; Precamb. Res. 99 225–254.

    Article  Google Scholar 

  • Krogstad E J, Balakrishnan S, Mukhopadhyay D K, Rajamani V and Hanson G N 1989 Plate tectonics 2.5 billion years ago: Evidence at Kolar, South India; Science 243 1337–1340.

    Article  Google Scholar 

  • Krogstad E J, Hanson G N and Rajamani V 1991 U–Pb ages of zircon and sphene for two gneiss terrains adjacent to the Kolar Schist Belt, south India: Evidence for separate crustal evolution histories; J. Geol. 99 801–816.

    Article  Google Scholar 

  • Krogstad E J, Hanson G N and Rajamani V 1995 Sources of continental magmatism adjacent to the Late Archean Kolar Suture Zone, south India: Distinct isotopic and elemental signatures of two Late Archean magmatic series; Contrib. Mineral. Petrol. 122 159–173.

    Article  Google Scholar 

  • Li X 1994 A comprehensive U–Pb, Sm–Nd, Rb–Sr and 40Ar–39Ar geochronological study of Guidong Granodiorite, southeast China: Records of multi-tectonothermal events in a single pluton; Chem. Geol. 115 283–295.

    Article  Google Scholar 

  • Lugmair G W and Carlson R W 1978 The Sm–Nd history of KREEP; Proc. 9th Lunar Planet. Sci. Conf., pp. 689–704.

  • Mahoney J B, Weis D, Kieffer B, Friedman R, Pretorius W, Scoates J, Goolaerts A and Maerschalk C 2003 Ongoing Isotopic Characterization of USGS Standards: MC-ICPMS and TIMS data from The Pacific Centre for Isotopic and Geochemical Research, University of British Columbia (Abst.) Abstracts with Programs, Annual Meeting; Geol. Soc. Amer. 35 243.

    Google Scholar 

  • Mezger K 1990 Geochronology in granulites; In: Granulites and Crustal Evolution (eds) Vielzeuf D and Vidal Ph (Dordrecht, The Netherlands: Kluwer Academic Publishers) pp. 451–470.

    Google Scholar 

  • Mohanta M K 1998 Geochemistry and nuclear energy potential of the granitic gneisses around Ramagiri gold fields; unpubl. Ph.D. dissertation, Jawaharlal Nehru University, New Delhi, 319 pp.

  • Nutman A P, Chadwick B, Krishna Rao B and Vasudev V N 1996 SHRIMP U–Pb zircon ages of acid volcanic rocks in the Chitradurga and Sandur Groups, and granites adjacent to the Sandur schist belt, Karnataka; J. Geol. Soc. India 41 153–164.

    Google Scholar 

  • Pan Y, Fleet M E and MacRae N D 1993 Late alteration in titanite (CaTiSiO5): Redistribution and remobilization of rare earth elements and implications for U/Pb and Th/Pb geochronology and nuclear waste disposal; Geochim. Cosmochim. Acta 57 355–367.

    Article  Google Scholar 

  • Pichamuthu C S 1965 Regional metamorphism and charnockitization in Mysore State, India; Indian Mineral. 6 119–126.

    Google Scholar 

  • Pidgeon R T, Bosch D and Bruguier O 1996 Inherited zircon and titanite U–Pb systems in an archaean syenite from southwestern Australia: Implications for U–Pb stability of titanite; Earth Planet. Sci. Lett. 141 187–198.

    Article  Google Scholar 

  • Poitrasson F, Hanchar J M and Schaltegger U 2002 The current state and future of accessory mineral research; Chem. Geol. 191 3–24.

    Article  Google Scholar 

  • Prowatke S and Klemme S 2005 Effect of melt composition on the partitioning of trace elements between titanite and silicate melt; Geochim. Cosmochim. Acta 69 695–709.

    Article  Google Scholar 

  • Prowatke S and Klemme S 2006 Rare earth element partitioning between titanite and silicate melts: Henry’s law revisited; Geochim. Cosmochim. Acta 70 4997– 5012.

    Article  Google Scholar 

  • Raase P, Raith M, Ackermand D and Lal R K 1986 Progressive metamorphism of mafic rocks from greenschist to granulite facies in the Dharwar craton of south India; J. Geol. 94 261–282.

    Article  Google Scholar 

  • Richard P, Shimizu N and Allègre C J 1976 143Nd/146Nd a natural tracer: An application to oceanic Basalts; Earth Planet. Sci. Lett. 31 269–278.

    Article  Google Scholar 

  • Rollinson H R 1993 Using Geochemical Data: Evaluation, Presentation, Interpretation (Harlow, Essex: Longman) 352 pp.

    Google Scholar 

  • Ryerson F J and Hess P C 1978 Implications of liquid–liquid distribution coefficients to mineral–liquid partitioning; Geochim. Cosmochim. Acta 42 921–932.

    Article  Google Scholar 

  • Ryerson F J and Watson E B 1987 Rutile saturation in magmas: Implications for Ti–Nb–Ta depletion in island-arc basalts; Earth Planet. Sci. Lett. 86 225–239.

    Article  Google Scholar 

  • Saini N K, Mukherjee P K, Rathi M S, Khanna P P and Purohit K K 1998 A new geochemical reference sample of granite (DG-H) from Dalhousie, Himachal Himalaya; J. Geol. Soc. India 52 603–606.

    Google Scholar 

  • Sawka W N, Chappell B W and Norrish K 1984 Light-rare-earth-element zoning in sphene and allanite during granitoid fractionation; Geology 12 131–134.

    Article  Google Scholar 

  • Scott D J and St-Onge M R 1995 Constraints on Pb closure temperature based on rocks from the Ungava orogen, Canada: Implications for U–Pb geochronology and P-T-t path determinations; Geology 23 1123–1126.

    Article  Google Scholar 

  • Seifert W 2005 REE-, Zr-, and Th-rich titanite and associated accessory minerals from a kersantite in Frankenwald, Germany; Mineral. Petrol. 84 129–146.

    Article  Google Scholar 

  • Seifert W and Kramer W 2003 Accessory titanite: An important carrier of zirconium in lamprophyres; Lithos 71 81–98.

    Article  Google Scholar 

  • Stern R A and Hanson G N 1991 Archean high Mg granodiorite: A derivative of light rare earth element enriched monzodiorite of mantle origin; J. Petrol. 32 201–238.

    Google Scholar 

  • Stevenson R, Henry P and Gariépy C 1999 Assimilation-fractional crystallization origin of Archean Sanukitoid Suites: Western Superior Province, Canada; Precamb. Res. 96 83–99.

    Article  Google Scholar 

  • Storey C D, Jeffries T E and Smith M 2006 Common lead-corrected laser ablation ICP–MS U–Pb systematics and geochronology of titanite; Chem. Geol. 227 37–52.

    Article  Google Scholar 

  • Swami Nath J, Ramakrishnan M and Viswanatha M N 1976 Dharwar stratigraphic model and Karnataka craton evolution; Geol. Surv. India Records 107 149–175.

    Google Scholar 

  • Taylor S R and McLennan S M 1985 The Continental Crust: Its Composition and Evolution (Oxford: Blackwell) 312 pp.

    Google Scholar 

  • Tiepolo M, Oberti R and Vannucci R 2002 Trace-element incorporation in titanite: Constraints from experimentally determined solid/liquid partitioning coefficients; Chem. Geol. 191 105–119.

    Article  Google Scholar 

  • Tucker R D, Råheim A, Krogh T E and Corfu F 1987 Uranium–lead zircon and titanite ages from the northern portion of the Western Gneiss Region, south-central Norway; Earth Planet. Sci. Lett. 81 203–211.

    Article  Google Scholar 

  • Ward C D, McArthur J M and Walsh J N 1992 Rare earth element behaviour during evolution and alteration of the Dartmoor granite, SW England; J. Petrol. 33 785–815.

    Google Scholar 

  • Watson E B 1976 Two-liquid partition coefficients: Experimental data and geochemical implications; Contrib. Mineral. Petrol. 56 119–134.

    Article  Google Scholar 

  • Zhang L S and Schärer U 1996 Inherited Pb components in magmatic titanite and their consequences for the interpretation of U–Pb ages; Earth Planet. Sci. Lett. 138 57–65.

    Article  Google Scholar 

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Anand, R., Balakrishnan, S. Geochemical and Sm–Nd isotopic study of titanite from granitoid rocks of the eastern Dharwar craton, southern India. J Earth Syst Sci 120, 237–251 (2011). https://doi.org/10.1007/s12040-011-0045-x

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