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Structural and optical properties of Sr-doped NdFeO3 nanoparticles prepared by a simple co-precipitation method

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Abstract

The present study reports the structure and optical properties of Sr-doped NdFeO3 nanoparticles synthesized by the simple co-precipitation method without the introduction of surfactants. Structural phase formation of the crystal exhibited orthorhombic planes of all samples (Nd1−xSrxFeO3; x = 0.1, 0.2, and 0.3). The average crystal size and unit cell volume are increasing with a dopant (DXRD = 28 ± 3–35±3 nm; V = 236.52–238.07 Å3). The obtained Sr-doped NdFeO3 nanoparticles have higher absorption in the visible region (λ = 400–800 nm) than in the UV range (λ = 200–400 nm) and the band gap value (Eg = 0.87–1.06 eV) is much lower than similar rare-earth perovskite series such as NdFe1−xCoxO3, Y1−xSmxFeO3, HoFe1−xNixO3, LaFe1−xTixO3, and Y1−xGdxFe1−xCoyO3 synthesized by different methods. The excellent optical properties of Sr-doped NdFeO3 nanomaterials give them great potential for applications related to optics.

Graphical abstract

Sr-doped NdFeO3 nanoparticles were synthesized by the simple co-precipitation method. The obtained Sr-doped NdFeO3 nanoparicles have higher absorption in the visible region than in the UV range and the band gap value (Eg = 0.87–1.06 eV) is much lower than similar rare-earth perovskites synthesized by different methods.

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Correspondence to BUI XUAN VUONG.

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CHUNG, N.T.K., TIEN, N.A., DIEM, C.H. et al. Structural and optical properties of Sr-doped NdFeO3 nanoparticles prepared by a simple co-precipitation method. J Chem Sci 134, 34 (2022). https://doi.org/10.1007/s12039-022-02031-7

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  • DOI: https://doi.org/10.1007/s12039-022-02031-7

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