Abstract
The present study reports the structure and optical properties of Sr-doped NdFeO3 nanoparticles synthesized by the simple co-precipitation method without the introduction of surfactants. Structural phase formation of the crystal exhibited orthorhombic planes of all samples (Nd1−xSrxFeO3; x = 0.1, 0.2, and 0.3). The average crystal size and unit cell volume are increasing with a dopant (DXRD = 28 ± 3–35±3 nm; V = 236.52–238.07 Å3). The obtained Sr-doped NdFeO3 nanoparticles have higher absorption in the visible region (λ = 400–800 nm) than in the UV range (λ = 200–400 nm) and the band gap value (Eg = 0.87–1.06 eV) is much lower than similar rare-earth perovskite series such as NdFe1−xCoxO3, Y1−xSmxFeO3, HoFe1−xNixO3, LaFe1−xTixO3, and Y1−xGdxFe1−xCoyO3 synthesized by different methods. The excellent optical properties of Sr-doped NdFeO3 nanomaterials give them great potential for applications related to optics.
Graphical abstract
Sr-doped NdFeO3 nanoparticles were synthesized by the simple co-precipitation method. The obtained Sr-doped NdFeO3 nanoparicles have higher absorption in the visible region than in the UV range and the band gap value (Eg = 0.87–1.06 eV) is much lower than similar rare-earth perovskites synthesized by different methods.
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References
Omar R G, Jesus F S D, Fernando P G, Claudia A C E, Marius C E and Maria R C 2019 Enhanced multiferroic properties of YFeO3 by doping with Bi3+ Mater. 12 2054
Kopeychenko E I, Mittova I Ya, Perov N S, Nguyen A T, Mittova V O, Alekhina Yu A and Pham V 2021 Synthesis, composition and magnetic properties of cadmium-doped lanthanum ferrite nanopowders Inorg. Mater. 57 367
Berezhnaya M V, Perov N S, Almjasheva O V, Mittova V O, Nguyen A T, Mittova I Ya, Druzhinina L V and Alechina Yu A 2019 Synthesis and magnetic properties of barium-doped nanocrystal lanthanum orthoferrite Rus. J. Gen. Chem. 89 480
Khalifa N O, Widatallah H M, Gismelseed A M, Al-Mabsali F N, Sofin R G S and Pekala M 2016 Magnetic and Mössbauer studies of pure and Ti-doped YFeO3 nanocrystalline particles prepared by mechanical milling and subsequent sintering Hyperf. Inter. 237 46
Berezhnaya M V, Al’myasheva O V, Mittova V O, Nguyen A T and Mittova I Ya 2018 Sol-gel synthesis and properties of Y1−xBaxFeO3 nanocrystals Rus. J. Gen. Chem. 88 626
Oemar U, Ang P, Hidajat K and Kawi A 2013 Promotional effect of Fe on perovskite LaNixFe1−xO3 catalyst for hydrogen production via steam reforming of toluene Inter. J. Hydr. Ener. 38 5525
Sasikala C, Durairaj N, Baskaran I, Sathyaseelan B, Henini M and Manikandan E 2017 Transition metal titanium (Ti) doped LaFeO3 nanoparticles for enhanced optical structure and magnetic properties J. Alloys Compd. 712 870
Habib Z, Majid K, Ikram M, Sultan K, Mir S A and Asokan K 2016 Influence of Ni substitution at B-site for Fe3+ ions on morphological, optical, and magnetic properties of HoFeO3 ceramics Appl. Phys. A 122 550
Tien N A, Mittova I Ya, Solodukhin D O, Al’myasheva O V, Mittova V O, and Demidova S Yu 2014 Sol-gel formation and properties of nanocrystals of solid solution Y1−xCaxFeO3 Rus. J. Inorg. Chem. 59 40
Shen H, Xu J, Jin M and Jiang G 2012 Influence of manganese on the structure and magnetic properties of YFeO3 nanocrystal Ceram. Inter. 38 1473
Luu M D, Dao N N, Nguyen D V, Pham N C, Vu T N and Doan T D 2016 A new perovskite-type NdFeO3 adsorbent: synthesis, characterization, and As (V) adsorption Adv. Natur. Sci. Nanosci. Nanotechn. 7 15
Zhou Z, Guo L, Yang H, Liu Q and Ye F 2014 Hydrothermal synthesis and magnetic properties of multiferroic rare-earth orthoferrites J. Alloys Compd. 583 21
Motlagh M K, Noroozifar M, Yousefi M and Jahani S 2013 Chemical synthesis and characterization of perovskite NdFeO3 nanocrystals via a co-precipitation method Inter. J. Nanosci. Nanotechn. 9 7
Zharvan V, Kamaruddin Y N, Samnur S and Sujiono E H 2017 The effect of molar ratio on crystal structure and morphology of Nd1+xFeO3 (x=0.1, 0.2 and 0.3) oxide alloy material synthesized by solid state reaction method IOP Conf. Seri. Mater. Sci. Eng. 202 012072
Mir S, Ikram M and Asokan K 2014 Effect of Ni doping on optical, electrical and magnetic properties of Nd orthoferitte J. Phys. Conf. Seri. 534 012017
Tugova E, Yastrebov S, Karpov O and Smith R 2017 NdFeO3 nanocrystals under glycine nitrate combustion formation J. Cryst. Growth 467 88
Babu P R and Babu R 2016 Starch assisted sol-gel synthesis and characterization of NdFeO3 Inter. J. Chem Tech Res. 9 364
Serna P V, Campos C G, Jesus F S D, Miro A M B, Loran J A J and Longwell J 2016 Mechanosynthesis, crystal structure and magnetic characterization of neodymium orthoferrite Mater. Res. 19 0214
Yousefi M, Zeid S S and Motlagh M K 2017 Synthesis and characterization of nano-structured perovskite type neodymium orthoferrite NdFeO3 Curr. Chem. Lett. 6 23
Bui X V and Nguyen A T 2021 Sol-gel synthesis, crystal structure and magnetic properties of nanocrystalline praseodymium orthoferrite Cond. Mat. Inter. 23 196
Nguyen A T, Nguyen T T L, Bui X V, Nguyen T H D, Lieu D H, Le T M L and Pham V 2020 Optical and magnetic properties of HoFeO3 nanocrystals prepared by a simple co-precipitation method using ethanol J. Alloys Compd. 834 155098
Pham T H D and Nguyen A T 2021 Optical and magnetic of orthoferrite NdFeO3 nanomaterials synthesized by simple co-precipitation method Cond. Mat. Inter. 23 585
Nguyen A T, Pham N T V, Le T H, Chau H D, Mittova V O, Nguyen T T L, Dinh A D, Hao T H V and Mittova I Ya 2019 Crystal structure and magnetic properties of LaFe1−xNixO3 nanomaterials prepared via a simple co-precipitation method Ceram. Inter. 45 21768
Nguyen A T, Pham V, Chau H D, Mittova V O, Mittova I Ya, Kopeychenko E I, Nguyen T T L, Bui X V, Nguyen T P A 2020 Effect of Ni substitution on phase transition, crystal structure and magnetic properties of nanostructured YFeO3 perovskite J. Molec. Struct. 1215 128293
Nguyen A T, Pham N T V, Nguyen T T L, Mittova V O, Vo Q M, Berezhnaya M V, Mittova I Ya, Do T H and Chau H D 2019 Crystal structure and magnetic properties of perovskite YFe1−xMnxO3 nanopowders synthesized by co-precipitation method Solid State Sci. 96 105922
Housecroft C E and Sharpe A G 2005 Inorganic Chemistry 2nd ed. (Upper Saddle River, NJ, USA: Pearson, Prentice Hall)
Kharton V V, Kovalevsky A V, Patrakeev M V, Tsipis E V, Viskup A P, Kolotygin V A, Yaremchenko A A, Shaula A L, Kiselev E A and Waerenborg J C 2008 Oxygen nonstoichiometry, mixed conductivity, and Mössbauer spectra of Ln0.5A0.5FeO3−δ (Ln = La–Sm, A = Sr, Ba): effect of cation size Chem. Mater. 20 6457
Ramana C V, Smith R J and Hussain O M 2003 Grain size effects on the optical characteristics of pulsed-laser deposited vanadium oxide thin films Phys. Stat. Solid. A 199 R4
Deotale A J and Nandedkar R V 2016 Correlation between particle size, strain and band gap of iron oxide nanoparticles Mater. Sci. Mater. Today: Proc. 3 2069
Wang M and Wang T 2019 Structural, magnetic and optical properties of Gd and Co co-doped YFeO3 nanopowders Mater. 12 2423
Bharadwaj P S J, Kundu S and Kollipara V S 2020 Structural, optical and magnetic properties of Sm3+ doped yttrium orthoferrite (YFeO3) obtained by sol-gel synthesis route J. Phys. Cond. Matt. 32 035810
Nguyen A T, Pham L T, Mittova I Ya, Mittova V O, Nguyen T T L, Nguyen V H and Bui X V 2021 Co-doped NdFeO3 nanoparticles: synthesis, optical and magnetic properties study Nanomater. 11 937
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CHUNG, N.T.K., TIEN, N.A., DIEM, C.H. et al. Structural and optical properties of Sr-doped NdFeO3 nanoparticles prepared by a simple co-precipitation method. J Chem Sci 134, 34 (2022). https://doi.org/10.1007/s12039-022-02031-7
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DOI: https://doi.org/10.1007/s12039-022-02031-7