Journal of Chemical Sciences

, Volume 129, Issue 5, pp 573–578 | Cite as

Polyoxometalate-based 3D porous framework with inorganic molecular nanocage units

  • Shaobin Li
  • Zihao Li
  • Jingyu Zhang
  • Zhengnan Su
  • Shiying Qi
  • Shihong Guo
  • Xiaoguo Tan
Regular Article

Abstract

A new polyoxometalate-based 3D porous framework with inorganic molecular nanocage unit, (\(\hbox {H}_{2}\hbox {dap})[\hbox {K}(\hbox {H}_{2}\hbox {O})_{2}\) (\(\hbox {V}_{10}\hbox {O}_{28})_{0.5}\)] (1) (dap \(=\) 1,2-diaminopropane), has been synthesized and characterized by routine methods. In 1, the decavanadate clusters, as twelve-dentate connectors, link eight potassium ions to form a 3D porous framework with inorganic molecular cage units. There are two dap ligand molecules occupying in each inorganic molecular cage. Furthermore, the electrochemical properties of 1 were studied, which indicate that 1 has a good electrocatalytic activity towards reduction of iodate (\(\hbox {IO}_{3}^{-})\) ascribed to the V-center.

Graphical Abstract

A new polyoxometalate-based 3D porous inorganic nanocage framework has been synthesized. The electrochemical properties indicate that it has a good electrocatalytic activity towards the reduction of iodate.

Keywords

Polyoxometalates inorganic nanocage 3d porous framework electrochemistry electrocatalysis 

Notes

Acknowledgements

This work was financially supported by the NSF of China (No. 21603113), the NSF of Heilongjiang Province (No. QC2016014) and Undergraduate Training Programs for Innovation and Entrepreneurship of Qiqihar University (No. 201610221088).

Supplementary material

12039_2017_1265_MOESM1_ESM.doc (1.1 mb)
Supplementary material 1 (doc 1084 KB)
12039_2017_1265_MOESM2_ESM.doc (75 kb)
Supplementary material 2 (doc 75 KB)
12039_2017_1265_MOESM3_ESM.pdf (209 kb)
Supplementary material 3 (pdf 208 KB)

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Copyright information

© Indian Academy of Sciences 2017

Authors and Affiliations

  • Shaobin Li
    • 1
  • Zihao Li
    • 1
  • Jingyu Zhang
    • 1
  • Zhengnan Su
    • 1
  • Shiying Qi
    • 1
  • Shihong Guo
    • 1
  • Xiaoguo Tan
    • 1
  1. 1.College of Materials Science and EngineeringQiqihar UniversityQiqiharChina

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