Skip to main content
SpringerLink
Log in

Hydrodechlorination of (CH3)3SiCHCl2 over Pd, Ni, Co and Fe supported on AlF3

  • Regular Article
  • Published:
Journal of Chemical Sciences Aims and scope Submit manuscript

Abstract

Gas phase hydrodechlorination (HDC) process of Me3SiCHCl 2 was studied in a flow reactor at 200 ∘C using a 2% metal loading (w/w) of four different monometallic catalysts (Pd/AlF 3, Ni/AlF 3,Co/AlF 3 and Fe/AlF 3). The catalysts were prepared by sol-gel method and structurally examined by BET method, FT-IR and XPS techniques. The XPS technique showed that Ni II, Fe III and Co III exist as oxides. The major products in the HDC process of Me 3SiCHCl 2 were identified by GC and GC-MS and found to include Me 3SiCH 2Cl, Me 3SiCl, and Me 4Si. The effect of these catalysts on the quantitative conversion, selectivity and conversion rates are reported.

Gas phase hydrodechlorination process of Me3SiCHCl2 was studied in a flow reactor at 200°C using a 2% metal loading (w/w) of four different monometallic catalysts (Pd/AlF3, Ni/AlF3, Co/AlF3 and Fe/AlF3). The XPS technique showed that NiII, FeIII and CoIII exist as oxides. The major products in the process of Me3SiCHCl2 were identified to include Me3SiCH2Cl, Me3SiCl, and Me4Si

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Figure 1
Figure 2
Figure 3
Figure 4

Similar content being viewed by others

References

  1. Ahn B S, Lee S C, Moon D J and Lee B G 1996 A study on the hydrodechlorination reaction of dichlorodifluoromethane over PdAlF3 catalyst J. Mol. Catal. 106 83

    Article  CAS  Google Scholar 

  2. Karpiński Z, Bonarowska M and Juszczyk W 2014 Hydrodechlorination of tetrachloromethane over silica-supported palladium-gold alloys PJCT 16 101

    Google Scholar 

  3. Bonarowska M, Malinowski A, Juszczyk W and Karpiński Z 2001 Hydrodechlorination of CCl 2 F 2 (CFC-12) over silica-supported palladium–gold catalysts Appl. Catal. B-Environ. 30 187

    Article  CAS  Google Scholar 

  4. Bodnariuk P, Coq B, Ferrat G and Figueras F 1989 Carbon-chlorine hydrogenolysis over PdRh and PdSn bimetallic catalysts J. Catal. 116 459

    Article  CAS  Google Scholar 

  5. Sajiki H, Kume A, Hattori K, Nagase H and Hirota K 2002 Complete and truly catalytic degradation method of PCBs using Pd/C–Et3 N system under ambient pressure and temperature Tetrahedron Lett. 43 7251

    Article  CAS  Google Scholar 

  6. Coq B, Cognion J M, Figueras F and Tournigant D 1993 Conversion under hydrogen of dichlorodifluoromethane over supported palladium catalysts J. Catal. 141 21

    Article  CAS  Google Scholar 

  7. Coq B, Figueras F, Hub S and Tournigant D 1995 Effect of the metal-support interaction on the catalytic properties of palladium for the conversion of difluorodichloromethane with hydrogen: Comparison of oxides and fluorides as supports J. Phys. Chem.-US 99 11159

    Article  CAS  Google Scholar 

  8. Hina R H and Al-Fayyoumi R K 2004 Conversion of dichlorodifluoromethane with hydrogen over Pd/AlF 3 and Ru/AlF 3 prepared by sol–gel method J. Mol. Catal. A-Chem. 207 27

    Article  CAS  Google Scholar 

  9. He F and Zhao D 2008 Hydrodechlorination of trichloroethene using stabilized Fe-Pd nanoparticles: Reaction mechanism and effects of stabilizers, catalysts and reaction conditions Appl. Catal. B-Environ. 84 533

    Article  CAS  Google Scholar 

  10. Liu T, Wang X and Yin D 2015 Recent progress towards ionic hydrogenation: Lewis acid catalyzed hydrogenation using organosilanes as donors of hydride ions RSC Adv. 5 75794

    Article  CAS  Google Scholar 

  11. Ding S, Xiao W, Huang J, Deng S and Zhang N 2015 Hydrogenation of silicon tetrachloride to trichlorosilane over activated carbon-supported cobalt catalysts Res. Chem. Intermediat. 41 5691

    Article  CAS  Google Scholar 

  12. Kim B-h and Woo H-G 2004 Dehydrocoupling, redistributive coupling, and addition of main group 4 hydrides Adv. Organomet. Chem. 52 143

    Google Scholar 

  13. Colin P, Jacquot R and Morel P 2002 U.S. Patent No. US 06384257. Washington, D.C.: U.S. Patent and Trademark Office

  14. Drose J, Knott W and Wolfgram D 1999 U.S. Patent No. 5856548 A. Washington, D.C.: U.S. Patent and Trademark Office

  15. Lee J Y, Lee W H, Park Y -K, Kim H Y, Kang N Y, Yoon K B, Choi W C and Yang O -B 2012 Catalytic conversion of silicon tetrachloride to trichlorosilane for a poly-Si process Sol. Energ. Mat. Sol. C 105 142

    Article  CAS  Google Scholar 

  16. Kalambettu A B, Rajangam P and Dharmalingam S 2012 The effect of chlorotrimethylsilane on bonding of nano hydroxyapatite with a chitosan polyacrylamide matrix Carbohyd. Res. 352 143

    Article  Google Scholar 

  17. Maloney R and Sakamoto J 2011 Large deformation of chlorotrimethylsilane treated silica aerogels J. Non-Cryst. Solids 357 2059

    Article  CAS  Google Scholar 

  18. Xu L -W 2011 Editorial [Hot Topic: Organosilicon-mediated Organic Synthesis/Organosilicon Chemistry (Guest Editor: Li Wen Xu)] Curr. Org. Chem. 15 2742

    Article  CAS  Google Scholar 

  19. Li X, Eustergerling B and Shi Y 2007 Mass spectrometric study of gas-phase chemistry in a hot-wire chemical vapor deposition reactor with tetramethylsilane Int. J. Mass. Spectrom. 263 233

    Article  CAS  Google Scholar 

  20. Inagaki N, Suzuki K and Nejigaki K 1983 Application of polymer films plasma polymerized in the tetramethylsilane/ammonia mixture to moisture sensor J. Polym. Sci. Pol. Lett. 21 353

    Article  CAS  Google Scholar 

  21. Malik S, Shah K J and Kartha K R 2010 Iodine-hexamethyldisilane (HMDS)-mediated anomerization of peracetylated 1, 2-trans-linked alkyl and aryl glycosides Carbohyd. Res. 345 867

    Article  CAS  Google Scholar 

  22. Durán-Galván M, Hemmer J R and Connell B T 2010 Synthesis of tertiary 1, 3-butadien-2-ylcarbinols from chromium-catalyzed addition of (4-bromobut-2-ynyl) trimethylsilane to ketones Tetrahedron Lett. 51 5080

    Article  Google Scholar 

  23. Parker B and Son D Y 2002 Silylated amino-triazines: New ligands with potential multi-coordination modes Inorg. Chem. Commun. 5 516

    Article  CAS  Google Scholar 

  24. Dhanya S, Kumar A and Naik P D 2007 Dissociation dynamics of chloromethyltrimethylsilane at 193 nm Chem. Phys. Lett. 438 8

    Article  CAS  Google Scholar 

  25. Turner N H and Schreifels J A 2000 Surface analysis: X-ray photoelectron spectroscopy and auger electron spectroscopy Anal. Chem. 72 99

    Article  Google Scholar 

  26. Wang B, Gao F and Ma H 2007 Preparation and XPS studies of macromolecule mixed-valent Cu (I, II) and Fe (II, III) complexes J. Hazard. Mater. 144 363

    Article  CAS  Google Scholar 

  27. Sun S and Wang A 2006 Adsorption kinetics of Cu (II) ions using N, O-carboxymethyl-chitosan J. Hazard. Mater. 131 103

    Article  CAS  Google Scholar 

  28. Weinberg W H 1996 Eley-Rideal surface chemistry: Direct reactivity of gas phase atomic hydrogen with adsorbed species Acc. Chem. Res. 29 (10) 479

    Article  CAS  Google Scholar 

  29. Coq B, Ferrat G and Figueras F 1986 Conversion of chlorobenzene over palladium and rhodium catalysts of widely varying dispersion J. Catal. 101 434

    Article  CAS  Google Scholar 

  30. Keane M A and Murzin D Y 2001 A kinetic treatment of the gas phase hydrodechlorination of chlorobenzene over nickel/silica: Beyond conventional kinetics Chem. Eng. Sci. 56 3185

    Article  CAS  Google Scholar 

Download references

Acknowledgement

This work was financially supported by the Deanship of Research, Jordan University of Science and Technology, Irbid, Jordan.

Author information

Authors and Affiliations

  1. Department of Chemistry, Jordan University of Science and Technology, P.O. Box 3030, Irbid, 22110, Jordan

    RATEB HINA, ISAM ARAFA & OMAR ENNAB

Authors
  1. RATEB HINA
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. ISAM ARAFA
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. OMAR ENNAB
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to RATEB HINA.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

HINA, R., ARAFA, I. & ENNAB, O. Hydrodechlorination of (CH3)3SiCHCl2 over Pd, Ni, Co and Fe supported on AlF3 . J Chem Sci 129, 353–358 (2017). https://doi.org/10.1007/s12039-017-1234-1

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12039-017-1234-1

Keywords

Search

Navigation