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Synthesis, crystal structure and magnetic properties of 1-(2,5-dimethylphenyl)piperazine-1,4-dium tetrachloridocuprate(II)

Journal of Chemical Sciences volume 128, pages 905–911 (2016)Cite this article

Abstract

The synthesis and physico-chemical characterization of a novel organic-inorganic hybrid material, 1-(2,5-dimethylphenyl)piperazine-1,4-dium tetrachloridocuprate(II), have been reported. This compound crystallizes in the monoclinic system with the space group of P21/n and cell parameters a = 9.833(3), b = 16.337(2), c = 10.452(3) Å, β = 102.13(4)∘, Z = 4 and V = 1641.5(7) Å 3. In the title salt, (C12H20N2)[CuCl4], the geometry of the CuCl\(_{4}^{\mathrm {~2-}}\) ion is intermediate between tetrahedral and square planar. In the atomic arrangement tetrachlorocuprate anions and the piperazine-1,4-dium cations are held together via N-H …Cl and C-H …Cl to give a 1-D hybrid chain running along the a-axis. The six-membered piperazinedium ring adopts a chair conformation. The vibrational absorption bands were identified by infrared spectroscopy. Magnetic measurements reveal that moderate antiferromagnetic (AF) Cu–Cu interactions dominate in the title compound.

The synthesis and the physico-chemical characterization of a novel organic-inorganic hybrid material, 1-(2,5-dimethylphenyl)piperazine-1,4-dium tetrachloridocuprate(II), is reported.

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Acknowledgement

This work was supported by the National Natural Science Foundation of China (Grant No. 21233004).

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Authors and Affiliations

  1. Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, Université de Carthage, 7021, Zarzouna, Tunisie

    L KHEDHIRI, M RZAIGUI & C BEN NASR

  2. Fujian Provincial Key Laboratory of Fire Retardant Materials, Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen, 361005, Fujian Province, People’s Republic of China

    JIN-XIAO MI

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  1. L KHEDHIRI
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  2. JIN-XIAO MI
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  3. M RZAIGUI
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  4. C BEN NASR
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Correspondence to C BEN NASR.

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Supplementary Information (SI)

Crystallographic data for the structural analysis have been deposited at the Cambridge Crystallographic Data Centre, CCDC No. 1407713. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html, or from the CCDC, 12 Union Road, Cambridge, CB2 1EZ, UK: Fax: (+ 44) 01223-336-033; e-mail: deposit@ccdc.cam.ac

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KHEDHIRI, L., MI, JX., RZAIGUI, M. et al. Synthesis, crystal structure and magnetic properties of 1-(2,5-dimethylphenyl)piperazine-1,4-dium tetrachloridocuprate(II). J Chem Sci 128, 905–911 (2016). https://doi.org/10.1007/s12039-016-1087-z

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  • DOI: https://doi.org/10.1007/s12039-016-1087-z

Keywords

  • Cu(II) complex
  • X-ray diffraction
  • FT-IR
  • magnetic properties.