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K3[Fe(CN)6].3H2O supported on silica gel: An efficient and selective reagent for the cleavage of oximes to their corresponding carbonyl compounds in aqueous medium

Journal of Chemical Sciences volume 127, pages 493–497 (2015)Cite this article

Abstract

K3[Fe(CN)6].3H2O supported on silica gel, a new oxidant, for efficient, simple and selective cleavage of ketoximes and aldoximes to their corresponding carbonyl compounds in aqueous medium is described. Further oxidation of aldehydes to carboxylic acid and formation of by-products were not observed. α−β unsaturated oxime was deoximated smoothly without oxidation of the double bond.

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Acknowledgement

The authors acknowledge the support of the Hamedan Payame Noor University to this work.

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Authors and Affiliations

  1. Department of Chemistry, Payame Noor University, 19395-4697, Tehran, I. R. of IRAN

    ABBAS AMINI MANESH & BEHZAD SHIRMARDI SHAGHASEMI

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  1. ABBAS AMINI MANESH
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  2. BEHZAD SHIRMARDI SHAGHASEMI
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Correspondence to ABBAS AMINI MANESH.

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MANESH, A.A., SHAGHASEMI, B.S. K3[Fe(CN)6].3H2O supported on silica gel: An efficient and selective reagent for the cleavage of oximes to their corresponding carbonyl compounds in aqueous medium. J Chem Sci 127, 493–497 (2015). https://doi.org/10.1007/s12039-015-0801-6

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  • DOI: https://doi.org/10.1007/s12039-015-0801-6

Keywords

  • K3[Fe(CN)6].3H2O
  • Silica gel
  • oxime
  • aldehyde
  • ketone