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Fluorescent naphthalene-based benzene tripod for selective recognition of fluoride in physiological condition

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Abstract

Aluminium complex of a naphthalene-based benzene tripod ligand system has been reported for the selective recognition of fluoride in aqueous medium in physiological condition. The ligand can selectively recognize Al3+ through enhancement in the fluorescence intensity and this in situ formed aluminium complex recognizes fluoride through quenching of fluorescence. The receptor system detects fluoride in nanomolar range. The sensing property was extended for practical utility to sense fluoride in tap water, pond water and river water.

A highly fluorescent tripodal aluminum complex was used for the sensing of fluoride in physiological condition and in waste water.

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Acknowledgements

GD thanks CSIR (01/2727/13/EMR-II) and Science & Engineering Research Board (SR/S1/OC-62/2011) New Delhi, India for financial support and CIF of IITG for providing instrument facilities. BKD and CK thank IIT Guwahati for fellowship.

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Correspondence to GOPAL DAS.

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DATTA, B.K., KAR, C. & DAS, G. Fluorescent naphthalene-based benzene tripod for selective recognition of fluoride in physiological condition. J Chem Sci 127, 337–342 (2015). https://doi.org/10.1007/s12039-015-0779-0

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