Abstract
Water soluble iron(III) porphyrins immobilized in imidazolium ionic liquids serve as an effective catalyst for the H2O2 mediated oxidation of guanidoximes to selectively give corresponding cyanamides in good yields. The use of ionic liquid with non-coordinating counter anion PF6 affords the product in high yield by facilitating the formation of anionic iron peroxo intermediate.
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The authors are grateful to the Council of Scientific and Industrial Research, New Delhi and University of Delhi for financial assistance.
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KUMARI, P., NAGPAL, R., CHAUHAN, P. et al. Efficient iron(III) porphyrins-catalyzed oxidation of guanidoximes to cyanamides in ionic liquids. J Chem Sci 127, 13–18 (2015). https://doi.org/10.1007/s12039-014-0751-4
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DOI: https://doi.org/10.1007/s12039-014-0751-4