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Synthesis and magnetic properties of a 1-D helical chain derived from a Nickel-Sodium Schiff base complex

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Abstract

The reaction of the deprotonated form of the Schiff base ligand; (E)-2-methoxy-6-((phenylimino) methyl)phenol (L) with nickel chloride hydrate results in the formation of the 1-dimentional coordination polymer; Na[Ni(L)2(OMe)(MeOH)]n (1). The structure was determined via single crystal X-ray diffraction measurements. A careful analysis of the complex shows that the polymer exists as a helical structure, where the helicity is brought about by the presence of an alkali metal ion which is observed for the first time. Moreover the helical structure in 1 is maintained predominantly through covalent bond rather than supramolecular interactions. Direct current magnetic susceptibility measurement suggests that complex 1 obeys the Curie law. The fitting of magnetic data using the PHI software package yields parameters of S = 1, g = 2.26 and D = +4.51 (or D = −7.24 cm−1) for 1.

We report a 1-D helical chain of Nickel Schiff base complexes whose helicity is brought by a sodium ion in the crystal lattice. Preliminary magnetic behavior suggests that there is no super-exchange interaction between the nickel ions via a closed shell sodium ion.

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References

  1. Nakano T and Okamoto Y 2001 Chem. Rev. 101 4013

  2. Pauling L, Corey R B and Branson H R 1951 Proc. Natl. Acad. Sci. U. S. A. 37 205

  3. Watson J D and Crick F H C 1953 Nature 171 737

  4. Chen N, Li M-X, Yang P, He X, Shao M and Zhu S-R. 2013 Cryst. Growth Des. 13 2650

  5. Chen Z, Qin S, Liu D, Shen Y and Liang F 2013 Cryst. Growth Des. 13 3389

  6. He W-W, Yang J, Yang Y, Liu Y-Y and Ma J-F 2012 Dalton Trans. 41 9737

  7. Kano K and Hasegawa H 2001 J. Am. Chem. Soc. 123 10616

  8. Lu W-G, Gu J-Z, Jiang L, Tan M-Y and Lu T-B 2008 Cryst. Growth Des. 8 192

  9. Wen L-L, Dang D-B, Duan C-Y, Li Y-Z, Tian Z-F and Meng Q-J 2005 Inorg. Chem. 44 7161

  10. Xiao D-R, Wang E-B, An H-Y, Li Y-G, Su Z-M and Sun C-Y 2006 Chem. Eur. J. 12 6528

  11. Zahn S and Canary J W 2000 Science 288 1404

  12. Cui Y, Evans O R, Ngo H L, White P S and Lin W 2002 Angew. Chem. Int. Ed. 41 1159

  13. Deuss P J, den Heeten R, Laan W and Kamer P C J 2011 Chem. Eur. J. 17 4680

  14. Evans O R and Lin W 2001 Chem. Mater. 13 3009

  15. Hou H, Meng X, Song Y, Fan Y, Zhu Y, Lu H, Du C and Shao W 2002 Inorg. Chem. 41 4068

  16. Hou H, Wei Y, Song Y, Zhu Y, Li L and Fan Y 2002 J. Mater. Chem. 12 838

  17. Kathalikkattil A C, Bisht K K, Aliaga-Alcalde N and Suresh E 2011 Cryst. Growth Des. 11 1631

  18. Kitagawa S, Kitaura R and Noro S-i 2004 Angew. Chem. Int. Ed. 43 2334

  19. Kondo M, Miyazawa M, Irie Y, Shinagawa R, Horiba T, Nakamura A, Naito T, Maeda K, Utsuno S and Uchida F 2002 Chem. Commun. 2156

  20. Lee S J, Hu A and Lin W 2002 J. Am. Chem. Soc. 124 12948

  21. Lin W, Wang Z and Ma L 1999 J. Am. Chem. Soc. 121 11249

  22. Meng X, Song Y, Hou H, Fan Y, Li G and Zhu Y 2003 Inorg. Chem. 42 1306

  23. Seo J S, Whang D, Lee H, Jun S I, Oh J, Jeon Y J and Kim K 2000 Nature 404 982

  24. Trindade A F, Gois P M P and Afonso C A M 2009 Chem. Rev. (Washington, DC, U. S.) 109 418

  25. Zhang J, Chen S, Wu T, Feng P and Bu X 2008 J. Am. Chem. Soc. 130 12882

  26. Zhang Q, Bu X, Lin Z, Biasini M, Beyermann W and Feng P 2007 Inorg. Chem. 46 7262

  27. Biswas C, Drew M G B, Estrader M and Ghosh A 2009 Dalton Trans. 5015

  28. Lin F, Peng H-Y, Chen J-X, Chik D T W, Cai Z, Wong K M C, Yam V W W and Wong H N C 2010 J. Am. Chem. Soc. 132 16383

  29. Prema D, Oshin K, Desper J and Levy C J 2012 Dalton Trans. 41 4998

  30. Anokhina E V and Jacobson A J 2004 J. Am. Chem. Soc. 126 3044

  31. Anthony S P and Radhakrishnan T P 2004 Chem. Commun. 1058

  32. Heo J, Jeon Y-M and Mirkin C A 2007 J. Am. Chem. Soc. 129 7712

  33. Jiang L, Feng X-L, Su C-Y, Chen X-M and Lu T-B 2007 Inorg. Chem. 46 2637

  34. Jiang L, Lu T-B and Feng X-L 2005 Inorg. Chem. 44 7056

  35. Ohrstrom L, Larsson K, Borg S and Norberg S T 2001 Chem. Eur. J. 7 4805

  36. Roth A, Koth D, Gottschaldt M and Plass W 2006 Cryst. Growth Des. 6 2655

  37. Isfort C S, Kreickmann T, Pape T, Froehlich R and Hahn F E 2007 Chem. Eur. J. 13 2344

  38. Kim H-J, Lee E, Park H-S and Lee M 2007 J. Am. Chem. Soc. 129 10994

  39. Wang R, Zhou Y, Sun Y, Yuan D, Han L, Lou B, Wu B and Hong M 2005 Cryst. Growth Des. 5 251

  40. Wu S-T, Wu Y-R, Kang Q-Q, Zhang H, Long L-S, Zheng Z, Huang R-B and Zheng L-S 2007 Angew. Chem. Int. Ed. 46 8475

  41. Zhang Y, Li J, Chen J, Su Q, Deng W, Nishiura M, Imamoto T, Wu X and Wang Q 2000 Inorg. Chem. 39 2330

  42. Delsuc N, Godde F, Kauffmann B, Leger J-M and Huc I 2007 J. Am. Chem. Soc. 129 11348

  43. Dumitru F, Legrand Y-M, Van der Lee A and Barboiu M 2009 Chem. Commun. 2667

  44. Hu H-Y, Xiang J-F, Yang Y and Chen C-F 2008 Org. Lett. 10 1275

  45. Sun Q, Bai Y, He G, Duan C, Lin Z and Meng Q 2006 Chem. Commun. 2777

  46. Xiao D-R, Wang E-B, An H-Y, Li Y-G and Xu L 2007 Cryst. Growth Des. 7 506

  47. Xiao J, Xu J, Cui S, Liu H, Wang S and Li Y 2008 Org. Lett. 10 645

  48. Wen H-R, Wang C-F, Li Y-Z, Zuo J-L, Song Y and You X-Z 2006 Inorg. Chem. 45 7032

  49. Zheng X-D, Jiang L, Feng X-L and Lu T-B 2008 Inorg. Chem. 47 10858

  50. Goetz S and Kruger P E 2006 Dalton Trans. 1277

  51. Keegan J, Kruger P E, Nieuwenhuyzen M, O’Brien J and Martin N 2001 Chem. Commun. 2192

  52. Piguet C, Bernardinelli G, Bocquet B, Quattropani A and Williams A F 1992 J. Am. Chem. Soc. 114 7440

  53. Piguet C, Bernardinelli G and Williams A F 1989 Inorg. Chem. 28 2920

  54. Provent C, Hewage S, Brand G, Bernardinelli G, Charbonniere L J and Williams A F 1997 Angew. Chem., Int. Ed. Engl. 36 1287

  55. Tynan E, Jensen P, Kelly N R, Kruger P E, Lees A C, Moubaraki B and Murray K S 2004 Dalton Trans. 3440

  56. Upadhyay A, Komatireddy N, Ghirri A, Tuna F, Langley S K, Srivastava A K, Sanudo E C, Moubaraki B, Murray K S, McInnes E J L, Affronte M and Shanmugam M 2014 Dalton Trans. 43 259

  57. Upadhyay A, Vaidya S, Venkatasai V S, Jayapal P, Srivastava A K, Shanmugam M and Shanmugam M 2013 Polyhedron 66 87

  58. Chilton N F, Anderson R P, Turner L D, Soncini A and Murray K S 2013 J. Comput. Chem. 34 1164

  59. Schwarzenbach G, Buergi H B, Jensen W P, Lawrance G A, Moensted L and Sargeson A M 1983 Inorg. Chem. 22 4029

  60. Zeller A, Herdtweck E and Strassner T 2004 Inorg. Chem. Commun. 7 296

  61. Luan X-J, Wang Y-Y, Li D-S, Liu P, Hu H-M, Shi Q-Z and Peng S-M 2005 Angew. Chem.Int. Ed. 44 3864

  62. Plasseraud L, Maid H, Hampel F and Saalfrank R W 2001 Chem. Eur. J. 7 4007

  63. Qi Y, Luo F, Batten S R, Che Y-X and Zheng J-M 2008 Cryst. Growth Des. 8 2806

  64. Zhang J, Chen S, Zingiryan A and Bu X 2008 J. Am. Chem. Soc. 130 17246

  65. Zhang S, Yang S, Lan J, Yang S and You J 2008 Chem. Commun. 6170

  66. Cordes D B, Sharma C V K and Rogers R D 2007 Cryst. Growth Des. 7 1943

  67. Flores-Lopez, L Z, Parra-Hake M, Somanathan R and Walsh P J 2000 Organometallics 19 2153

  68. Lalehzari A, Desper J and Levy C J 2008 Inorg. Chem. 47 1120

  69. Li X-Z, Hao P-P, Wang D and Zhu L-N 2013 Cryst. Eng. Comm. 15 2800

  70. Telfer S G, Sato T, Harada T, Kuroda R, Lefebvre J and Leznoff D B 2004 Inorg. Chem. 43 6168

  71. Zheng X-D, Jiang L, Feng X-L and Lu T-B 2009 Dalton Trans. 6802

  72. Byrne P, Lloyd G O, Anderson K M, Clarke N and Steed J W 2008 Chem. Commun. 3720

  73. Han L, Valle H and Bu X 2007 Inorg. Chem. 46 1511

  74. Ikeda M, Tanaka Y, Hasegawa T, Furusho Y and Yashima E 2006 J. Am. Chem. Soc. 128 6806

  75. Jouaiti A, Hosseini M W and Kyritsakas N 2003 Chem. Commun. 472

  76. Lehn J M, Rigault A, Siegel J, Harrowfield J, Chevrier B and Moras D 1987 Proc. Natl. Acad. Sci. U. S. A. 84 2565

  77. Zhang W, Wang Z-Q, Sato O and Xiong R-G 2009 Cryst. Growth Des. 9 2050

  78. Zhang F, Yajima T, Li Y-Z, Xu G-Z, Chen H-L, Liu Q-T and Yamauchi O 2005 Angew. Chem. Int. Ed. 44 3402

  79. Biradha K and Fujita M 2002 Angew. Chem. Int. Ed. 41 3392

  80. Carlucci L, Ciani G, Proserpio D M and Sironi A 1995 Angew. Chem.Int. Ed. Engl. 34 1895

  81. Carlucci L, Cozzi N, Ciani G, Moret M, Proserpio D M and Rizzato S 2002 Chem. Commun. 1354

  82. Fujita M, Kwon Y J, Washizu S and Ogura K 1994 J. Am. Chem. Soc. 116 1151

  83. Bartual-Murgui C, Salmon L, Akou A, Ortega-Villar N A, Shepherd H J, Munoz M C, Molnar G, Real J A and Bousseksou A 2012 Chem. Eur. J. 18 507

  84. Dey R, Haldar R, Maji T K and Ghoshal D 2011 Cryst. Growth Des. 11 3905

  85. Hawes C S and Kruger P E 2013 Polyhedron 52 255

  86. Li X, Cai Y, Fang Z, Wu L, Wei B and Lin S 2011 Cryst. Growth Des. 11 4517

  87. Li Y and Shi J 2014 Adv. Mater. Ahead of Print

  88. Meng F, Qin L, Zhang M and Zheng H 2014 Cryst. Eng. Comm. 16 698

  89. Zhang G, Yang G and Ma J S 2006 Cryst. Growth Des. 6 375

  90. Huang Y-Q, Zhao X-Q, Shi W, Liu W-Y, Chen Z-L, Cheng P, Liao D-Z and Yan S-P 2008 Cryst. Growth Des. 8 3652

  91. Kar P, Biswas R, Drew M G B, Ida Y, Ishida T and Ghosh A 2011 Dalton Trans. 40 3295

  92. Shova S, Novitchi G, Gdaniec M, Caneschi A, Gatteschi D, Korobchenko L, Voronkova V K, Simonov Y A and Turta C 2002 Eur. J. Inorg. Chem. 3313

  93. Wen H-R, Wang C-F, Song Y, Zuo J-L and You X-Z 2005 Inorg. Chem. 44 9039

  94. Zheng X-D, Hua Y-L, Xiong R-G, Ge J-Z and Lu T-B 2011 Cryst. Growth Des. 11 302

  95. Charbonniere L J, Williams A F, Piguet C, Bernardinelli G and Rivara-Minten E 1998 Chem. Eur. J. 4 485

  96. Tuna F, Lees M R, Clarkson G J and Hannon M J 2004 Chem. - Eur. J. 10 5737

  97. Boca R 2004 Coord. Chem. Rev. 248 757

  98. Carlin R L, O’Connor C J and Bhatia S H 1976 J. Am. Chem. Soc. 98 3523

  99. Pardi L A, Hassan A K, Hulsbergen F B, Reedijk J, Spek A L and Brunel L-C 2000 Inorg. Chem. 39 159

  100. Rogez G, Rebilly J-N, Barra A-L, Sorace L, Blondin G, Kirchner N, Duran M, van Slageren J, Parsons S, Ricard L, Marvilliers A and Mallah T 2005 Angew. Chem.Int. Ed. 44 1876

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Acknowledgements

MS thanks the funding agencies Department of Science and Technology (DST) (SR/S1/IC-32/2011), DST nanomission (SR/NM/NS-1119/2011) and IIT Bombay for financial support. KSM acknowledges the support of an Australia-India AISRF grant. We thank Dr. B Moubaraki for experimental assistance. AU acknowledges CSIR for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, 400 076, Maharashtra, India

    APOORVA UPADHYAY, CHINMOY DAS, SHAIK NAGUL MEERA & MAHESWARAN SHANMUGAM

  2. School of Chemistry, University of Monash, Clayton, Victoria, 3800, Australia

    STUART K LANGLEY & KEITH S MURRAY

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  1. APOORVA UPADHYAY
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  2. CHINMOY DAS
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Correspondence to MAHESWARAN SHANMUGAM.

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Supplementary Information

The cif file for the complex 1 is given in the ESI. CCDC number: 999644. Supplementary information is available at www.ias.ac.in/chemsci.

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UPADHYAY, A., DAS, C., MEERA, S.N. et al. Synthesis and magnetic properties of a 1-D helical chain derived from a Nickel-Sodium Schiff base complex. J Chem Sci 126, 1443–1449 (2014). https://doi.org/10.1007/s12039-014-0712-y

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