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Synthesis, characterization and self-assembly of Co3+ complexes appended with phenol and catechol groups

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Abstract

This work presents the syntheses, characterization and hydrogen bonding based self-assembly of Co3+ complexes of pyridine-amide based bidentate ligands containing appended phenol and catechol groups. Placement of multiple hydrogen bond donors (phenolic OH and amidic NH groups) and acceptors (Oamide groups) in these molecules results in interesting self-assembled architectures.

Cobalt complexes of pyridine-amide based bidentate ligands containing appended phenol and catechol groups are discussed. Placement of multiple hydrogen bond donors and acceptors in these coordination complexes results in interesting self-assembly.

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Acknowledgements

Authors thank Science and Engineering Research Board (SERB), Govt. of India for the generous financial support and CIF-USIC of this university for the instrumental facilities. AA and DB thank University Grant Commission (UGC) for their fellowships.

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  1. Department of Chemistry, University of Delhi, Delhi, 110 007, India

    AFSAR ALI, DEEPAK BANSAL & RAJEEV GUPTA

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  1. AFSAR ALI
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Correspondence to RAJEEV GUPTA.

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Supplementary Information

Figures for absorption spectra, NMR spectra and thermal analysis; and tables for NMR spectra data. The electronic supplementary information can be seen at www.ias.ac.in/chemsci. CCDC 994231-994234 contain the crystallographic data for this paper. These data can be obtained free of charges from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.

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ALI, A., BANSAL, D. & GUPTA, R. Synthesis, characterization and self-assembly of Co3+ complexes appended with phenol and catechol groups. J Chem Sci 126, 1535–1546 (2014). https://doi.org/10.1007/s12039-014-0703-z

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