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Coordination of lanthanide cation to an Anderson type polyoxometalate anion leads to isomorphous metal-oxide based one-dimensional inorganic solids: Synthesis, crystal structure and spectroscopy

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Abstract

One-dimensional isomorphous inorganic polymers containing Anderson type heteropoly anion as a basic building unit, namely [La(H2O)7Cr(OH)6Mo6O18]n⋅4nH2O (1), [Gd(H2O)7Cr(OH)6Mo6O18]n⋅4nH2O (2), [Gd(H2O)7Al(OH)6Mo6O18]n⋅4nH2O (3), and [Eu(H2O)7Al(OH)6Mo6O18]n⋅4nH2O (4) have been synthesized and studied by the powdered X–ray diffraction, TGA, IR, electronic and ESR spectroscopy, and unambiguously by single crystal X-ray crystallography. Isomorphous compounds 1-4 are crystallized in orthorhombic system with Pca2 1 space group. The crystal structure analysis reveals a one-dimensional extended chain in which the Anderson type heteropolyanion, acting as the building unit, is linked by rare earth metal ions in a zig-zag fashion. In the crystal structure, all types of oxygens of the heteropolyanion, lattice waters, lanthanum coordinated waters are extensively involved in O—H ⋯O hydrogen bonding interactions. Compounds are additionally characterized by UV-visible and ESR spectroscopy.

A series of four one-dimensional isomorphous inorganic solids namely, [La(H2O)7Cr(OH)6Mo6O18]n•4nH2O (1), [Gd(H2O)7Cr(OH)6Mo6O18]n•4nH2O (2), [Gd(H2O)7Al(OH)6Mo6O18]n•4nH2O (3), and [Eu(H2O)7Al(OH)6Mo6O18]n•4nH2O (4) have been synthesized and characterized by the powdered X–ray diffraction studies, TG analysis, IR-, electronic- and ESR-spectroscopy, and unambiguously by single crystal X˗ray crystallography.

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Acknowledgements

We thank Science & Engineering Research Board (a statutory body under the Department of Science and Technology), Government of India, for financial support (Project No. SB/SI/IC/034/2013). The national X-ray diffractometer facility at University of Hyderabad, by the Department of Science and Technology, Government of India is gratefully acknowledged. TA and SR are grateful to the Council of Scientific and Industrial Research (CSIR), Government of India, for fellowships.

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  1. School of Chemistry, University of Hyderabad, Hyderabad, 500 046, India

    VADDYPALLY SHIVAIAH, TANMAY CHATTERJEE & SAMAR K DAS

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  1. VADDYPALLY SHIVAIAH
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Supplementary Information

FT-IR spectra and powder X-ray diffraction patterns for compounds 1-4, TGA plots for compounds 1, 3 and 4 and some figures related to the crystal structures are available at

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SHIVAIAH, V., CHATTERJEE, T. & DAS, S.K. Coordination of lanthanide cation to an Anderson type polyoxometalate anion leads to isomorphous metal-oxide based one-dimensional inorganic solids: Synthesis, crystal structure and spectroscopy. J Chem Sci 126, 1525–1533 (2014). https://doi.org/10.1007/s12039-014-0688-7

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