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Building-up novel coordination polymer with Zn(II) porphyrin dimer: Synthesis, structures, surface morphology and effect of axial ligands

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Abstract

Highly flexible Zn(II)1,2-bis(meso-octaethylporphyrin)ethane (1) has been used as host in which two porphyrin rings are found to be face-to-face in non-coordinating solvents. Upon addition of one relatively smaller 4,4′-dipyridine (L1) and one extended N,N′-bispyridine-4-yl-methylene ethylenediamine (L2) guest ligands, the syn conformation of 1 is switched to the anti complexes 1∙(L1)2 and 1∙L 2, respectively. Single crystal X-ray structures of all the complexes are reported in which a stable one-dimensional coordination polymer is produced only in 1∙L 2 that is, to the best of our knowledge, the first structural report of 1D-coordination polymer with porphyrin dimer. Solution structures of the complexes along with binding studies in solution between 1 and L have also been investigated. The morphology of the polymeric complex 1∙L 2 on silicon wafer surface was examined by Atomic Force Microscopy (AFM) in which the crystalline islands of well defined facets of size ranging from 200–550 nm perimeter and a height of 20–40 nm have been observed.

Highly flexible Zn(II)bisporphyrin, which is found to be cofacial, forms a stable 1D coordination polymer with N,N′-bispyridine-4-yl-methylene ethylenediamine which, on silicon wafer surface, produces crystalline islands of well defined facets of size ranging from 200–550 nm perimeter and a height of 20-40 nm.

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Acknowledgement

We are thankful to the Science & Engineering Research Board (SERB) and Council of Scientific and Industrial Research (CSIR), New Delhi for financial support. S.A.I., S.B. and A.D. thank CSIR, India for their fellowships. We thank Prof. Thiruvancheril G. Gopakumar for valuable discussion regarding AFM measurements.

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  1. Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, 208 016, India

    S K ASIF IKBAL, SANFAORI BRAHMA, AVINASH DHAMIJA & SANKAR PRASAD RATH

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  1. S K ASIF IKBAL
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  2. SANFAORI BRAHMA
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Correspondence to SANKAR PRASAD RATH.

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Supplementary Information

CCDC-999047 and 999048 contain the X-ray crystallographic details in CIF format for compound 1∙(L1)2 and 1∙ L2, respectively. These data can be obtained free of charge at www.ccdc.cam.ac.uk/conts/retrieving.htmlor [from the Cambridge Crystallographic Data Center, 12 Union Road, Cambridge CB2 1EZ, UK; Fax: + 44 1223 336 033; E-mail: deposit@ccdc.cam.ac.uk].

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IKBAL, S.K.A., BRAHMA, S., DHAMIJA, A. et al. Building-up novel coordination polymer with Zn(II) porphyrin dimer: Synthesis, structures, surface morphology and effect of axial ligands. J Chem Sci 126, 1451–1461 (2014). https://doi.org/10.1007/s12039-014-0686-9

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  • DOI: https://doi.org/10.1007/s12039-014-0686-9

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