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Synthesis and structural characterization of a calcium coordination polymer based on a μ 3 -bridging tetradentate binding mode of glycine#

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Abstract

A new coordination polymer namely [[Ca6(H–gly)12(H2O)18]Cl12·6H2O]n (1) (H–gly = glycine) has been isolated from the calcium chloride–glycine–water system and structurally characterized. Each Ca(II) in 1 is eight-coordinated and is bonded to eight oxygen atoms three of which are from terminal water molecules and five oxygen atoms from four symmetry related zwitterionic glycine ligands. The H–gly ligands exhibit two different binding modes viz. a monodentate carboxylate ligation and a μ3-tetradentate bridging carboxylate binding mode, which results in the formation of a one-dimensional coordination polymer. In the infinite chain the Ca(II) atoms are organized in a zigzag fashion. A comparative study reveals a rich and diverse structural chemistry of calcium halide–glycine compounds.

The synthesis and structural characterization of a new coordination polymer namely [[Ca6(H–gly)12(H2O)18]Cl12·6H2O]n (1) (H-gly = glycine) isolated from the calcium chloride–glycine–water system is reported.

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References

  1. Fromm K M 2008 Coord. Chem. Rev. 252 856

    Article  CAS  Google Scholar 

  2. Einspahr H and Bugg C E 1980 Acta Crystallogr. B36 264

    CAS  Google Scholar 

  3. Einspahr H and Bugg C E 1981 Acta Crystallogr. B37 1044

    CAS  Google Scholar 

  4. Katz A K, Glusker J P, Beebe S A and Bock C W 1996 J. Am. Chem. Soc. 118 5752

    Article  CAS  Google Scholar 

  5. Murugavel R and Korah R 2007 Inorg. Chem. 46 11048

    Article  CAS  Google Scholar 

  6. Murugavel R, Baheti K and Anantharaman G 2001 Inorg. Chem. 40 6870

    Article  CAS  Google Scholar 

  7. Murugavel R, Karambelkar V V and Anantharaman G 2000 Indian J. Chem. 39A 843

    Google Scholar 

  8. Murugavel R, Karambelkar V V, Anantharaman G and Walawalkar M G 2000 Inorg. Chem. 39 1381

    Article  CAS  Google Scholar 

  9. Murugavel R and Banerjee S 2003 Inorg. Chem. Commun. 6 810

    Article  CAS  Google Scholar 

  10. Murugavel R, Kumar P, Walawalkar M G and Mathialagan R 2007 Inorg. Chem. 46 6828

    Article  CAS  Google Scholar 

  11. Fleck M, Held P, Schwendtner K and Bohaty L 2008 Z. Kristallogr. 223 212

    Article  CAS  Google Scholar 

  12. Yusenko K, Fox S, Guni P and Strasdeit H 2008 Z. Anorg. Allg. Chem. 634 2347

    Article  CAS  Google Scholar 

  13. Fox S, Büsching I, Barklage W and Strasdeit H 2007 Inorg. Chem. 46 818

    Article  CAS  Google Scholar 

  14. Dan M, Cheetham A K and Rao C N R 2006 Inorg. Chem. 45 8227

    Article  CAS  Google Scholar 

  15. Liang P C, Liu K-K, Yeh C-T, Lin C-H and Zima V 2011 Cryst. Growth Des. 11 699

    Article  CAS  Google Scholar 

  16. Guo Z, Li G, Zhou L, Su S, Lei Y, Dang S and Zhang H 2009 Inorg. Chem. 48 8069

    Article  CAS  Google Scholar 

  17. Rossin A, Ienco A, Costantino F, Montini T, Credico B D, Caporali M, Gonsalvi L, Fornasiero P and Peruzzini M 2008 Cryst. Growth Des. 8 3302

    Article  CAS  Google Scholar 

  18. Appelhans L N, Kosa M, Radha A V, Simoncic P, Navrotsky A, Parrinello M and Cheetham A K 2009 J. Am. Chem. Soc. 131 15375

    Article  CAS  Google Scholar 

  19. Williams C A, Blake A J, Wilson C, Hubberstey P and Schroder M 2008 Cryst. Growth Des. 8 911

    Article  CAS  Google Scholar 

  20. Yuan R X, Xiong R G, Chen Z F, You X Z, Peng S M and Lee G-H 2001 Inorg. Chem. Commun. 4 430

    Article  CAS  Google Scholar 

  21. Das M C, Ghosh S K, Sanudo E C and Bharadwaj P K 2009 Dalton Trans. 1644

  22. Neogi S, Navarro J A R and Bharadwaj P K 2008 Cryst. Growth Des. 8 1554

    Article  CAS  Google Scholar 

  23. Yu L C, Chen Z F, Liang H, Zhou C S and Li Y 2005 J. Mol. Struct. 75 241

    Google Scholar 

  24. Kim M K, Bae K L and Ok K M 2011 Cryst. Growth Des. 11 930

    Article  CAS  Google Scholar 

  25. Bacchi A, Carcelli M, Pelizzi C, Pelizzi G, Pelagatti P, Rogolino D, Tegoni M and Viappiani C 2003 Inorg. Chem. 42 5871

    Article  CAS  Google Scholar 

  26. Volkringer C, Loiseau T, Férey G, Warren J H, Wragg D S and Morris R E 2007 Solid State Sci. 9 455

    Article  CAS  Google Scholar 

  27. Jisha K R, Suma S and Sudarsanakumar M R 2010 Polyhedron 29 3164

    Article  CAS  Google Scholar 

  28. Fei Z, Geldbach T J, Scopelliti R and Dyson P J 2006 Inorg. Chem. 45 6331

    Article  CAS  Google Scholar 

  29. Yang Y, Jiang G, Li Y Z, Bai J, Pan Y and You X Z 2006 Inorg. Chim. Acta 359 3257

    Article  CAS  Google Scholar 

  30. Grirrane A, Pastor A, Álvarez E, Moyano R and Galindo A 2007 Inorg. Chem. Commun. 10 1125

    Article  CAS  Google Scholar 

  31. Zhu H F, Zhang Z H, Sun W Y, Okamura T and Ueyama N 2005 Cryst. Growth Des. 5 177

    Article  CAS  Google Scholar 

  32. Jini T, Saban K V, Varghese G, Naveen S, Shridhar M A and Prasad J S 2007 J. Alloys Compounds. 433 211

    Article  CAS  Google Scholar 

  33. Shuai Q, Chen S and Gao S 2007 Inorg. Chim. Acta 360 1381

    Article  CAS  Google Scholar 

  34. Volkringer C, Marrot J, Ferey G and Loiseau T 2008 Cryst. Growth Des. 8 685

    Article  CAS  Google Scholar 

  35. Dietzel P C, Blom R and Fjellvag H 2009 Z. Anorg. Allg. Chem. 635 1953

    Article  CAS  Google Scholar 

  36. Srinivasan B R, Shetgaonkar S Y and Raghavaiah P 2009 Polyhedron 28 2879

    Article  CAS  Google Scholar 

  37. Srinivasan B R, Shetgaonkar S Y, Sawant J V and Raghavaiah P 2008 Polyhedron 27 3299

    Article  CAS  Google Scholar 

  38. Srinivasan B R, Shetgaonkar S Y, Näther C and Bensch W 2009 Polyhedron 28 534

    Article  CAS  Google Scholar 

  39. Srinivasan B R and Shetgaonkar S Y 2010 J. Coord. Chem. 63 3403

    Article  CAS  Google Scholar 

  40. Srinivasan B R, Shetgaonkar S Y and Näther C 2011 Z. Anorg. Allg. Chem. 637 130

    Article  CAS  Google Scholar 

  41. Srinivasan B R, Shetgaonkar S Y and Ghosh N N 2011 J. Coord. Chem. 64 1113

    Article  CAS  Google Scholar 

  42. Natarajan S and Rao J K M 1980 Z. Kristallogr. 152 179

    Article  CAS  Google Scholar 

  43. Rao J K M and Natarajan S 1980 Acta Crystallogr. 36B 1058

    Google Scholar 

  44. Natarajan S and Rao J K M 1981 J. Inorg. Nucl. Chem. 43 1693

    Article  CAS  Google Scholar 

  45. Natarajan S, Ravikumar K and Rajan S S 1984 Z. Kristallogr. 168 75

    Article  CAS  Google Scholar 

  46. Ravikumar K, Rajan S S, Natarajan S, Ponnuswamy M N and Trotter J 1986 Z. Kristallogr. 175 217

    Article  CAS  Google Scholar 

  47. Natarajan S, Shanmugam G, Dhas S A M B and Athimoolam S 2007 Acta Crystallogr. 63E m2897

    Google Scholar 

  48. Murugavel R and Korah R 2007 Synth. React. Inorg. Metal–Organic Nano Metal Chem. 37 779

    CAS  Google Scholar 

  49. Korah R, Kalita L and Murugavel R 2011 Indian J. Chem. 50A 763

    CAS  Google Scholar 

  50. Sheldrick G M 2008 Acta Crystallogr. 64A 112

    Google Scholar 

  51. Pfeiffer P and Modelski J V 1912 Z. Physiol. Chem. 81 329

    Article  Google Scholar 

  52. Pfeiffer P and Modelski J V 1913 Z. Physiol. Chem. 85 1

    Article  CAS  Google Scholar 

  53. Pfeiffer P and Wittka F 1915 Ber. Dtsch. Chem. Ges. 48 1289

    Article  CAS  Google Scholar 

  54. Balkunova L P and Kydynov M K 1977 Izv. Akad. Nauk Kirgiz. SSR 39

  55. Balkunova L P and Kydynov M K 1992 Zh. Neorg. Khim. 37 683

    CAS  Google Scholar 

  56. Natarajan S and Mathew M 1985 Indian J. Phys. 59A 131

    CAS  Google Scholar 

  57. Hussain I and Goodgame M 1994 J. Chem. Soc. Pak. 16 100

    CAS  Google Scholar 

  58. Jayalakshmi K and Vijayan M 1967 Acta Crystallogr. 23 669

    Article  CAS  Google Scholar 

  59. Natarajan S, Kalyana Sundar J, Athimoolam S and Srinivasan B R 2011 J. Coord. Chem 64 2274

    Article  CAS  Google Scholar 

  60. Narayanan P and Venkataraman S 1975 Z. Kristallogr. 142 52

    Article  Google Scholar 

  61. Fleck M 2008 Z. Kristallogr. 223 222

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. School of Physics, Madurai Kamaraj University, Madurai, 625 021, India

    SUBRAMANIAN NATARAJAN & J KALYANA SUNDAR

  2. Department of Chemistry, Goa University, Goa, 403 206, India

    BIKSHANDARKOIL R SRINIVASAN

  3. Laboratory of X-ray Crystallography, Indian Institute of Chemical Technology, Hyderabad, 500 007, India

    K RAVIKUMAR

  4. Department of Physics, Thiagarajar College, Madurai, 625 009, India

    R V KRISHNAKUMAR

  5. Department of Physics, The Madura College, Madurai, 625 011, India

    J SURESH

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  1. SUBRAMANIAN NATARAJAN
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  2. BIKSHANDARKOIL R SRINIVASAN
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  3. J KALYANA SUNDAR
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#Dedicated to Prof. Sabyasachi Sarkar on his 65th birthday

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NATARAJAN, S., SRINIVASAN, B.R., SUNDAR, J.K. et al. Synthesis and structural characterization of a calcium coordination polymer based on a μ 3 -bridging tetradentate binding mode of glycine# . J Chem Sci 124, 781–790 (2012). https://doi.org/10.1007/s12039-012-0266-9

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  • DOI: https://doi.org/10.1007/s12039-012-0266-9

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