Abstract
Some oxovanadium(IV) complexes, namely bis(1,1,1-trifluro-2,4-pentanedionato-O,O′) oxovanadium (IV), [VO(tfac)2(H2O)], bis(1-phenyl-2,4-pentanedionato-O,O′)oxovanadium(IV), [VO(phac)2(H2O)], bis(1,3-diphenyl-2,4-pentanedionato-O,O′)oxovanadium(IV), [VO(dphac)2 (H2O)], of the type [VO(O4)] and bis(pyrolidineaniline)oxovanadium(IV), [VO(pyran)2(H2O)], bis(p-hydroxypyrolidineaniline) oxovanadium(IV), [VO(p-hydroxypyran)2(H2O)], bis(p-methoxypyrolidineaniline) oxovanadium(IV), [VO(p-MeOpyran)2 (H2O)], bis(p-chloropyrolidineaniline)oxovanadium(IV), [VO(p-chloropyran)2(H2O)], bis(p-bromopyrolidineaniline)oxovanadium(IV), [VO(p-bromopyran)2(H2O)], bis(p-cyano pyrolidineaniline)oxovanadium(IV), [VO(p-cyanopyran)2(H2O)], and bis(pyrolidinebenzylamine) oxovanadium(IV), [VO(pyrbz)2(H2O)], of the type [VO(N4)] were synthesized and characterized by IR, UV-Vis, mass spectrometry, elemental analysis, magnetic moment and thermogravimetry in order to evaluate their thermal stability and thermal decomposition pathways. The number of steps and, in particular, the starting temperature of decomposition of these complexes depends on the equatorial ligand. Also, formation constants of the complexes have been determined by UV-Vis absorption spectroscopy through titration of the ligands with the metal ions at constant ionic strength (0.1 M NaClO4) and at 25°C. According to the thermodynamic studies, as the steric character of the ligand increases, the complexation tendency to VO(IV) center decreases. Also, the ab initio calculations were carried out to determine the structural and the geometrical properties of the complexes.
Similar content being viewed by others
References
Mohammadi K, Thompson K H, Patrick B O, Storr T, Martins C, Polishchuk E, Yuen V G, McNeill J H and Orvig C 2005 J. Inorg. Biochem. 99 2217
Crans D C 2000 J. Inorg. Biochem. 80 123
Maurya R C and Rajput S 2004 J. Molecular Struct. 687 34
Plass W 2003 Coord. Chem. Rev. 237 205
Rehder D 2003 Inorg. Chem. Commun. 6 604
Aranha P E, Souza. M, Romera S, Ramos L A, Santos M, Dockal E and Cavalheiro E T G 2007 Thermochim. Acta 453 9
Ahmad S, Isab A A, Ali S and Al-Arfaj A R 2006 Polyhedron 25 1633
Posner B I, Shaver A and Fantus I G 1990 in New antidiabetic drugs (eds) C J Bailey and P R Flatt (Gordon London S), p. 107
Posner B I, Faure R, Burgess J W, Bevan A P, Lachance D, Zhang-Sun G, Fantus I G, Hall D A, Lum B S and Shaver A 1994 J. Biol. Chem. 269 4596
Shaver A, Hall D A, Ng J B, Lebuis A M, Hynes R C and Posner B I 1995 Inorg. Chim. Acta 229 253
Shaver A, Ng J B, Hall D A, Soo Lum B and Posner B I 1993 Inorg. Chem. 32 3109
Kadota S, Fantus I G, Deragon G, Guyda H J, Hersh B and Posner B I 1987 Biochem. Biophys. Res. Commun. 147 259
McNeill J H, Yuen V G, Hoveyda H R and Orvig C 1992 J. Med. Chem. 35 1489
Caravan P, Gelmini L, Glover N, Herring F G, Li H, McNeill J H, Rettig S J, Setyawati I A, Shuter E, Sun Y, Tracey A S, Yuen V G and Orvig C 1995 J. Am. Chem. Soc. 117 12759
Li J, Elberg G, Crans D C and Shechter Y 1996 Biochem. 35 8314
Morgan G T and Moss H W 1914 J. Chem. Soc. 103 78
Kaneda K, Jitsukawa K, Itoh T and Teranishi S 1980 J. Org. Chem. 45 3004
Hirao T 1997 Chem. Rev. 97 2707
Wender P A, Rice K D and Schnute M E 1997 J. Am. Chem. Soc. 119 7897
Taguchi H, Isobe K, Nakamura Y and Kawaguchi S 1975 Chem. Lett. 757
Selbin J, Manning H R and Cessac G 1963 J. Inorg. Nucl. Chem. 2 1253
Atherton N M, Gibbon P J and Shohoji M C B 1982 J. Chem. Soc. Dalton Trans 2289
Dodge R P, Templeton D H and Zalkin A 1961 J. Chem. Phys. 35 55
Amin S, Cryer K, Zhang B, Dutta S, Eaton S, Anderson O, Miller S and Crans D 2000 Inorg. Chem. 39 406
Frisch M J, Trucks G W, Schlegel H B, Scuseria G E, Robb M A, Cheeseman J R, Montgomery J A, Kudin K N, Burant J C, Millam J M, Iyengar S S, Tomasi J, Barone V, Mennucci B, Cossi M, Scalmani G, Rega N, Petersson G A, Nakatsuji H, Hada M, Ehara M, Toyota K, Fukuda R, Hasegawa J, Ishida M, Nakajima T, Honda Y, Kitao O, Nakai H, Klene M, Li X, Knox J E, Hratchian H P, Cross J B, Adamo C, Jaramillo J, Gomperts R, Stratmann R E, Yazyev O, Austin A J, Cammi R, Pomelli C, Ochterski J W, Ayala P Y, Morokuma K, Voth G A, Salvador P, Dannenberg J J, Zakrzewski V G, Dapprich S, Daniels A D, Strain M C, Farkas O, Malick D K, Rabuck A D, Raghavachari K, Foresman J B, Ortiz J V, Cui Q, Baboul A G, Clifford S, Cioslowski J, Stefanov B B, Liu G, Liashenko A, Piskorz P, Komaromi I, Martin R L, Fox D J, Keith T, Al-Laham M A, Peng C Y, Nanayakkara A, Challacombe M, Gill P M W, Johnson B, Chen W, Wong M W, Gonzalez C and Pople J A 2003 (Pittsburgh PA: Gaussian, Inc)
Ghose A K, Pritchett A and Crippen G M 1994 J. Comput. Chem. 9 80
Rogers D and Hopfinger A J 1994 J. Chem. Inf. Comput. Sci. 34 854
Bodor N, Gabanyi Z and Wong C 1989 J. Am. Chem. Soc. 111 3783
Ooi T, Oobatake M, Nemethy G and Scheraga H A 1987 Proc. Natl. Acad. Sci. USA 84 3086
Viswanadhan V N, Ghose A K, Revankar G N and Robins R K 1989 J. Chem. Inf. Comput. Sci. 29 163
Ghose A K and Crippen GM 1987 J. Chem. Inf. Comput. Sci. 27 21
Selwood P W 1956 Magnetochemistry (New York: Interscience)
Symal A 1975 Coord. Chem. Rev. 21 309
Selbin J 1966 Coord. Chem. Rev. 1 293
Abdel-Ghani N T and Sherif O E 1989 Thermochim. Acta 156 69
Leggett D L 1985 Computational methods for the determination of formation constant (New York: Plenum Press)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Asadi, M., Ghatee, M.H., Torabi, S. et al. Synthesis, characterization, ab initio calculations, thermal behaviour and thermodynamics of some oxovanadium(IV) complexes involving O,O- and N,N-donor moieties. J Chem Sci 122, 539–548 (2010). https://doi.org/10.1007/s12039-010-0088-6
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12039-010-0088-6