Journal of Chemical Sciences

, Volume 120, Issue 6, pp 507–513 | Cite as

Facially amphiphilic thiol capped gold and silver nanoparticles



A series of bile acid-derived facially amphiphilic thiols have been used to cap sliver and gold nanoparticles. The self-assembling properties of these steroid-capped nanoparticles have been investigated and reported in this article.


Bile acid facially amphiphilic thiol metal nanoparticles self-assembly organic-inorganic hybrid materials 


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  1. 1.(a)
    Nanoparticle based inks and method of making the same’ Nohr R S and Macdonald J G US Patent no. WO/2002/028660Google Scholar
  2. 1.(b)
    Magdassi S, Bassa A, Vinetsky Y and Kamyshny A 2003 Chem. Mater. 15 2208CrossRefGoogle Scholar
  3. 1.(c)
    Santhanam V and Andres R P 2004 Nano Lett. 4 41CrossRefGoogle Scholar
  4. 1.(d)
    Zheng Z, Yang M and Zhang B 2008 J. Phys. Chem. C112 6597Google Scholar
  5. 2.(a)
    Yonezawa T, Onoue S-ya and Kimizuka N 2002 Chem. Lett. 31 1172CrossRefGoogle Scholar
  6. 2.(b)
    Rowe M P, Steinecker W H and Zellers E T 2007 Anal. Chem. 79 1164CrossRefGoogle Scholar
  7. 3.(a)
    Wohltjen H and Snow A W 1998 Anal. Chem. 70 2856CrossRefGoogle Scholar
  8. 3.(b)
    Elghanian R, Storhoff J J, Mucic R C, Letsinger R L and Mirkin C A 1997 Science 277 1078CrossRefGoogle Scholar
  9. 3.(c)
    Wie A, Kim B, Sadtler B and Tripp S L 2001 Chem. Phys. Chem. 2 743Google Scholar
  10. 3.(d)
    Rao C N R, Kulkarni G U, Govindaraj A, Sathishkumar B C and Thomas P J 2000 Pure Appl. Chem. 72 21CrossRefGoogle Scholar
  11. 3.(e)
    Rao C N R, Kulkarni G U, Thomas P J and Edward P P 2000 Chem. Soc. Rev. 29 27CrossRefGoogle Scholar
  12. 3.(f)
    Huang D, Liao F, Molesa S, Redinger D and Subramanian V 2003 J. Electrochem. Soc. 150 G412CrossRefGoogle Scholar
  13. 3.(g)
    Kuila B K, Garai A and Nandi A K 2007 Chem. Mater. 19 5443CrossRefGoogle Scholar
  14. 3.(h)
    Bradbury C R, Zhao J and Fermin D J 2008 J. Phys. Chem. C112 10153Google Scholar
  15. 4.
    Xu, S, Hartvickson S and Zhao J S 2008 Langmuir 24 7492CrossRefGoogle Scholar
  16. 5. (a)
    Mohr C, Hofmeister H, Radnik J and Claus P 2003 J. Am. Chem. Soc. 125 1905Google Scholar
  17. 5.(b)
    Lou J, Lou Y, Maye M M, Zhong C J and Hepel M 2001 Electrochem. Commun. 3 172CrossRefGoogle Scholar
  18. 5.(c)
    Jaramillo T F, Baeck S-H, Cuenya B R and McFarland E W 2003 J. Am. Chem. Soc. 125 7148CrossRefGoogle Scholar
  19. 5.(d)
    Pasquato L, Rancan F, Scrimin P, Mancin F and Frigeri C 2000 Chem. Commun. 2253Google Scholar
  20. 5.(e)
    Li H, Luk Y-Y and Mrksich M 1999 Langmuir 15 4957CrossRefGoogle Scholar
  21. 5.(f)
    Mallikarjuna N N and Varma R S 2007 Cryst. Growth Des. 7 686CrossRefGoogle Scholar
  22. 5.(g)
    El-Shall M S 2008 Acc. Chem. Res. 41 783CrossRefGoogle Scholar
  23. 6.(a)
    Bruchez Jr M, Moronne M, Gin P, Weiss S and Alivisatos A P 1998 Science 281 2013CrossRefGoogle Scholar
  24. 6.(b)
    Cahn W C W and Nie S 1998 Science 281 2016CrossRefGoogle Scholar
  25. 6.(c)
    Alivisatos P 2004 Nat. Biotechnol. 22 47CrossRefGoogle Scholar
  26. 6.(d)
    Claridge S A, Goh S L, Frechet J M J, Williams S C, Micheel C M and Alivisatos A P 2005 Chem. Mater. 17 1628CrossRefGoogle Scholar
  27. 6.(e)
    Nadagouda M N and Varma R S 2007 Biomacromolecules 8 2762CrossRefGoogle Scholar
  28. 7.
    Cagno S, Janssens K and Mendera M 2008 Anal. Bioanal. Chem. 391 1389CrossRefGoogle Scholar
  29. 8.(a)
    Yonezzawa T, Yasui K and Kimizuka N 2001 Langmuir 17 271Google Scholar
  30. 8.(b)
    Hasobe T, Imahori H, Kamat P V, Ahn T K, Kim S K, Kim D, Fujimoto A, Hirakawa T and Fukuzumi S 2005 J. Am. Chem. Soc. 127 1216CrossRefGoogle Scholar
  31. 8.(c)
    Foos E E, Snow A W, Twig M E and Ancona M G 2002 Chem. Mater. 14 2401CrossRefGoogle Scholar
  32. 8.(d)
    Son S U, Jang Y, Yoon Y K, Kang E and Hyeon T 2004 Nano Lett. 4 1147CrossRefGoogle Scholar
  33. 8.(e)
    Gandubert V J and Lennox R B 2005 Langmuir 21 6532CrossRefGoogle Scholar
  34. 8.(f)
    Yee C K, Ulman A, Ruiz J D, Parikh A, White H and Rafailovich M 2003 Langmuir 19 9450CrossRefGoogle Scholar
  35. 8.(g)
    Ahonen P, Laaksonen T, Nykanen A, Ruokolainen J and Kontturi K 2006 J. Phys. Chem. B110 12954Google Scholar
  36. 8.(h)
    Ray S, Das A K and Banerjee A 2006 Chem. Commun. 26 2816CrossRefGoogle Scholar
  37. 8.(i)
    Vemula P K and John G Chem. Commun. 2006 21 2218CrossRefGoogle Scholar
  38. 8.(j)
    Wang X, Egan C E, Zhou M, Prince K, Mitchell D R G and Caruso R A 2007 Chem. Commun. 29 3060CrossRefGoogle Scholar
  39. 8.(k)
    Sengupta A, Thai C, Sastry M, Matthaei J, Schwartz D, Davis E and Baneyx F 2008 Langmuir. 24 2000CrossRefGoogle Scholar
  40. 9.(a)
    Daniel M-C and Astruc D 2004 Chem. Rev. 104 293CrossRefGoogle Scholar
  41. 9.(b)
    van Bommel K J C, Friggeri A and Shinkai S 2003 Angew. Chem., Int. Ed. 42 980CrossRefGoogle Scholar
  42. 9.(c)
    Love C S, Chechik V, Smith D K, Wilson K, Ashworth I and Brennan C 2005 Chem. Commun. 1971Google Scholar
  43. 9.(d)
    Ono Y, Nakashima K, Sano M, Kanekiyo Y, Inoue K, Hojo J and Shinkai S 1998 Commun. 1477Google Scholar
  44. 9.(e)
    Jung J H, Ono Y and Shinkai S 2000 Angew. Chem., Int. Ed. 39 1862CrossRefGoogle Scholar
  45. 9.(f)
    Sugiyasu K, Tamura S, Takeuchi M, Berthier D, Huc I, Oda R and Shinkai S 2002 Chem. Commun. 1212Google Scholar
  46. 9.(g)
    Kobayashi S, Hanabusa K, Hamasaki N, Kimura M, Shirai H and Shinkai S 2000 Chem. Mater. 12 1523CrossRefGoogle Scholar
  47. 9.(h)
    Kobayashi S, Hamasaki N, Suzuki M, Kimura M, Shirai H and Hanabusa K 2002 J. Am. Chem. Soc. 124 6550CrossRefGoogle Scholar
  48. 9.(i)
    Singh N and Lyon L A 2007 Chem. Mater. 19 719CrossRefGoogle Scholar
  49. 9.(j)
    Vinod V P, Phadtare S, Joshi H M, Sastry M and Rao M 2007 J. Nanosci. Nanotechnol. 7 2767CrossRefGoogle Scholar
  50. 10.
    Bhat S and Maitra U 2006 Chem. Mater. 18 4224Google Scholar
  51. 11.
    Kang S Y and Kim K 1998 Langmuir 14 226CrossRefGoogle Scholar
  52. 12.
    Brust M, Walker M, Bethell D, Schiffrin D J and Whyman R J 1994 J. Chem. Soc., Chem. Commun. 801Google Scholar
  53. 14.(a)
    Battacharya S and Srivastava A 2003 Langmuir 19 4439Google Scholar
  54. 14.(b)
    Bhattacharya S, Srivastava A and Pal A 2006 Angew. Chem. Int. Ed. 45 2934CrossRefGoogle Scholar
  55. 16.(a)
    Shipway A N, Katz E and Willner I 2000 Chem. Phys. Chem. 1 18Google Scholar
  56. 16.(b)
    Soten I and Ozin G A 1999 Curr. Opin. Coll. Interf. Sci. 4 325CrossRefGoogle Scholar
  57. 16.(c)
    Malikova N, Santos I P, Schierhorn M, Kotov N A and Marzan L M L 2002 Langmuir 18 3694CrossRefGoogle Scholar
  58. 16.(d)
    Andersen P C and Rowlen K L 2002 Appl. Spectro. 56 124ACrossRefGoogle Scholar

Copyright information

© Indian Academy of Sciences 2008

Authors and Affiliations

  1. 1.Department of Organic ChemistryIndian Institute of ScienceBangaloreIndia
  2. 2.Chemical Biology UnitJawaharlal Nehru Centre for Advanced Scientific ResearchBangaloreIndia

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