Abstract
The present study reports the successful synthesis of Zn/Cu layered double hydroxides (LDHs) by a simple hydrolysis route and detailed characterization using a wide variety of techniques, i.e., PXRD, FTIR, TGA, ICP-MS and SEM/EDX. The study proposes a facile and cost-effective method for exchanging the interlayer anion with the conducting polymeric anion (PANI) that results in a material with enhanced thermal, optical and electrical properties, which may be of interest in a variety of applications. The morphology, thermal stability and interactions of PANI-modified Zn/Cu LDH were compared with pristine LDH. In addition, the structural memory effect property of Zn/Cu lattice was examined, where after rehydration the calcined sample of as-synthesized LDH was successfully reformed into layered structure with good crystallinity.
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Acknowledgements
We are sincerely thankful to the Delhi Technological University for providing the necessary facilities to conduct the research. PS is highly thankful to UGC BSR for Research startup Grant No. F.30-416/2018 (BSR). BP is deeply grateful to CSIR, India, for financial assistance (SRF).
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Pandey, B., Singh, P. & Kumar, V. Facile synthesis of Zn/Cu and PANI modified layered double hydroxides with insights into structural memory effect property. Bull Mater Sci 45, 169 (2022). https://doi.org/10.1007/s12034-022-02754-w
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DOI: https://doi.org/10.1007/s12034-022-02754-w