Abstract
Molybdenum trioxide (MoO3) thin films are grown on ITO-coated glass substrates by thermal deposition technique under the presence of oxygen partial pressure (PO2) about 2 × 10–3 mbar at various substrate temperatures to enhance electrochromic efficiency. Even at room temperature, the experimental films were crystalline, and crystallinity increased as the substrate temperature (Ts) was raised to 150°C. It is noted that the uniform spherical structure was transformed to a needle-like structure at Ts = 150°C. The transmittance of the films improved with substrate temperature, and corresponding bandgap values were measured. The films grown at Ts = 150°C reported the highest colouration efficiency.
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Madhuri K V, Srinivasa Rao K, Uthanna S, Naidu B S and Hussain O M 2001 J. Indian Inst. Sci. 81 653
Scarminio J, Lourenco A and Gorenstein A 1997 Thin Solid Films 302 66
Thomas C A 1976 ECS J. Solid State Sci. Technol. 123 527
Patil R S, Uplane M D and Patil P S 2008 Int. J. Electrochem. Sci. 3 259
Sivakumar R, Manisankar P, Jayachandran M and Sanjeeviraja C 2006 Sol. Energy Mater. Sol. Cells 90 2438
Madhuri K V and Ashrit P V 2014 Int. J. Eng. Technol. 3 245
Granqvist C G 1995 Handbook of inorganic electrochromic materials (Amsterdam: Elsevier)
Ferroni M, Guidi V, Martinelli G, Sacerdoti M, Nelli P and Sberveglieri G 1997 Thin Solid Films 307 148
Comini E, Faglia G, Sbervoglieri G, Cantalini C, Passacantando M, Santucci S et al 2000 Sens. Actuators B 68 168
Yao D D, Ou J Z, Latham K, Zhuiykov S, O’Mullane A P and Kalantar-zadeh K 2012 Cryst. Growth Des. 12 1865
Zhou J, Lin N, Wang L, Zhang K, Zhu Y and Qian Y 2015 J. Mater. Chem. A 3 7463
Ashrith P 2017 Transition metal oxide thin films-based chromogenics and devices 1st Edn (Amsterdam, Netherlands; Cambridge, MA, United States: Elsevier)
Lampert C M and Granqvist C G 1990 SPIE Institute series IS4 Proceedings of the SPIE Vol. 10304 (Bellingham, WA: SPIE Opt. Engr. Press)
Gaigneaux E M, Fukui K and Iwasawa Y 2000 Thin Solid Films 374 49
Wang J, Matsubara I, Murayama N, Woosuck S and Izu N 2006 Thin Solid Films 514 329
Li W, Cheng F, Tao Z and Chen J 2006 J. Phys. Chem. B 110 119
Hosseini S H, Saghafi M and Heshmati-Manesh S 2012 Mater. Manuf. Process. 27 1271
Arfaoui A, Touihri S, Mhamdi A, Labidi A and Manoubi T 2015 Appl. Surf. Sci. 357 1089
Pandeeswari R and Jayaprakash B G 2014 Biosens. Bioelectron. 53 182
Julien C and Nazri G A 1994 Solid-state batteries materials design and optimization (Boston, London: Kluwer Academic Publishers)
Sian T S and Reddy G B 2004 Sol. Energy Mater. Sol. Cells 82 375
Al-Kuhaili M F, Durrani S M A and Khawaja E E 2002 Thin Solid Films 408 188
Sabhapathi V K, Hussian O M, Ramakrishana Reddy K T, Uthanna S, Naidu B S and Reddy P J 1995 Phys. Status Solidi (a) 148 167
Lin S Y, Chen Y C, Wang C M, Hsieh P T and Shih S C 2009 Appl. Surf. Sci. 255 3868
Ramana C V and Julien C M 2006 Chem. Phys. Lett. 428 114
Ferreira F F, Cruz T G S, Fantini M C A, Tabacniks M H, De Castro S C, Morais J et al 2000 Solid State Ion. 137 357
Okumu J, Koerfer F, Salinga C, Pedersen T P and Wuttig M 2006 Thin Solid Films 515 1327
Mohamed S H and Venkataraj S 2007 Vacuum 81 636
Guerrero R M, Garcia J R V, Santes V and Gomez E 2007 J. Alloys Compd. 434 701
Boudoud L, Benramdane N, Desfeux R, Khelifa B and Mathieu C 2006 Catal. Today 113 230
Hsu C S, Chan C C, Huang C T, Peng C H and Hsu W C 2008 Thin Solid Films 516 4839
Donald M Mattox 2010 Handbook of physical vapour deposition (PVD) processing 2 edn, Elsevier (Amsterdam: William Andrew Applied Science Printers)
Kazikawa Y 2011 Thin film growth, physics, materials science applications Ist edn, Part 1 (Woodhead Pub. Ltd.)
Subbarayudu S, Madhavi V and Uthanna S 2014 Int. J. Mater. Sci. 4 78
Tauc J 1974 Optical properties of amorphous semiconductors, amorphous and liquid semiconductors (London and New York: Springer), p 159
Cardenas R, Torres J and Alfonso J E 2005 Thin Solid Films 478 146
Subbarayudu S, Madhavi V and Uthanna S 2013 Adv. Mater. Lett. 4 637
De Castro I A, Datta R S, Ou J Z, Castellanos-Gomez A, Sriram S and Daeneke T 2017 Adv. Mater. 29 1701619
Dixit D and Madhuri K V 2019 Mater. Today: Proc. 19 2688
Sivakumar R, Gopinath C S, Jayachandran M and Sanjeeviraja C 2007 Curr. Appl. Phys. 7 76
Sivakumar R, Gopalakrishnan R, Jayachandran M and Sanjeeviraja C 2007 Curr. Appl. Phys. 7 51
Ohring M 1992 The Materials science of thin films 1st edn. (San Diego, CA: Academic Press)
Joannopoulos J D, Johnson S C, Winn N and Meade R D 2008 Photonic crystals: molding the flow of light 2nd edn. (New Jersey: Princeton University Press)
Morin F J 1959 Phys. Rev. Lett. 3 34
Kuzmin A and Purans J 1993 J. Phys.: Condens. Matter 5 2333
Chen H-C, Jan D-J, Chen C-H and Huang K-T 2013 Electrochim. Acta 93 307
Madhavi V, Kondaiah P, Hussain O M and Uthanna S 2014 Physica B 454 141
Patil C E, Tarwal N L, Jadhav P R, Shinde P S, Deshmukh H P, Karanjkar M M et al 2014 Curr. Appl. Phys. 14 389
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Madhuri, K.V., Dixit, D. Study on structural and optical properties of thermally evaporated MoO3 thin films. Bull Mater Sci 45, 83 (2022). https://doi.org/10.1007/s12034-022-02664-x
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DOI: https://doi.org/10.1007/s12034-022-02664-x