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Sensing and optical activities of new pyrazole containing polymeric analogues

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Abstract

The semi-linear pyrazole containing polymeric structures have been synthesized by three different methods to produce 4-(4-(phenyldiazenyl)-1H-pyrazole-3,5-diyl)oligomer, copolymer and homopolymer analogous with molecular weight up to 24000 g mol–1. Thermogravimetric analysis showed that the copolymer and homopolymer analogous have high thermal stability than the oligomer. The photoluminescence behaviour and sensing application of the new compounds were analysed by UV–visible spectroscopy and fluorescence spectroscopy. The copolymer analogue was found to show high sensitivity to acetate anion.

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Acknowledgement

Hanan Elnagdy thanks ICCR, New Delhi, for a fellowship. DS is thankful to DST, New Delhi, India, for a research Grant [No. EMR/2016/002345].

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Authors and Affiliations

  1. Department of Chemistry, Dibrugarh University, Dibrugarh, 786004, India

    Hanan Mohamed Fathy Elnagdy, Tikendrajit Chetia, Bolin Chetia & Diganta Sarma

  2. Department of Physics, Dibrugarh University, Dibrugarh, 786004, India

    Nibedita Dehingia & Pankaj Dutta

Authors
  1. Hanan Mohamed Fathy Elnagdy
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  2. Tikendrajit Chetia
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  3. Nibedita Dehingia
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  4. Bolin Chetia
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  5. Pankaj Dutta
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  6. Diganta Sarma
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Corresponding author

Correspondence to Diganta Sarma.

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Elnagdy, H.M.F., Chetia, T., Dehingia, N. et al. Sensing and optical activities of new pyrazole containing polymeric analogues. Bull Mater Sci 45, 86 (2022). https://doi.org/10.1007/s12034-022-02660-1

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