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Conduction mechanism in rare earth-doped perovskite material through impedance analysis

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Abstract

Perovskite (PVSK) has been considered as a promising material for electrochemical energy storage devices. In this paper, the conduction mechanism of rare earth europium-doped perovskite material, Pb1−xEux (Zr0.60Ti0.40)1−x/4O3 as an electrode material for solar cell as well as supercapacitor has been studied. The structural and electrical properties were studied at room temperature for different compositions of Eu-doped PVSK, x = 0.00, 0.03, 0.06 and 0.09. Europium-doped PVSK was prepared via solid-state technique in the higher range of temperature. Structural and surface morphologies were done by X-ray diffraction and SEM. The electrical property has been studied via CIS technique at different frequencies. Study of ac conductivity and impedance analysis affirms PVSK as a potential material for the electrode of photo supercapacitor, a device which helps in the conversion of light energy into electrical and which also helps in energy storage mechanism.

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Authors and Affiliations

  1. Department of Physics, Graduate School College for Women, Kolhan University, Jamshedpur, 831001, India

    Sweta Sharma

  2. Department of Physics, National Institute of Technology, Jamshedpur, 831014, India

    M D Soaib Khan & Rajeev Ranjan

  3. Department of Physics, ARSD College, University of Delhi, New Delhi, 110021, India

    Yogesh Kumar

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  1. Sweta Sharma
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  2. M D Soaib Khan
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  3. Yogesh Kumar
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  4. Rajeev Ranjan
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Correspondence to Rajeev Ranjan.

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Sharma, S., Khan, M.D.S., Kumar, Y. et al. Conduction mechanism in rare earth-doped perovskite material through impedance analysis. Bull Mater Sci 44, 206 (2021). https://doi.org/10.1007/s12034-021-02489-0

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