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Properties of ionic liquid cross-linked hydrogels and their application of derusting

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Abstract

Dimethylaminoethyl methacrylate maleate (DMAEMA–MA) polymerizable ionic liquid was synthesized from 2-(dimethylamino)ethyl methacrylate and maleic acid and characterized by 1HNMR and FTIR. IC-P hydrogel was prepared by hydrothermal synthesis method using 2-acrylamide-2-methylpropane sulphonic acid and acrylamide as monomers, DMAEMA–MA as crosslinker and potassium peroxodisulphate as initiator. BIS-P hydrogel was prepared by using N,N′-methylene bisacrylamide (BIS) as non-ionic crosslinker, and the performances of BIS-P and IC-P hydrogels were compared. The results showed that IC-P hydrogel had a pore structure similar to BIS-P. When the dosage of DMAEMA–MA was 1.6% (based on the total mass of monomers), the swelling rate of the prepared IC1.6 hydrogel in water can reach 235.97%, the conductivity was 58.8 μS cm−1, and the derusting effect of Q235 low carbon steel with rust grade C could reach grade A. Moreover, DMAEMA–MA could improve the thermal stability of IC-P hydrogel.

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Acknowledgements

This work was supported by Jilin Province Science and Technology Development plan project (20180201019SF), the Research Fund of Science and Technology Department of Jilin Province (20100551) and special project of Industrial Technology Research and Development in Jilin Province (2013779).

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Authors and Affiliations

  1. Jilin Institute of Chemical Technology, Institute of Petrochemical Technology and Institute of Postgraduate, Jilin, 132022, Jilin Province, People’s Republic of China

    Jian Sun, Jiyang Wang, Hong Wang, Dailin Li, Huajing Gao & Zhaohui Jin

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  1. Jian Sun
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  2. Jiyang Wang
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  3. Hong Wang
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Correspondence to Jian Sun.

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Sun, J., Wang, J., Wang, H. et al. Properties of ionic liquid cross-linked hydrogels and their application of derusting. Bull Mater Sci 44, 183 (2021). https://doi.org/10.1007/s12034-021-02471-w

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