Abstract
Catalytic degradation of textile dyes in diluted aqueous solutions with minimal consumption of energy is a great challenge for wastewater treatment and environmental protection. Efficient heterogeneous catalysts are needed to completely oxidize azo-dyes under soft conditions. In this work, catalysts of Cu–Co oxide (1:2 molar ratio) supported on halloysite (Ha) nanotubes (CuCo(5%)/Ha and CuCo(10%)/Ha) were synthesized and used in the catalytic wet peroxide oxidation of reactive yellow 145 (RY-145) and basic red 46 (BR-46). The catalysts were characterized by chemical analysis, X-ray diffraction, Raman spectroscopy, \(\hbox {N}_{2}\) adsorption isotherms, scanning electron microscopy and transmission electron microscopy. The results showed that the synthesized catalysts possess nanotubular structure with good mesoporosity, and the spinel structure \(\hbox {CuCo}_{2}\hbox {O}_{4}\) was identified as the active phase deposited on Ha. The catalysts degraded these azo-dyes in diluted solutions (\(22\, \hbox {mg l}^{-1}\) of RY-145 and \(35\, \hbox {mg l}^{-1}\) of BR-46) under mild reaction conditions (\(25^{\circ }\hbox {C}\), atmospheric pressure, pH 4 and minimum amounts of both catalyst and \(\hbox {H}_{2}\hbox {O}_{2})\). Significant levels of dye conversion (\(93.1\pm 2.2\%\) for RY-145 and \(54.4 \pm 2.0\%\) for BR-46) were achieved in a relatively short time. In addition, significant values of total organic carbon removal (\(59.5 \pm 1.8\%\) for RY-145 and \(33.9 \pm 1.4\%\) for BR-46) were obtained, indicating the total oxidation of a significant fraction of these dyes to \(\hbox {CO}_{2}\) and \(\hbox {H}_{2}\hbox {O}\).
Similar content being viewed by others
References
Abdel-Raouf N, Al-Homaidan A A and Ibraheem I B M 2012 Saudi J. Biol. Sci. 19 257
Torres-Luna J A, Carriazo J G and Sanabria N R 2016 Environ. Technol. 37 1346
Zaharia C and Suteu D 2012 in Puzyn T (ed.) Organic pollutants ten years after the Stockholm convention environmental and analytical update (Croatia: InTech Europe) p 55
Gómez M J, Pazos F, Guijarro F J, de Lorenzo V and Valencia A 2007 Mol. Syst. Biol. 3 1
Alves de Lima R O, Bazo A P, Salvadori D M F, Rech C M, de Palma Oliveira D and de Aragão Umbuzeiro G 2007 Mutat. Res. Genet. Toxicol. Environ. Mutagen. 626 53
Bouatay F, Dridi-Dhaouadi S, Drira N and Farouk Mhenni M 2016 Desalin. Water Treat. 57 13561
Byberg R, Cobb J, Diez Martin L, Thompson R W, Camesano T, Zahraa O et al 2013 Environ. Sci. Pollut. Res. 20 3570
Jaafarzadeh N, Takdastan A, Jorfi S, Ghanbari F, Ahmadi M and Barzegar G 2018 J. Mol. Liq. 256 462
Demir N, Gündüz G and Dükkancı M 2015 Environ. Sci. Pollut. Res. 22 3193
Natarajan S, Bajaj H C and Tayade R J 2018 J. Environ. Sci. 65 201
Balapure K, Bhatt N and Madamwar D 2015 Bioresour. Technol. 175 1
de Souza S M, Bonilla K A S and de Souza A A U 2010 J. Hazard. Mater. 179 35
Ong S-A, Uchiyama K, Inadama D, Ishida Y and Yamagiwa K 2010 Bioresour. Technol. 101 9049
Zollinger H 2003 Color chemistry: syntheses, properties, and applications of organic dyes and pigments (Zurich: Wiley-VCH)
Gül Ş and Özcan-Yıldırım Ö 2009 Chem. Eng. J. 155 684
Patil N N and Shukla S R 2015 J. Water Process. Eng. 7 314
Parvaresha V, Hashemib H, Khodabakhshic A and Sedehid M 2018 Desalin. Water Treat. 111 345
Caner N, Kiran I, Ilhan S, Pinarbasi A and Iscen C F 2011 Sep. Sci. Technol. 46 2283
Abd El-Rahim W, Moawad H, Abdel Azeiz A and Sadowsky M 2017 J. Biotechnol. 260 11
Fahimirad B, Asghari A and Rajabi M 2017 Spectrochim. Acta A: Mol. Biomol. Spectrosc. 179 58
Fu J and Kyzas G Z 2014 Chinese J. Catal. 35 1
Ghuge S P and Saroha A K 2018 J. Water Process. Eng. 23 217
Bouafia-Chergui S, Oturan N, Khalaf H and Oturan M A 2010 J. Environ. Sci. Health, A: Toxic/Hazard. Subst. Environ. Eng. 45 622
Dong J, Dong H, Han L, Fu B, Chen Y and Zhan Y 2015 Desalin. Water Treat. 56 1056
Baloyi J, Ntho T and Moma J 2018 RSC Adv. 8 5197
Bokare A D and Choi W 2014 J. Hazard. Mater. 275 121
Bao X, Qin Z, Zhou T and Deng J 2018 J. Environ. Sci. 65 236
Reza K M, Kurny A and Gulshan F 2016 Int. J. Environ. Sci. Technol. 7 325
Covinich L G, Massa P, Fenoglio R J and Area M C 2016 Crit. Rev. Environ. Sci. Technol. 46 1745
Munoz M, de Pedro Z M, Casas J A and Rodriguez J J 2015 Appl. Catal. B: Environ. 176–177 249
Vela-Monroy C A, Saavedra-Alemán M J and Carriazo-Baños J G 2016 Tecno Lógicas 19 13
Wang N, Zheng T, Zhang G and Wang P 2016 J. Environ. Chem. Eng. 4 762
Yu C, Li G, Wei L, Fan Q, Shu Q and Yu J C 2014 Catal. Today 224 154
Liu S, Gu Y, Wang S, Zhang Y, Fang Y, Johnson D M et al 2013 Chin. Sci. Bull. 58 2340
Carriazo J G, Bossa-Benavides L F and Castillo E 2012 Quím. Nova 35 1101
Carrillo A M and Carriazo J G 2015 Appl. Catal. B: Environ. 164 443
Molano W A, Cárdenas J C, Sierra C A, Carriazo J G and Ochoa-Puentes C 2018 ChemistrySelect 3 4430
Carrillo A M, Urruchurto C M, Carriazo J G, Moreno S and Molina R A 2014 Rev. Mex. Ing. Quím. 13 563
Nath N C D, Debnath T, Kim E-K, Ali Shaikh M A and Lee J-J 2018 Electrochim. Acta 273 474
Palacios-Hernández T, Hirata-Flores G A, Contreras-López O E, Mendoza-Sánchez M E, Valeriano-Arreola I, González-Vergara E et al 2012 Inorg. Chim. Acta 392 277
Ercolino G, Grodzka A, Grzybek G, Stelmachowski P, Specchia S and Kotarba A 2017 Top. Catal. 60 333
Liu Z-Q, Xiao K, Xu Q-Z, Li N, Su Y-Z, Wang H-J et al 2013 RSC Adv. 3 4372
Silambarasan M, Padmanathan N, Ramesh P and Geetha D 2016 Mater. Res. Express 3 1
Alvarez A, Ivanova S, Centeno M A and Odriozola J A 2012 Appl. Catal. A: Gen. 431–432 9
Thommes M, Kaneko K, Neimark A V, Olivier J P, Rodriguez-Reinoso F, Rouquerol J et al 2015 Pure Appl. Chem. 87 1051
Tartaj P, Morales M P, Gonzalez-Carreño T, Veintemillas-Verdaguer S and Serna C J 2011 Adv. Mater. 23 5243
Carriazo J G, Molina R and Moreno S 2008 Appl. Catal. A 334 168
Carriazo J G, Guélou E, Barrault J, Tatibouet J M, Molina R and Moreno S 2005 Catal. Today 107–108 126
Garrido-Ramirez E G, Sivaiah M V, Barrault J, Valange S, Theng B K G, Ureta-Zañartu M S et al 2012 Microporous Mesoporous Mater. 162 189
Song S, Xu X, Xu L, He Z, Ying H, Chen J et al 2008 Ind. Eng. Chem. Res. 47 1386
Alahiane S, Qourzal S, El-Ouardi M, Abaamrane A and Assabbane A 2014 Am. J. Anal. Chem. 5 445
Acknowledgements
We gratefully acknowledge Universidad Nacional de Colombia for supplying the resources for this scientific research. This work was developed in the Lab-DRES (Laboratorio de Diseño y Reactividad de Estructuras Sólidas, UN-Bogotá), and at the Engineering and Architecture Faculty (UN-Manizales).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Torres-Luna, J.A., Giraldo-Gómez, G.I., Sanabria-González, N.R. et al. Catalytic degradation of real-textile azo-dyes in aqueous solutions by using Cu–Co/halloysite. Bull Mater Sci 42, 137 (2019). https://doi.org/10.1007/s12034-019-1817-1
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s12034-019-1817-1