New diphosphopentamolybdate (VI) (\(\hbox {C}_{6}\hbox {H}_{14}\hbox {N})_{4}\)(\(\hbox {NH}_{4})_{2}[\hbox {P}_{2}\hbox {Mo}_{5}\hbox {O}_{23}]\cdot \hbox {H}_{2}\hbox {O}\) synthesis, crystal structure, experimental and theoretical studies

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Abstract

The title compound (\(\hbox {C}_{6}\hbox {H}_{14}\hbox {N})_{4}(\hbox {NH}_{4})_{2}[\hbox {P}_{2}\hbox {Mo}_{5}\hbox {O}_{23}]\cdot \hbox {H}_{2}\hbox {O}\) (1) was obtained by solution method using ammonium molybdate tetrahydrate, phosphoric acid and cyclohexylamine reagents in aqueous solution. A single-crystal X-ray diffraction study shows that the compound crystallizes in triclinic crystal system with space group P-1 and cell constants \(a = 10.7178(4)\) Å, \(b= 15.0809(6)\) Å, \(c= 15.7745(9)\) Å, \(\alpha = 71.510(6){^{\circ }}\), \(\beta = 75.508(2){^{\circ }}\) and \(\gamma = 88.493(8){^{\circ }}\). Also, in this article, we report results of thermal, electrochemical and spectral studies. In addition, the majority of theoretical properties were carefully studied.

Keywords

Diphosphopentamolybdate synthesis crystal structure physicochemical properties theoretical study 

Notes

Acknowledgements

This scientific work was supported by the Ministry of Higher Education and Scientific Research of Tunisia.

Supplementary material

12034_2018_1561_MOESM1_ESM.docx (161 kb)
Supplementary material 1 (docx 160 KB)

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Copyright information

© Indian Academy of Sciences 2018

Authors and Affiliations

  1. 1.Laboratory of Materials, Crystal Chemistry and Applied Thermodynamics, Faculty of Sciences MonastirUniversity of MonastirMonastirTunisia

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