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Structural investigation of V2O5–P2O5–K2O glass system with antibacterial potential

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Abstract

The xV2O(1−x)[0.8 P2O5 ⋅ 0.2 K2O] glass system with 0 ≤ x ≤ 50 mol% was prepared and the structural changes induced in these glasses by increasing the vanadium oxide content were investigated by IR and ESR spectroscopies. The dual behaviour role of V2O5 oxide, as network modifier (for x ≤ 10 mol%) and the network former (x ≥ 20 mol%), as a consequence of phosphate network depolymerization and P–O–V and V–O–V linkages appearance was also highlighted. The antibacterial effect of the glasses with x ≤ 20 mol% V2O5 content was tested by optical density (OD) measurements. A linear correlation between the amount of vanadium and the antibacterial effect was evidenced.

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Acknowledgements

We extend many thanks to Prof V Simon for her useful suggestions in the manuscript preparation.

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Authors and Affiliations

  1. Iuliu Hatieganu University of Medicine and Pharmacy, Faculty of Pharmacy, RO-400023, Cluj-Napoca, Romania

    N S VEDEANU

  2. National Institute for Research and Development for Isotopic and Molecular Technologies, RO-400293, Cluj-Napoca, Romania

    I B COZAR

  3. Babes-Bolyai University, Faculty of Physics, Kogalniceanu 1, 400084, Cluj-Napoca, Romania

    R STANESCU & O COZAR

  4. University of Agricultural Science and Veterinary Medicine, 400372, Cluj-Napoca, Romania

    R STEFAN & D VODNAR

  5. Academy of Romanian Scientists, Splaiul Independentei 54, RO-050094, Bucharest, Romania

    O COZAR

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  1. N S VEDEANU
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Correspondence to I B COZAR.

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VEDEANU, N.S., COZAR, I.B., STANESCU, R. et al. Structural investigation of V2O5–P2O5–K2O glass system with antibacterial potential. Bull Mater Sci 39, 697–702 (2016). https://doi.org/10.1007/s12034-016-1214-y

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  • DOI: https://doi.org/10.1007/s12034-016-1214-y

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