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Facile combustion synthesis of novel CaZrO3:Eu3+, Gd3+ red phosphor and remarkably enhanced photoluminescence by Gd3+ doping

Bulletin of Materials Science volume 38, pages 215–220 (2015)Cite this article

Abstract

A facile sol–gel combustion route was reported for the direct preparation of CaZrO3:Eu3+ and CaZrO3:Eu3+, Gd3+. The obtained deposits were characterized by XRD, TGA-DSC, SEM, EDS, PL measurements and microscope fluorescence. When the Gd3+ ions were introduced in this compound, the emissions of CaZrO3:Eu3+were remarkably enhanced. The emission spectrum of CaZrO3:Eu3+, Gd3+ nanocrystals exhibited a red shift compared with CaZrO3:Eu3+ samples. A new mechanism of the improved photoluminescent properties of Eu3+ by Gd3+ was investigated. The optimized phosphor CaZrO3:5%Eu3+, 2%Gd3+ could be considered an efficient red-emitting component for white lighting devices excited in the near-ultraviolet region.

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References

  1. Zhang H, Fu X, Niu S and Xin Q 2008 J. Alloys Compd. 459 103

    Article  Google Scholar 

  2. Xie A, Yuan X M, Wang F X, Shi Y, Li J, Liu L and Mu Z F 2010 J. Alloys Compd. 501 124

    Article  Google Scholar 

  3. Jüstel T, Nikol H and Ronda C R 1998 Angew. Chem. Int. Ed. 37 3084

    Article  Google Scholar 

  4. Ianoş R and Barvinschi P 2010 J. Solid State Chem. 183 491

    Article  Google Scholar 

  5. Galuskin E V, Gazeev V M, Armbruster T, Zadov A E, Galuskina I O, Pertsev N N, DzierŻanowski P, Kadiyski M, Gyrbanov A G, Wrzalik R and Winiarski A 2008 Am. Mineral. 93 1903

    Article  Google Scholar 

  6. Li X J, Jiao H, Wang X M, Zeng Z Z and Jing X P 2010 J. Rare Earths 28 504

    Article  Google Scholar 

  7. Yan B and Xiao X Z 2007 J. Alloys Compd. 433 251

    Article  Google Scholar 

  8. Rodríguez R, Estevez M and Vargas S 2011 J. Non-Cryst. Solids 357 1383

    Article  Google Scholar 

  9. Wang Z L, Li G R, Ou Y N, Feng Z P, Qu D L and Tong Y X 2011 J. Phys. Chem. C 115 351

    Article  Google Scholar 

  10. Gu Y, Zhang Q, Li Y and Wang H 2011 J. Alloys Compd. 509 L109

    Article  Google Scholar 

  11. Rambabu U, Khanna P K, Rao I C and Buddhudu S 1998 Mater. Lett. 34 269

    Article  Google Scholar 

  12. Rosa L R, Katie J J and Anthony L D 2010 J. Phys. Chem. C 114 13884

    Article  Google Scholar 

  13. Hachani S, Monine B, El-akrmi A and Ferid M 2009 Opt. Mater. 31 678

    Article  Google Scholar 

  14. Tachihante M, Fournier M T, Arbus A and Cousseins J C 1984 Solid State Commun. 51 577

    Article  Google Scholar 

  15. Feofilov S P, Zhou Y, Jeong J Y, Keszler D A and Meltzer R S 2007 J. Lumin. 122–123 503

    Article  Google Scholar 

  16. Romanowski W R, Golab S, Dzik G D and Solarz P 2002 Appl. Phys. A 74 581

    Article  Google Scholar 

  17. Wu C C, Chen K B, Lee C S, Chen T M and Cheng B M 2007 Chem. Mater. 19 3278

    Article  Google Scholar 

  18. Ju G, Hu Y, Chen L, Wang X, Mu Z, Wu H and Kang F 2011 J. Alloys Compd. 509 655

    Google Scholar 

  19. Mothudi B M, Ntwaeaborwa O M, Pitale S S and Swart H C 2010 J. Alloys Compd. 508 262

    Article  Google Scholar 

  20. Du H Y, Li G S and Sun J Y 2007 J. Rare Earths 25 19

    Article  Google Scholar 

  21. Polizzi S, Bucella S, Speghini A, Vetrone F, Naccache R, Boyer J C and Capobianco J A 2004 Chem. Mater. 16 1330

    Article  Google Scholar 

  22. Mohapatra M, Mishra R K, Kaushik C P and Godbole S V 2010 Physica B 405 4790

    Article  Google Scholar 

  23. Kodaira C A, Brito H F, Malta O L and Serra O A 2003 J. Lumin. 101 11

    Article  Google Scholar 

  24. Gu M, Liu Q, Mao S, Mao D and Chang C 2008 Cryst. Growth Des. 8 1422

    Article  Google Scholar 

  25. Igarashi T, Ihara M, Kusunoki T and Ohno K 2000 Appl. Phys. Lett. 76 1549

    Article  Google Scholar 

  26. Yuan J L, Zeng X Y, Zhao J T, Zhang Z J, Chen H H and Zhang G B 2007 J. Solid State Chem. 180 3310

    Article  Google Scholar 

  27. Li Y, Chang Y, Lin Y, Chang Y and Lin Y 2007 J. Alloys Compd. 439 367

    Article  Google Scholar 

  28. Omkaram I, Vengala Rao B and Buddhudu S 2009 J. Alloys Compd. 474 565

    Article  Google Scholar 

  29. Guo C F, Ding X and Xu Y 2010 J. Am. Ceram. Soc. 93 1708

    Article  Google Scholar 

  30. Llanosa J, Castillo R, Espinoza D, Olivares R and Brito I 2011 J. Alloys Compd. 509 5295

    Article  Google Scholar 

  31. Lin C P, Chen S T and Chen T M 2002 Tamkang J. Sci. Eng. 5 81

    Google Scholar 

Download references

Acknowledgements

This work was supported by projects from The Chinese PLA Medical Science and Technique Foundation (CWS11J243) and The Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry, P R China.

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Authors and Affiliations

  1. State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100, P R China

    QINGQING DU, GUANGJUN ZHOU, HAIFENG ZHOU & ZHONGSEN YANG

  2. SEPCO III, Qingdao, 266100, P R China

    SHUO ZHANG

  3. College of Control Science and Engineering, Shandong University, Jinan, 250100, P R China

    XIAO JIA

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  1. QINGQING DU
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  2. GUANGJUN ZHOU
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  3. SHUO ZHANG
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  4. XIAO JIA
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Correspondence to GUANGJUN ZHOU.

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DU, Q., ZHOU, G., ZHANG, S. et al. Facile combustion synthesis of novel CaZrO3:Eu3+, Gd3+ red phosphor and remarkably enhanced photoluminescence by Gd3+ doping. Bull Mater Sci 38, 215–220 (2015). https://doi.org/10.1007/s12034-014-0787-6

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  • DOI: https://doi.org/10.1007/s12034-014-0787-6

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