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Electrical and magnetic properties of (BiNa)1/2(FeV)1/2O3

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Abstract

Potential multiferroic material, (BiNa)1/2(FeV)1/2O3, synthesized using solid-state route is investigated. The phase formation was confirmed by X-ray diffraction and surface morphology by scanning electron microscopy (SEM). Structural data reveal the single phase formation corroborated by SEM. The grain distribution is uniform with an average grain size of 3·6 μm. Electrical properties were investigated in a frequency range (1 kHz–1 MHz) by complex impedance spectroscopy (CIS) technique. The material showed negative temperature coefficient of resistance (NTCR) reflecting semiconductor behaviour. A.C. conductivity was found to obey Johnscher’s law. Conductivity mechanism is discussed and activation energy estimated (1·17 eV) for the conduction process is associated with Fe3 + → Fe2 +  variable state. The M–H curve showed the presence of ferromagnetism in the studied material.

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Correspondence to R N P CHOUDHARY.

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BERA, S.K., BARIK, S.K., CHOUDHARY, R.N.P. et al. Electrical and magnetic properties of (BiNa)1/2(FeV)1/2O3 . Bull Mater Sci 35, 47–51 (2012). https://doi.org/10.1007/s12034-011-0256-4

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  • DOI: https://doi.org/10.1007/s12034-011-0256-4

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