Abstract
Potential multiferroic material, (BiNa)1/2(FeV)1/2O3, synthesized using solid-state route is investigated. The phase formation was confirmed by X-ray diffraction and surface morphology by scanning electron microscopy (SEM). Structural data reveal the single phase formation corroborated by SEM. The grain distribution is uniform with an average grain size of 3·6 μm. Electrical properties were investigated in a frequency range (1 kHz–1 MHz) by complex impedance spectroscopy (CIS) technique. The material showed negative temperature coefficient of resistance (NTCR) reflecting semiconductor behaviour. A.C. conductivity was found to obey Johnscher’s law. Conductivity mechanism is discussed and activation energy estimated (1·17 eV) for the conduction process is associated with Fe3 + → Fe2 + variable state. The M–H curve showed the presence of ferromagnetism in the studied material.
Similar content being viewed by others
References
Ahmad M M, Yamane Y, Yamada K and Tanaka S 2007 J. Phys. D: Appl. Phys. 40 6020
Arbi K, Tabellout M, Lazarraga M G, Rojo J M and Sanz J 2007 Phys. Rev. B72 094302
Barik S K, Choudhary R N P and Mahapatra P K 2008 J. Mater. Sci.: Mater. Electron. 19 607
Cross L E 1987 Ferroelectrics 76 241
Fernandez J F, Moure C, Villegas M, Duran P, Kosec M and Drazic G 1998 J. Eur. Ceram. Soc. 18 1695
Jiang M, Liu X and Chen G 2009 Scr. Mater. 60 909
Jonscher A K 1977 Nature 267 673
Hosono Y, Harada K and Yamashita Y 2001 Jpn. J. Appl. Phys. 40 5722
Khomchenko V A, Kiselev D A, Vieira J M, Kholkin A L, Sá M A and Pogorelov Y G 2007 Appl. Phys. Lett. 90 242901
Macdonald J R 1987 Impedance spectroscopy emphasizing solid materials and systems (New York: John Wiley & Sons)
Mott N F 1990 Metal insulator transitions (London: Taylor and Francis)
Wang Y, Xu G, Ji X, Ren Z, Weng W, Du P, Shen G and Han G 2009 J. Alloys Compd. 475 L25
Yan Z, Wang K F, Qu J F, Wang Y, Song Z T and Feng S L 2007 Appl. Phys. Lett. 91 082906
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
BERA, S.K., BARIK, S.K., CHOUDHARY, R.N.P. et al. Electrical and magnetic properties of (BiNa)1/2(FeV)1/2O3 . Bull Mater Sci 35, 47–51 (2012). https://doi.org/10.1007/s12034-011-0256-4
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12034-011-0256-4