Abstract
Structure of Bi\(_{\boldsymbol{100-x}}\)Ga\(_{\boldsymbol{x}}\) molten alloys containing 38·5, 50, 70 and 91·5 at. % Ga has been studied by means of X-ray diffraction method and compared with viscosity measurements data. Significant changes in the structure factor profile were observed in vicinity of the concentration 70 at. % Ga. The dynamic viscosity coefficient was calculated by use of a statistical atomic distribution model and a Born–Green kinetic theory. The concentration dependence of viscosity is in agreement with change of structure parameters obtained from diffraction data.
This is a preview of subscription content, access via your institution.
References
Born M and Green H S 1947 Proc. R. Soc. A190 455
Buhalenko V V, Il’inskii A G, Romanov A V, Slusarenko S I and Chen S-Sh 1992 Metallofizika 14 42 (in Russian)
Huber B, Richter K W, Flandorfer H, Mikula A and Ipser H 2008 Int. J. Mater. Res. 99 18
Iida T, Ueda M and Morita Z 1976 Tetsu-to-Hagane 62 1169
Inui M and Takeda S 1993 J. Non-Cryst. Solids 156–158 153
Kaplow R, Strong S L and Averbach B L 1965 Phys. Rev. A138 1336
Ostrovskii O I, Grigoryan V A and Vishkarev A F 1988 Svoistva metallicheskikh rasplavov (Moscow: Metallurgiya) (in Russian)
Plevachuk Yu, Sklyarchuk V, Yakymovych A and Shtablavyi I 2009 Proceedings of the 6th international conference on electromagnetic processing of materials (EPM 2009) (Dresden: Forschungszentrum Dresden–Rossendorf) p. 415
Sklyarchuk V, Mudry S and Yakymovych A 2008 J. Phys.: Conf. Series 98 062021
Terzieff P 2008 J. Alloys Compds. 453 233
Vollmann J and Riedel D 1996 J. Phys.: Condens. Matter 8 6175
Wilson J R 1972 Structure of liquid metals and alloys (Moscow: Metallurgiya) [Russian translation]
Yagodin D A, Filippov V V, Popel P S, Sidorov V E and Son L D 2008 J. Phys.: Conf. Series 98 062019
Zelener B V, Norman G E and Filinov V S 1981 Perturbation theory and pseudopotential in statistical thermodynamics (Moscow: Nauka)
Author information
Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
MUDRY, S., YAKYMOVYCH, A., SHTABLAVYI, I. et al. Correlation between diffraction and viscosity data for Bi–Ga molten alloys. Bull Mater Sci 35, 83–87 (2012). https://doi.org/10.1007/s12034-011-0253-7
Received:
Revised:
Published:
Issue Date:
Keywords
- Bi–Ga alloys
- structure factor
- X-ray diffraction method
- viscosity
- melts