Abstract
The Na2ZnP2O7 compound was obtained by the conventional solid-state reaction. The sample was characterized by X-ray powder diffraction, infrared analysis and electrical impedance spectroscopy. The impedance plots show semicircle arcs at different temperatures and an electrical equivalent circuit has been proposed to explain the impedance results. The circuits consist of the parallel combination of bulk resistance R p and constant phase elements CPE. Dielectric data were analyzed using complex electrical modulus M* for the sample at various temperatures. The frequency dependence of the conductivity is interpreted in terms of Jonscher’s law. The conductivity σ d.c. follows the Arrhenius relation. The near value of activation energies obtained from the analysis of M″ and conductivity data confirms that the transport is through ion hopping mechanism, dominated by the motion of the Na+ ions in the structure of the investigated materials.
Similar content being viewed by others
References
Almond D P and West A R 1987 J. Solid State Ionics 23 27
Anantha P S and Hariharan K 2005 J. Mater. Sci. & Eng. B121 12
Ben Rhaiem A, Hlel F, Guidara K and Gargouri M 2009a J. Alloy. Compd. 485 718
Ben Rhaiem A, Chouaib S and Guidara K 2009b J. Ionics (accepted)
Ben Rhaiem A, Guidara K, Gargouri M and Daoud A 2005 J. Alloy. Compd. 87 392
Belharouak I, Gravereau P, Parent C, Chaminade J P, Lebraud E and Le Flem G 2000 J. Solid State Chem. 152 466
Chen S A and Liao C S 1993 J. Macromol. 26 2810
Dridi N, Boukhari A, Réau J M, Rbib E and Holt E M 2000 J. Solid State Ionics 127 141
Dridi N, Boukhari A, Réau J M, Rbib E and Holt E M 2001 J. Mater. Letts. 47 212
Erragh F, Boukhari A and Holt E M 1998 J. Acta Crystallogr. C54 1373
Erragh F, Boukhari A, Eloudi B and Abraham F 1995 J. Solid State Chem. 120 23
El Maadi A, Boukhari A and Holt E M 1995 J. Chem. Crystallogr. 25 531
Ganguli M, Harish Bhat M and Rao K J 1999 J. Phys. Chem. Glasses 40 297
Ghosh S and Ghosh A 2002 J. Solid State Ionics 149 67
Gómez D and Algría A 2001 J. Non-Crystallogr. Solids 287 246
Hodge L M, Ingram M D and West A R 1976 J. Electroanal. Chem. 74 125
Jarboui A, Ben Rhaiem A, Hlel F, Guidara K and Gargouri M 2010 J. Ionics 16 67
Jonscher A K 1977 J. Nature (London) 267 673
Kuhlmann U, Thomsen C, Prokoviev A V, Bullesfeld F, Uhrig E and Assmus W 2001 J. Physica B301 285
Lenfredi S, Saia P S, Lebullenger R and Hemandes A C 2002 J. Solid State Ionics 146 329
Louati B, Gargouri M, Guidara K and Mhiri T 2005 J. Phys. Chem. Solids 66 762
Mahadevan Pillai V P, Thomas B R, Nayar V and Lii K H 1999 J. Spectrochim. Acta A55 1809
Nadeem M, Akhtar M J and Khan A Y 2005 Sol. State Commun. 134 431
Padmasree K P, Kanchan D K and Kulkarni A R 2006 J. Solid State Ionics 177 475
Papathanassiou A N 2005 J. Chem. Solids 66 1849
Parathan D K, Samantry B K, Chauthaey R N P and Thakur A K 2005 J. Mater. Sci. Eng. B116 431
Reau J M, Jun X Y, Senegas J, Le Deit Ch and Poulain M 1997 J. Solid State Ionics 95 191
Santha N, Nayar V and Keresztury G 1993 J. Spectrochim. Acta A49 47
Sanz F, Parada C, Rojo J M, Ruiz-Valero C and Saez-Puche R 1999 J. Solid State Chem. 145 604
Sural M and Gosh A 2000 J. Solid State Ionics 130 259
Uvarov N F, Hairetdinov E F, Reau J M, Bobe J M, Senegas J and Poulain M 1994 J. Solid State Ionics 74 195
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Chouaib, S., Ben Rhaiem, A. & Guidara, K. Dielectric relaxation and ionic conductivity studies of Na2ZnP2O7 . Bull Mater Sci 34, 915 (2011). https://doi.org/10.1007/s12034-011-0214-1
Received:
Revised:
Published:
DOI: https://doi.org/10.1007/s12034-011-0214-1