Abstract
Heterogeneous oxidation of cyclohexane with tertiobutyl hydroperoxide was carried out on Pt/oxide (Al2O3, TiO2 and ZrO2) catalysts in the presence of different solvents (acetic acid and acetonitrile). The catalysts were prepared using Pt(NH3)2(NO2)2 as a precursor and characterized by chemical analysis using the ICP–AES method, XRD, TEM, FTIR and BET surface area determination. The oxidation reaction was carried out at 70°C under atmospheric pressure. The results showed the catalytic performance of Pt/Al2O3 as being very high in terms of turnover frequency.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Anisia K S and Kumar A 2004 Appl. Catal. A: Gen. 273 193
Bellifa A, Lahcene D, Technar Y N, Choukchou-Braham A, Bachir R, Bedrane S and Kappenstein C 2006 Appl. Catal. A: Gen. 305 1
Carballo L, Serrano C, Wolf E E and Carberry J 1978 J. Catal. 52 507
Corma F, Sepulveda-Escribano A, Fierro J L and Rodriguez-Reinoso F 1997 Appl. Catal. A: Gen. 150 165
Du Y, Xiong Y, Li J and Yang X 2009 J. Mol. Catal. A: Chem. 298 12
Ebadi A, Safari N and Peyrovi M H 2007 Appl. Catal. A: Gen. 321 135
Garetto T F and Apesteguia C R 2000 Catal. Today 62 189
Ingold K U 1989 Aldrichim. Acta 22 69
Kobayashi M, Kanno T, Konishi A and Takeda H 1988 React. Kinet. Catal. Lett. 37 89
Kumar R, Sithambarama S and Suib S L 2009 J. Catal. 262 304
Kuznetsova N I, Kirillova N V, Kuznetsova L I and Likholobov V A 2003 J. Mol. Catal. A: Chem. 204–205 591
Labalme V, Garbowsky E, Ghilhaume N and Primet M 1996 Appl. Catal. A: Gen. 138 93
Lu G, Zhao R, Qian G, Qi Y, Wang X and Suo J 2004 Catal. Lett. 97 115
Lu G, Ji D, Qian G, Qi Y, Wang X and Suo J 2005 Appl. Catal. A: Gen. 280 175
Marecot P, Fakche A, Kellali B, Mabilon G, Prigent M and Barbier J 1994 Appl. Catal. B: Environ. 3 283
Masters A F, Beattie J K and Roa A L 2001 Catal. Lett. 75 159
Papaefthimiou P, Ioannides T and Verykios X E 1998 Appl. Catal. B: Environ. 15 75
Perkas N, Minh D P, Gallezot P, Gedanken A and Besson M 2005 Appl. Catal. B: Environ. 59 121
Pires E L, Magalhaes J C and Schuchardt U 2000 Appl. Catal. A: Gen. 203 231
Pliangos C, Yentekakis I V, Papadakis V G, Vayenas C G and Verykios X E 1997 Appl. Catal. B: Environ. 14 161
Radic N, Grbic B and Terlecki-Baricevic A 2004 Appl. Catal. B: Environ. 50 153
Rasband W and Image J 1997–2005 U.S. National Institutes of Health, Bethesda, MD, USA http://rsb.info.nih.gov/ij/
Reddy J S and Sivasanker S 1991 Catal. Lett. 11 241
Sakthivel A and Selvam P 2002 J. Catal. 211 134
Sawatari N, Yokota T, Sakaguchi S and Ishii Y 2001 J. Org. Chem. 66 7889
Schuchardt U, Carvalho W A and Spinace E V 1993 Synlett. 713
Schuchardt U et al 2001 Appl. Catal. A: Gen. 211 1
Shulpin G B, Fink G S and Smith J R 1999 Tetrahedron 55 5345
Silva A C et al 2007 Appl. Catal. A: Gen. 317 154
Sooknoi T and Limtrakul J 2002 Appl. Catal. A: Gen. 233 227
Wangcheng Z, Guanzhong L, Yanglong G, Yun G, Yanqin W, Yunsong W, Zhigang Z and Xiaohui L 2008 J. Rare Earths 26 515
Xu L X, He C H, Zhu M Q and Fang S 2007 Catal. Lett. 114 202
Yao W, Chen Y, Min L, Fang H, Yan Z, Wang H and Wang J 2006 J. Mol. Catal. A: Chem. 246 162
Yuan H X, Xia Q H, Zhan H J, Lu X H and Su K X 2006 Appl. Catal. A: Gen. 304 178
Zhao R, Wang Y, Guo Y, Guo Y, Liu X, Zhang Z, Wang Y, Zhan W and Lu G 2006 Green Chem. 8 459
Zhou L, Xu J, Miau H, Wang F and Li X 2005 Appl. Catal. A: Gen. 292 223
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
REKKAB-HAMMOUMRAOUI, I., CHOUKCHOU-BRAHAM, A., PIRAULT-ROY, L. et al. Catalytic oxidation of cyclohexane to cyclohexanone and cyclohexanol by tert-butyl hydroperoxide over Pt/oxide catalysts. Bull Mater Sci 34, 1127–1135 (2011). https://doi.org/10.1007/s12034-011-0157-6
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12034-011-0157-6