Abstract
The conventional magnetic materials used in current technology, such as, Fe, Fe2O3, Cr2O3, SmCo5, Nd2Fe14B etc are all atom-based, and their preparation/processing require high temperature routes. Employing self-assembly methods, it is possible to engineer a bulk molecular material with long-range magnetic order, mainly because one can play with the weak intermolecular interactions. Since the first successful synthesis of molecular magnets in 1986, a large variety of them have been synthesized, which can be categorized on the basis of the chemical nature of the magnetic units involved: organic-, metal-based systems, heterobimetallic assemblies, or mixed organic-inorganic systems. The design of molecule-based magnets has also been extended to the design of poly-functional molecular magnets, such as those exhibiting second-order optical nonlinearity, liquid crystallinity, or chirality simultaneously with long-range magnetic order. Solubility, low density and biocompatibility are attractive features of molecular magnets. Being weakly coloured, unlike their opaque classical magnet ‘cousins’ listed above, possibilities of photomagnetic switching exist. Persistent efforts also continue to design the ever-elusive polymer magnets towards applications in industry. While providing a brief overview of the field of molecular magnetism, this article highlights some recent developments in it, with emphasis on a few studies from the author’s own lab.
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References
Allemand P, Khemani K, Koch K, Wudl F, Holczer K, Donovan S, Gruner G and Thompson J D 1991 Science 253 301
Arita R, Suwa Y, Kuroki K and Aoki H 2002 Phys. Rev. Lett. 88 127202
Bagkar N, Ganguly R, Choudhury S, Hassan P A and Yakhmi J V 2004 J. Mater. Chem. 14 1430
Bagkar N, Choudhury S, Kim K H, Chowdhury P, Lee S I and Yakhmi J V 2006a Thin Solid Films 513 325
Bagkar N, Betty C A, Hassan P A, Kahali K, Bellare J R and Yakhmi J V 2006b Thin Solid Films 497 259
Bagkar N, Choudhury S, Bhattacharya S and Yakhmi J V 2008 J. Phys. Chem. Part C 112 6467
Bałanda M, Rams M, Nayak S K, Tomkowicz Z, Haase W, Tomala K and Yakhmi J V 2006 Phys. Rev. B74 224421
Banister A J et al 1996 Angew. Chem. Int. Ed. 35 2533
Barbara B and Gunther L 1999 Physics World 35
Benard S, Yu P, Audiere J P, Riviere E, Clement R, Guilhem J, Tchertanov L and Nakatani K 2000 J. Am. Chem. Soc. 122 9444
Binnemans K et al 2000 J. Am. Chem. Soc. 122 4335
Bogani L et al 2005 Phys. Rev. B72 064406
Broderick W E, Thompson J A, Day P and Hoffman B M 1990 Science 249 410
Caneschi A, Gatteschi D, Sessoli R and Rey P 1989 Acc. Chem. Res. 22 392
Chavan S A, Yakhmi J V and Gopalakrishnan I K 1995 Mol. Cryst. Liq. Cryst. 274 11
Chavan S A, Ganguly R, Jain V K and Yakhmi J V 1996 J. Appl. Phys. 79 5260
Chavan S A, Larionova J, Kahn O and Yakhmi J V 1998 Philos. Mag. B6 1657
Choudhury S, Bagkar N, Dey G K, Subramanian H and Yakhmi J V 2002 Langmuir 18 7409
Choudhury S, Dey G K and Yakhmi J V 2003 J. Cryst. Growth 258 197
Entley W R and Girolami G S 1995 Science 268 397
Friedman J R, Sarachik M P, Tejada J and Ziolo R 1996 Phys. Rev. Lett. 76 3830
Fujita W and Awaga K 1999 Science 286 261
Hashimoto K and Ohkoshi S 1999 Philos. Trans. R. Soc. London A357 2977
Holmes S M and Girolami G S 1999 J. Am. Chem. Soc. 121 5593
Inoue K and Iwamura H 1994 J. Am. Chem. Soc. 116 3173
Inoue K, Hayamizu T, Iwamura H, Hashizume D and Ohashi Y 1996 J. Am. Chem. Soc. 118 1803
Inoue K, Imai H, Ghalsasi P S, Ohba M, Okawa H and Yakhmi J V 2001 Angew. Chem. Int. Ed. 40 4242
Itkis M E, Chi X, Cordes A W and Haddon R C 2002 Science 296 1443
Itoh K and Kinoshita M (eds) 2000 Molecular magnetism (Amsterdam: Gordon and Breach Science Publishers)
Jain R, Kabir K, Gilroy J B, Mitchell K A R, Wong K C and Hicks R G 2007 Nature 445 291
Kahn O 1993 Molecular magnetism (New York: VCH)
Kahn O 1995 Adv. Inorg. Chem. 43 179
Kahn O (ed.) 1996 Magnetism: A supramolecular function, NATO ASI Series C (Dordrecht: Kluwer) Vol. 484
Kahn O, Pei Y, Verdaguer M, Renard J P and Sletten J 1988 J. Am. Chem. Soc. 111 7823
Kahn O, Larionova J and Yakhmi J V 1999 Chem. Eur. J. 5 3443
Krober J, Codjovi E, Kahn O, Groliere F and Jay C 1993 J. Am. Chem. Soc. 115 9810
Kumar A, Yusuf S M, Keller L, Yakhmi J V, Srivastava J K and Paulose P L 2007 Phys. Rev. B75 224419
Kumar A, Yusuf S M, Keller L and Yakhmi J V 2008 Phys. Rev. Lett. 101 207206
Larionova J, Chavan S A, Yakhmi J V, Froystein A G, Sletten J, Sourisseau C and Kahn O 1997 Inorg. Chem. 36 6374
Leuenberger M N and Loss D 2001 Nature 410 789
Lohmann K J and Johnsen S 2000 Trends in Neuro Sci. 23 153
Ludi A and Gudel H U 1973 Struct. Bonding (Berlin) 14 1
Maspoch D et al 2003 Nature Mater. 2 190
Maspoch D, Domingo N, Ruiz-Molina D, Wurst K, Vaughan G, Tejada J, Rovira C and Veciana J 2004 Angew. Chem. Int. Ed. 43 1828
Mathoniere C, Carling S G, Yusheng D and Day P 1994 J. Chem. Soc. Chem. Commun. 1551
Mathoniere C, Nuttal C J, Carling S G and Day P 1996 Inorg. Chem. 35 1201
McConnell H M 1963 J. Chem. Phys. 39 1910
Miller J S 2000 Inorg. Chem. 39 4392
Miller J S, Calabrese J C, Epstein A J, Bigelow R B, Zang J H and Reiff W M 1986 J. Chem. Soc.: Chem. Commun. 1026
Miller J S and Pokhodnya K I 2007 J. Mater. Chem. 17 3585
Mito M, Tanimoto T, Kawae T, Hitaka M, Takeda K, Nakatsuji S, Morimoto H and Anzai H 2001 Polyhedron 20 1509
Mrzel A, Omerzu A, Umek P, Mihailovic D, Jaglicic Z and Trontelj Z 1998 Chem. Phys. Lett. 298 329
Mukadam M D, Kumar K, Yusuf S M, Yakhmi J V, Tewari R and Dey G K 2008 J. Appl. Phys. 103 123902
Nakatani K et al 1989 J. Am. Chem. Soc. 111 5739
Neels A, Stoeckli-Evans H, Chavan S A and Yakhmi J V 2001 Inorg. Chim. Acta 326 106
Okawa H, Mitsumi M, Ohba M, Kodera M and Matsumoto N 1994 Bull. Chem. Soc. Jap. 67 2139
Ohkoshi S I, Abe Y, Fujishima A and Hashimoto K 1999 Phys. Rev. Lett. 82 1285
Ohkoshi S I et al 2006 J. Am. Chem. Soc. 128 270
Ovchinnikov A A 1978 Theor. Chim. Acta 47 297
Palacio F, Antorrena G, Castro M, Burriel R, Rawson J, Smith J N, Bricklebank N, Novoa J and Clemens R 1997 Phys. Rev. Lett. 79 2336
Pei Y, Verdaguer M, Kahn O, Sletten J and Renard J P 1986 J. Am. Chem. Soc. 108 428
Pei Y, Kahn O, Nakatani K, Codjovi E, Mathoniere C and Sletten J 1991 J. Am. Chem. Soc. 113 6558
Pejakovic D A, Kitamura C, Miller J S and Epstein A E 2002 Phys. Rev. Lett. 88 057202
Philipse A P and Mass D 2002 Langmuir 18 9977
Rajca S, Wongsriratanakul J and Rajca S 2001 Science 294 1503
Sastry M D, Bhide M K, Kadam R M, Chavan S A, Yakhmi J V and Kahn O 1999 Chem. Phys. Lett. 301 385
Sra A K, Andruh M, Kahn O, Golhen S, Ouahab L and Yakhmi J V 1999 Angew. Chem. Int. Ed. 38 2606
Sra A K, Rombaut G, Lahitete F, Golhen S, Ouahab L, Mathoniere C, Yakhmi J V and Kahn O 2000 New J. Chem. 24 871
Sra A K, Tokumoto M and Yakhmi J V 2001 Philos. Mag. B81 477
Stumpf H O, Pei Y, Kahn O, Sletten J and Renard J P 1993a J. Am. Chem. Soc. 115 6738
Stumpf H O, Ouahab L, Pei Y, Grandjean D and Kahn O 1993b Science 261 447
Stumpf H O, Ouahab L, Pei Y, Bergerat P and Kahn O 1994a J. Am. Chem. Soc. 116 3866
Stumpf H O, Pei Y, Michaut C, Kahn O, Renard J P and Ouahab L 1994b Chem. Mater. 6 257
Tamura M, Nakazawa Y, Shiomi D, Nozawa K, Hosokoshi Y, Ishikawa M, Takahashi M and Kinoshita M 1991 Chem. Phys. Lett. 186 401
Turner S, Kahn O and Rabardel L 1996 J. Am. Chem. Soc. 118 6428
Vaz M G F et al 1999 Chem. Eur. J. 5 1486
Yakhmi J V 2003 Proc. of INAE conf. on nanotechnology (ICON-2003) (ed.) M J Zarabi (Indian National Acad. of Engineering) pp 78–87
Zhang J, Zhou P, Brinckerhoff W B, Epstein A J, Vazquez C, McLean R S and Miller J S 1996 A. C. S. Symp. Ser. 644 311
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Yakhmi, J.V. Molecule-based magnets. Bull Mater Sci 32, 217–225 (2009). https://doi.org/10.1007/s12034-009-0033-9
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DOI: https://doi.org/10.1007/s12034-009-0033-9