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Synthesis and structural studies of Na2O-ZnO-ZnF2-B2O3 oxyfluoride glasses

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This paper describes the synthesis and spectroscopic studies of the glass system, 20Na2O-(20-x) ZnO-xZnF2-60B2O3(x = 0, 5, 10, 15, 20), prepared by melt quenching method. The analyses of DSC and XRD did not show the crystallinity of the glass sample. 11B MAS-NMR shows the presence of sharp peak around −14 ppm. From the IR studies, the broadening of the peak around 1200–1400 and 800–1100 cm−1 shows the presence of mixed linkages like B-O-B, B-O-Zn in the network.

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Correspondence to V. M. Jali.

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Patil, S.D., Jali, V.M. & Anavekar, R.V. Synthesis and structural studies of Na2O-ZnO-ZnF2-B2O3 oxyfluoride glasses. Bull Mater Sci 31, 631–634 (2008). https://doi.org/10.1007/s12034-008-0100-7

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  • DOI: https://doi.org/10.1007/s12034-008-0100-7

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