Abstract
Lead strontium zirconate, Pb1−x Sr x ZrO3 (0 ≤ x ≤ 0·20) ceramics, were prepared by novel glycinenitrate self-propagating combustion technique. The crystal structure of the ceramics was investigated as a function of composition via X-ray diffraction (XRD). The XRD patterns obtained on these powders showed the formation of pure orthorhombic phase of lead strontium zirconate without impurities and all the compounds retained the orthorhombic structure. The samples were sintered at 900–1100°C for 2 h. It has been observed that the dielectric constant decreases with increase in strontium content (100 kHz). In all compositions, dielectric constant showed a peak at transition temperature and the magnitude of the peak was found to decrease with strontium doping level.
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Berlincourt D, Jaffe H, Krueger H H A and Jaffe B 1963 Appl. Phys. Lett. 3 90
Fushimi S and Ikeda T 1967 J. Am. Ceram. Soc. 50 129
Gachigi K, Pruna P M, Ranall C A, Shrout T R, Jang S J and Dougherty J P 1998 J. Korean Phys. Soc. 32 960
Gaukler Ludwig J, Sasaki Kazunari, Mitterdorfer Andreas, Godickemeier Martin and Bohac Petr 1994 Proc. first European solid state oxide fuel cell forum (ed.) Ulf Bossel (Lucerne, Switzerland) 12 p. 545
Goulpeau L 1967 Sov. Phys. Solid State 8 1970
Handerek J, Pisarski M and Ujma Z 1981a J. Phys. C14 2007
Handerek J, Pisarski M and Ujma Z 1981b J. Phys. C: Solid State 14 2007
Harrad E I, Ridah A, Carabatos-Nedelec C, Becker P, Handerek J, Uzma Z and Dmytrow D 1998 J. Raman Spectrosc. 29 123
Hatchell C, Sammes N M and Brown I W M 1999 J. Power Sources 77 64
Jaffe B, Cook W R and Jaffe H 1971a Piezoelectric ceramics (Marietta, Ohio: Academic Press, R. A. N. Publishers) p. 123
Jain S R and Adiga K C 1981 Combustion and Flame 40 71
Jona F and Shirane G 1957 Phys. Rev. 105 849
Kanno I, Hayashi S, Kitagawa M, Tikayama R and Hirao T 1995 Appl. Phys. Lett. 66 145
Kato J, Fuji H, Kagata H and Nishimoto K 1993 Jpn J. Appl. Phys. 32 4356
Krainik N N 1958 Sov. Phys. Tech. Phys. 3 493
Nedelec C C, Harrad I E, Handerek J, Brehat F and Wyncke B 1992 Ferroelectrics 125 483
Pan W Y, Zhang Q, Bhalla A and Cross L E 1989a J. Am. Ceram. Soc. 72 570
Pan W Y, Dam C W, Zhang Q and Cross L E 1989b J. Appl. Phys. 66 6014
Park S, Pan M, Markoski K, Yoshikawa S and Cross L E 1997 J. Appl. Phys. 82 1798
Pokharel B P and Pandey D 2000 J. Appl. Phys. 88 5364
Pokharel B P, Datta M K and Pandey D 1999a J. Mater. Sci. 34 691
Pokharel B P, Ranjan R, Pandey D, Siruguri V and Paranjpe S K 1999b Appl. Phys. Lett. 74 756
Rao C N R 1993 Mater. Sci. Engg. B18 1
Roberts S 1950 J. Am. Ceram. Soc. 33 63
Roberts S 1981 J. Am. Ceram. Soc. 64 533
Scott B A and Burns G 1972 J. Am. Ceram. Soc. 55 331
Shirane G 1952 Phys. Rev. 86 219
Shirane G and Hoshino S 1954 Acta Crystallogr. 7 203
Shirane G, Sawaguchi E and Takagi Y 1951 Phys. Rev. 84 476
Ujma Z, Handerek J, Pawelezyk M and Dmytrow D 1992 Ferroelectrics 129 127
McKinstry S and Dougherty J P 1997 J. Mater. Sci. 32 5169
Yoon K H, Hwang S C and Kang D H 1997 J. Mater. Sci. 32 17
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Boopathy, K., Samson Nesaraj, A. & Rajendran, V. Self-propagating combustion synthesis of Pb1−x Sr x ZrO3 (0 ≤ x ≤ 0·20) ceramics and their dielectric properties. Bull Mater Sci 31, 149–153 (2008). https://doi.org/10.1007/s12034-008-0026-0
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DOI: https://doi.org/10.1007/s12034-008-0026-0