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Vanadium Compounds as Biocatalyst Models

  • Juliana E. Parente
  • Patricia A. M. Williams
  • Evelina G. FerrerEmail author
Article
  • 27 Downloads

Abstract

Peroxidovanadium(V) and oxidovanadium(IV) compounds have been tested as peroxidase-similar compounds. Their catalytic performance was tested on phenol red and pyrogallol substrates. Bromination kinetic studies revealed Michaelis-Menten behavior with respect to phenol red for both complexes. Catalytic efficiency is ~ 104 M−1 min−1. Both vanadium complexes showed the capacity to oxidize pyrogallol, but only the oxidovanadium (IV) complex follows Michaelis-Menten kinetics with respect to this substrate (Km = 1.05 × 10-3 M). Peroxidovanadium(V) complex displayed a more complex mechanism, and further studies became necessary to elucidate it. The structure-activity relationship was also assessed.

Keywords

Vanadium complexes Biocatalyst models Peroxidase-similar activity Phenol red Pyrogallol 

Notes

Funding Information

This work was supported by the Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET, PIP 0611), Agencia Nacional de Promoción Científica y Tecnológica (ANPCyT, PICT16-1814), and Universidad Nacional de La Plata (UNLP, X777) of Argentina. EGF is a Research Fellow of CONICET. JEP and PAMW are Research Fellows of Comisión de Investigaciones Científicas de la Provincia de Buenos Aires (CICPBA) Argentina.

Compliance with Ethical Standards

Conflict of Interest

The authors declare that they have no conflict of interest.

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Authors and Affiliations

  1. 1.Center of Inorganic Chemistry (CEQUINOR, CONICET-CICPBA-UNLP)-Department of Chemistry-Faculty of Exact SciencesNational University of La PlataLa PlataArgentina

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